Spectral Efficient Coding Schemes in Optical Communications

Abstract Achieving high spectral efficiency in optical transmissions has recently attracted much attention, aiming to satisfy the ever increasing demand for high data rates in optical fiber co mmun ications. Therefore, strong Forward Error Correct ion (FEC) coding in co mb ination with mult ilevel modulat ion schemes is mandatory to approach the channel capacity of the transmission link. In this paper we g ive design rules on the joint optimization of coding and signal constellations under practical considerations. We give trade-offs between spectral efficiency and hardware complexity, by comparing coding schemes using capacity achieving constellations with bit-interleaved coded modulation and iterative decoding (BICM-ID) against applying conventional square quadrature amp litude modulation (QAM) constellations but emp loying powerful low co mplexity lo w-density parity-check (LDPC) codes. Both schemes are suitable for optical single carrier (SC) and optical orthogonal frequency-division mu ltiplexing (OFDM) transmission systems, where we consider the latter one in this paper, due to well-studied equalizat ion techniques in wireless communications. We numerically study the performance of different coded modulation formats in optical OFDM transmission, showing that for a fiber optical transmission lin k of 960 km reach the net spectral efficiency can be increased by ≈0.4 bit/s/Hz to 8.61 b it/s/Hz at a post FEC BER of <10 -15 by using coded optimized constellations instead of coded 64-QAM

Immobilization, Trapping, and Anion Exchange of Perrhenate Ion Using Copper-Based Tripodal Complexes

We describe a multidentate tripodal ligand in which three pendant arms carrying di(2-picolyl)amine units are linked to the ortho positions of a tris(o-xylyl) scaffold, providing N(CH[subscript 2]-o-C[subscript 6]H[subscript 4]CH[subscript 2]N(CH2py)[subscript 2])[subscript 3] (L). Reaction of L with CuCl[subscript 2] in the presence of hexafluorophosphate anion afforded blue cubes of [(CuCl)[subscript 3]L](PF[subscript 6])[subscript 3]·5H[subscript 2]O (1). Crystallographic studies of 1 revealed that the three symmetry-related arms each coordinate a {Cu[superscript II]Cl} unit, and two molecules of 1 are connected to one another through a Cu(μ-Cl)[subscript 2]Cu bridge, extending the molecular structure to form a two-dimensional (2-D) layer. These 2-D layers pack in an ABCABC... fashion with PF[subscript 6]– anions located in between. Reaction of 1 with a stoichiometric amount of perrhenate ion afforded blue plates of [(CuCl)[subscript 3]L](PF[subscript 6])(ReO[subscript 4])[subscript 2]·3H[subscript 2]O (2). Compound 2 has the same lattice structure as 1, but the tricopper unit backbone now traps one ReO[subscript 4]– anion through Coulombic interactions. In addition, three molecules of 2 are bridged by a perrhenate ion, forming a Cu[subscript 3](μ[superscript 3]-ReO[subscript 4]) cluster, to give a different 2-D structure displaying a rare tridentate bridging ReO[subscript 4]– mode. Thus, in addition to classic perrhenate trapping through weak Coulombic interactions, 2 represents an exceptional example in which the ReO[subscript 4]– anion is immobilized in an extended framework through tight covalent interactions. The interlamellar PF[subscript 6]– anions in 1 can be exchanged with other anions including perrhenate, perchlorate, or periodate. The structural similarity between perrhenate and pertechnetate makes these materials of potential interest for pertechnetate trapping

Consolidating Heterogeneous Enterprise Data for Named Entity Linking and Web Intelligence

Linking named entities to structured knowledge sources paves the way for state-of-the-art Web intelligence applications which assign sentiment to the correct entities, identify trends, and reveal relations between organizations, persons and products. For this purpose this paper introduces Recognyze, a named entity linking component that uses background knowledge obtained from linked data repositories, and outlines the process of transforming heterogeneous data silos within an organization into a linked enterprise data repository which draws upon popular linked open data vocabularies to foster interoperability with public data sets. The presented examples use comprehensive real-world data sets from Orell Füssli Business Information, Switzerland's largest business information provider. The linked data repository created from these data sets comprises more than nine million triples on companies, the companies' contact information, key people, products and brands. We identify the major challenges of tapping into such sources for named entity linking, and describe required data pre-processing techniques to use and integrate such data sets, with a special focus on disambiguation and ranking algorithms. Finally, we conduct a comprehensive evaluation based on business news from the New Journal of Zurich and AWP Financial News to illustrate how these techniques improve the performance of the Recognyze named entity linking component

Performance of combined constellation shaping and bit interleaved coded modulation with iterative decoding (BICM-ID)

The increasing demand of achieving high data rates in modern communication systems requires highly efficient bandwidth utilization. For this purpose, multilevel modulation schemes are used in association with forward error correction (FEC) codes in order to approach the channel capacity. However, there is a gap between the capacity of a uniform signal constellation and the Shannon unconstrained capacity. This gap can be reduced by applying constellation shaping. The task of shaping is to modify a uniform distributed signal constellation towards a Gaussian like distribution. In this paper, we investigate different approaches to combine the constellation shaping with a bit interleaved coded modulation with iterative decoding (BICM-ID) system. Simulation results show that this combination can offer a shaping gain up to 0.6 dB