Structure and structure relaxation

A discrete--dynamics model, which is specified solely in terms of the system's equilibrium structure, is defined for the density correlators of a simple fluid. This model yields results for the evolution of glassy dynamics which are identical with the ones obtained from the mode-coupling theory for ideal liquid--glass transitions. The decay of density fluctuations outside the transient regime is shown to be given by a superposition of Debye processes. The concept of structural relaxation is given a precise meaning. It is proven that the long-time part of the mode-coupling-theory solutions is structural relaxation, while the transient motion merely determines an overall time scale for the glassy dynamics

Structural relaxation in orthoterphenyl: a schematic mode coupling theory model analysis

Depolarized light scattering spectra of orthoterphenyl showing the emergence of the structural relaxation below the oscillatory microscopic excitations are described by solutions of a schematic mode--coupling--theory model

A mode-coupling theory for the glassy dynamics of a diatomic probe molecule immersed in a simple liquid

Generalizing the mode-coupling theory for ideal liquid-glass transitions, equations of motion are derived for the correlation functions describing the glassy dynamics of a diatomic probe molecule immersed in a simple glass-forming system. The molecule is described in the interaction-site representation and the equations are solved for a dumbbell molecule consisting of two fused hard spheres in a hard-sphere system. The results for the molecule's arrested position in the glass state and the reorientational correlators for angular-momentum index $\ell = 1$ and $\ell = 2$ near the glass transition are compared with those obtained previously within a theory based on a tensor-density description of the molecule in order to demonstrate that the two approaches yield equivalent results. For strongly hindered reorientational motion, the dipole-relaxation spectra for the $\alpha$-process can be mapped on the dielectric-loss spectra of glycerol if a rescaling is performed according to a suggestion by Dixon et al. [Phys. Rev. Lett. {\bf 65}, 1108 (1990)]. It is demonstrated that the glassy dynamics is independent of the molecule's inertia parameters.Comment: 19 pages, 10 figures, Phys. Rev. E, in prin

Reentrant glass transition in a colloid-polymer mixture with depletion attractions

Performing light scattering experiments we show that introducing short-ranged attraction to a colloidal suspension of nearly hard spheres by addition of free polymer produces new glass transition phenomena. We observe a dramatic acceleration of the density fluctuations amounting to the melting of a colloidal glass. Increasing the strength of the attractions the system freezes into another nonergodic state sharing some qualitative features with gel states occurring at lower colloid packing fractions. This reentrant glass transition is in qualitative agreement with recent theoretical predictions.Comment: 14 pages, 3 figure

Universal and non-universal features of glassy relaxation in propylene carbonate

It is demonstrated that the susceptibility spectra of supercooled propylene carbonate as measured by depolarized-light-scattering, dielectric-loss, and incoherent quasi-elastic neutron-scattering spectroscopy within the GHz window are simultaneously described by the solutions of a two-component schematic model of the mode-coupling theory (MCT) for the evolution of glassy dynamics. It is shown that the universal beta-relaxation-scaling laws, dealing with the asymptotic behavior of the MCT solutions, describe the qualitative features of the calculated spectra. But the non-universal corrections to the scaling laws render it impossible to achieve a complete quantitative description using only the leading-order-asymptotic results.Comment: 37 pages, 16 figures, to be published in Phys. Rev.

The mean-squared displacement of a molecule moving in a glassy system

The mean-squared displacement (MSD) of a hard sphere and of a dumbbell molecule consisting of two fused hard spheres immersed in a dense hard-sphere system is calculated within the mode-coupling theory for ideal liquid-glass transitions. It is proven that the velocity correlator, which is the second time derivative of the MSD, is the negative of a completely monotone function for times within the structural-relaxation regime. The MSD is found to exhibit a large time interval for structural relaxation prior to the onset of the $\alpha$-process which cannot be described by the asymptotic formulas for the mode-coupling-theory-bifurcation dynamics. The $\alpha$-process for molecules with a large elongation is shown to exhibit an anomalously wide cross-over interval between the end of the von-Schweidler decay and the beginning of normal diffusion. The diffusivity of the molecule is predicted to vary non-monotonically as function of its elongation.Comment: 18 pages, 12 figures, Phys. Rev. E, in prin

Structural Relaxation and Mode Coupling in a Simple Liquid: Depolarized Light Scattering in Benzene

We have measured depolarized light scattering in liquid benzene over the whole accessible temperature range and over four decades in frequency. Between 40 and 180 GHz we find a susceptibility peak due to structural relaxation. This peak shows stretching and time-temperature scaling as known from $\alpha$ relaxation in glass-forming materials. A simple mode-coupling model provides consistent fits of the entire data set. We conclude that structural relaxation in simple liquids and $\alpha$ relaxation in glass-forming materials are physically the same. A deeper understanding of simple liquids is reached by applying concepts that were originally developed in the context of glass-transition research.Comment: submitted to New J. Phy

An exactly solvable toy model that mimics the mode coupling theory of supercooled liquid and glass transition

A toy model is proposed which incorporates the reversible mode coupling mechanism responsible for ergodic-nonergodic transition with trivial Hamiltonian in the mode coupling theory (MCT) of structural glass transition. The model can be analyzed without relying on uncontrolled approximations inevitable in the current MCT. The strength of hopping processes can be easily tuned and the ideal glass transition is reproduced only in a certain range of the strength. On the basis of the analyses of our model we discuss about a sharp ergodic-nonergodic transition and its smearing out by "hopping".Comment: 5 pages, 2 ps-figures, inappropriate terms replace

Glassy dynamics in monodisperse hard ellipsoids

We present evidence from computer simulations for glassy dynamics in suspensions of monodisperse hard ellipsoids. In equilibrium, almost spherical ellipsoids show a first order transition from an isotropic phase to a rotator phase. When overcompressing the isotropic phase into the rotator regime, we observe super-Arrhenius slowing down of diffusion and relaxation, accompanied by two-step relaxation in positional and orientational correlators. The effects are strong enough for asymptotic laws of mode-coupling theory to apply. Glassy dynamics are unusual in monodisperse systems. Typically, polydispersity in size or a mixture of particle species is prerequisite to prevent crystallization. Here, we show that a slight particle anisometry acts as a sufficient source of disorder. This sheds new light on the question of which ingredients are required for glass formation.Comment: included data of prolate system in all figures and text, extended discussion of indicators of glassy dynamics, fixed symbol ambiguities, preprint forma

Localization of passive UHF RFID Labels with Kalman Filter

Localization via Radio Frequency Identification (RFID) is frequently used in different applications nowadays. It has the advantage that next to its ostensible purpose of identifying objects via their unique IDs it can simultaneously be used for the localization of these objects. In this work it is shown how Received Signal Strength Indicator (RSSI) measurements at different antennae of a passive UHF RFID label can be combined for localization. The localization is only done based on the RSSI measurements and a Kalman Filter (KF). Because of non-linearities in the measurement function it is necessary to incorporate an Extended Kalman Filter (EKF) or an Unscented Kalman Filter (UKF) where simulations have shown that the UKF performs better than the EKF. Additionally to the selection of the filter there are different possibilities to increase the localization accuracy of the UKF: The advantages of using Reference Tags (RT) or more than one tag per trolley (relative positioning) in combination with an Unscented Kalman Filter are discussed and simulations results show that the localization error can be decreased significantly via these methods. Another possibility to increase the localization accuracy and in addition to achieve a more realistic simulation is the consideration of the angle between reader antenna and tag. Simulation results with the incorporation of different numbers of fixed antennae lead to the conclusion that this is a useful surplus in the localization