99 research outputs found
Reaction of Diphenyldiazomethane with Phosphorus Monothioacids
The mechanism of the reaction of phosphorus monothioacids
with diaryldiazomethanes was studied in different solvent systems
at 20 °c. The thiolo to thiono product ratios were determined by
1H NMR spectroscopy and g.l.c. of the reaction mixtures. The
results imply that the reaction involves two competing processes
leading to the corresponding S- and 0-isomeric esters
MASSENSPEKTROMETRISCHE UNTERSUCHUNGEN AN ORGANOPHOSPHORVERBINDUNGEN VI. ÜBER DIE MASSENSPEKTROMETRIE VON DIETHYLTHIOPHOSPHINSÄUREALKYLESTERN UND DIE MASSENSPEKTROMETRISCHE UNTERSCHEIDUNG IHRER O, S
Reactions of monothio, monoseleno, and selenothio acids of phosphorus with aliphatic diazo compounds
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