10 research outputs found
Experimental electronic heat capacities of and Plutonium; heavy-fermion physics in an element
We have measured the heat capacities of PuAl and
Pu over the temperature range 2-303 K. The availability of data below
10 K plus an estimate of the phonon contribution to the heat capacity based on
recent neutron-scattering experiments on the same sample enable us to make a
reliable deduction of the electronic contribution to the heat capacity of
PuAl; we find
mJKmol as . This is a factor larger than that
of any element, and large enough for PuAl to be
classed as a heavy-fermion system. By contrast,
mJKmol in Pu. Two distinct anomalies are seen in the
electronic contribution to the heat capacity of
PuAl, one or both of which may be associated with
the formation of the martensitic phase. We suggest that the large
-value of PuAl may be caused by proximity to
a quantum-critical point.Comment: 4 pages, 4 figure
THE DENSITY OF LIQUID PLUTONIUM METAL
Measurements were made of the product of surface tension (ϒ) and the contact angle (θ) of liquid plutonium vs solid tantalum and of the density of liquid plutonium (p) as functions of temperature between 655 and 960°C. The following values were obtained: ϒ cos θ = 1030 - (0.967)T d/cm and p = [17.56 - (1.45 x 10)T] ± 0.021 g/cm. A single determination was also made of the liquid density of a plutonium-7.93 atomic percent iron alloy and he following value obtained: p = [16.88 - (1.36)T] ± 0.012 g/cm
Strong electron-phonon coupling in delta-phase stabilized Pu
Heat capacity measurements of the delta-phase stabilized alloy Pu-Al suggest
that strong electron-phonon coupling is required to explain the moderate
renormalization of the electronic density of states near the Fermi energy. We
calculate the heat capacity contributions from the lattice and electronic
degrees of freedom as well as from the electron-lattice coupling term and find
good overall agreement between experiment and theory assuming a dimensionless
electron-phonon coupling parameter of order unity, lambda ~ 0.8. This large
electron-phonon coupling parameter is comparable to reported values in other
superconducting metals with face-centered cubic crystal structure, for example,
Pd (lambda ~ 0.7) and Pb (lambda ~ 1.5). Further, our analysis shows evidence
of a sizable residual low-temperature entropy contribution, S_{res} ~ 0.4 k_B
(per atom). We can fit the residual specific heat to a two-level system.
Therefore, we speculate that the observed residual entropy originates from
crystal-electric field effects of the Pu atoms or from self-irradiation induced
defects frozen in at low temperatures.Comment: 9 pages, 11 figures, to appear in Phys. Rev.