Thermodynamic Irreversibility from high-dimensional Hamiltonian Chaos

This paper discusses the thermodynamic irreversibility realized in high-dimensional Hamiltonian systems with a time-dependent parameter. A new quantity, the irreversible information loss, is defined from the Lyapunov analysis so as to characterize the thermodynamic irreversibility. It is proved that this new quantity satisfies an inequality associated with the second law of thermodynamics. Based on the assumption that these systems possess the mixing property and certain large deviation properties in the thermodynamic limit, it is argued reasonably that the most probable value of the irreversible information loss is equal to the change of the Boltzmann entropy in statistical mechanics, and that it is always a non-negative value. The consistency of our argument is confirmed by numerical experiments with the aid of the definition of a quantity we refer to as the excess information loss.Comment: LaTeX 43 pages (using ptptex macros) with 11 figure

The law of action and reaction for the effective force in a nonequilibrium colloidal system

We study a nonequilibrium Langevin many-body system containing two 'test' particles and many 'background' particles. The test particles are spatially confined by a harmonic potential, and the background particles are driven by an external driving force. Employing numerical simulations of the model, we formulate an effective description of the two test particles in a nonequilibrium steady state. In particular, we investigate several different definitions of the effective force acting between the test particles. We find that the law of action and reaction does not hold for the total mechanical force exerted by the background particles, but that it does hold for the thermodynamic force defined operationally on the basis of an idea used to extend the first law of thermodynamics to nonequilibrium steady states.Comment: 13 page

Slow decay of dynamical correlation functions for nonequilibrium quantum states

A property of dynamical correlation functions for nonequilibrium states is discussed. We consider arbitrary dimensional quantum spin systems with local interaction and translationally invariant states with nonvanishing current over them. A correlation function between local charge and local Hamiltonian at different spacetime points is shown to exhibit slow decay.Comment: typos correcte

Exact transformation of a Langevin equation to a fluctuating response equation

We demonstrate that a Langevin equation that describes the motion of a Brownian particle under non-equilibrium conditions can be exactly transformed to a special equation that explicitly exhibits the response of the velocity to a time dependent perturbation. This transformation is constructed on the basis of an operator formulation originally used in nonlinear perturbation theory for differential equations by extending it to stochastic analysis. We find that the obtained expression is useful for the calculation of fundamental quantities of the system, and that it provides a physical basis for the decomposition of the forces in the Langevin description into effective driving, dissipative, and random forces in a large-scale description.Comment: 14 pages, to appear in J. Phys. A: Math. Ge