59 research outputs found

    Structural properties in Sr0.61a0.39Nb2O6 in the temperature range 10 K to 500 K investigated by high-resolution neutron powder diffraction and specific heat measurements

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    We report high-resolution neutron powder diffraction on Sr0.61Ba0.39Nb2O6, SBN61, in the temperature range 15-500 K. The results indicate that the low-temperature anomalies (T<100K) observed in the dielectric dispersion are due to small changes in the incommensurate modulation of the NbO6-octahedra, as no structural phase transition of the average structure was observed. This interpretation is supported by specific heat measurements, which show no latent heat, but a glass-like behavior at low temperatures. Furthermore we find that the structural changes connected with the ferroelectric phase transition at Tc approx. 350K start already at 200K, explaining the anisotropic thermal expansion in the temperature range 200-300K observed in a recent x-ray diffraction study.Comment: Accepted by PRB (2006

    Reducing the positional modulation of NbO6-octahedra in SrxBa1-xNb2O6 by increasing the Barium content: A single crystal neutron diffraction study at ambient temperature for x=0.61 and x=0.34

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    We report on the influence of the Barium content on the modulation amplitude in SrxBa1-xNb2O6 compounds by comparing Sr0.61Ba0.39Nb2O6 (SBN61) and Sr0.34Ba0.66Nb2O6 (SBN34). Our single crystal neutron diffraction results demonstrate that the amplitude of the positional modulation of the NbO6 octahedra is reduced with increasing barium content, indicating that the origin of the modulation is the partial occupation of the pentagonal channels by Sr and Ba atoms. By increasing the Sr content the bigger Ba atoms are replaced by the smaller Sr atoms, which leads to a larger deformation of the surrounding lattice and hence to a larger modulation amplitude. The more homogeneous the filling of these channels with one atomic type (Ba) the lower the modulation amplitude. Our results also show that the structure can be described with a two-dimensional incommensurate harmonic modulation. No second order modulation has been observed, both by single crystal diffraction measurements and q-scans. The positional modulation of the Nb atoms is much smaller than that of the oxygen atoms, such that the modulation can be seen as a rotational modulation of almost rigid NbO6-octahedra

    CLINICAL CASE OF COMBINATION OF NON-COMPACT MYOCARDIUM OF THE LEFT VENTRICLE WITH CONGENITAL ANOMALY OF THE CORONARY ARTERIES

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    Non-compact myocardium of the left ventricle is one of the rare primary cardiomyopathies, which is characterized by impaired endomyocardial morphogenesis, left ventricular hypertrophy, its excessive trabeculation and the formation of wide interstitial spaces. The unfavorable prognosis and high mortality in the syndrome of myocardial non-compactness determine the necessity for its recognition in the early stages and a differentiated approach to treatment. In the article, we give an example of clinical observation of a patient with non-compact myocardium of the left ventricle and a congenital anomaly of the coronary arteries, hospitalized to the healthcare institution «Grodno Regional Clinical Cardiology Center» in 2018. The patient was conducted a number of diagnostic methods for verification of the diagnosis
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