Making the case for an International Decade of Radiocarbon

Radiocarbon (14C) is a critical tool for understanding the global carbon cycle. During the Anthropocene, two new processes influenced 14C in atmospheric, land and ocean carbon reservoirs. First, 14C-free carbon derived from fossil fuel burning has diluted 14C, at rates that have accelerated with time. Second, 'bomb' 14C produced by atmospheric nuclear weapon tests in the mid-twentieth century provided a global isotope tracer that is used to constrain rates of air-sea gas exchange, carbon turnover, large-scale atmospheric and ocean transport, and other key C cycle processes. As we write, the 14C/12C ratio of atmospheric CO2 is dropping below pre-industrial levels, and the rate of decline in the future will depend on global fossil fuel use and net exchange of bomb 14C between the atmosphere, ocean and land. This milestone coincides with a rapid increase in 14C measurement capacity worldwide. Leveraging future 14C measurements to understand processes and test models requires coordinated international effort-a 'decade of radiocarbon' with multiple goals: (i) filling observational gaps using archives, (ii) building and sustaining observation networks to increase measurement density across carbon reservoirs, (iii) developing databases, synthesis and modelling tools and (iv) establishing metrics for identifying and verifying changes in carbon sources and sinks. This article is part of the Theo Murphy meeting issue 'Radiocarbon in the Anthropocene'

From the HINDAS Project : Excitation Functions for Residual Nuclide Production by Proton-Induced Reactions

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Quality dating: a well-defined protocol implemented at ETH for high-precision 14c-dates tested on late glacial wood

Advances in accelerator mass spectrometry have resulted in an unprecedented amount of new high-precision radiocarbon (14C) -dates, some of which will redefine the international 14C calibration curves (IntCal and SHCal). Often these datasets are unaccompanied by detailed quality insurances in place at the laboratory, questioning whether the 14C structure is real, a result of a laboratory variation or measurement-scatter. A handful of intercomparison studies attempt to elucidate laboratory offsets but may fail to identify measurement-scatter and are often financially constrained. Here we introduce a protocol, called Quality Dating, implemented at ETH-Zürich to ensure reproducible and accurate high-precision 14C-dates. The protocol highlights the importance of the continuous measurements and evaluation of blanks, standards, references and replicates. This protocol is tested on an absolutely dated German Late Glacial tree-ring chronology, part of which is intercompared with the Curt Engelhorn-Center for Archaeometry, Mannheim, Germany (CEZA). The combined dataset contains 170 highly resolved, highly precise 14C-dates that supplement three decadal dates spanning 280 cal. years in IntCal, and provides detailed 14C structure for this interval

Tree-Rings Reveal Two Strong Solar Proton Events in 7176 and 5259 BCE

The Sun sporadically produces eruptive events leading to intense fluxes of solar energetic particles (SEPs) that dramatically disrupt the near-Earth radiation environment. Such events have been directly studied for the last decades but little is known about the occurrence and magnitude of rare, extreme SEP events. Presently, a few events that produced measurable signals in cosmogenic radionuclides such as 14C, 10Be and 36Cl have been found. Analyzing annual 14C concentrations in tree-rings from Switzerland, Germany, Ireland, Russia, and the USA we discovered two spikes in atmospheric 14C occurring in 7176 and 5259 BCE. The ~2% increases of atmospheric 14C recorded for both events exceed all previously known 14C peaks but after correction for the geomagnetic field, they are comparable to the largest event of this type discovered so far at 775 CE. These strong events serve as accurate time markers for the synchronization with floating tree-ring and ice core records and provide critical information on the previous occurrence of extreme solar events which may threaten modern infrastructure. © 2022, The Author(s).The Laboratory of Ion Beam Physics is partially funded by its consortium partners PSI, EAWAG, and EMPA. N.B. is funded by the Swiss National Science Foundation (SNSF grant #SNF 197137). The establishment of the BRAMS Facility was jointly funded by the NERC, BBSRC and the University of Bristol and the measurements in this work were partly funded by an ERC Proof of Concept grant awarded to R.P.E. and financing E.C. postdoctoral contract (LipDat H2020 ERC-2018-PoC/812917). We thank Bisserka Gaydarska for sub-sampling the inter-laboratory replicates from M49, M234, Q2729 and Q2750, Cathy Tyers for reviewing the dating of the Irish and German samples, and Alexander Land for assistance in dating sample M49. P.F. received funding from the SNF Sinergia project CALDERA (no. 183571). R.H. is funded by Russian Science Foundation (grant № 21-14-00330). I.U. acknowledges the support from the Academy of Finland (grant 321882 ESPERA). C.L.P.’s and M.W.S.’s work on bristlecone pine was funded by the M.H. Wiener Foundation (ICCP Project). K.N. acknowledges the support provided by the Austrian Science Fund FWF (grant I-1183-N19)

Tree rings reveal globally coherent signature of cosmogenic radiocarbon events in 774 and 993 CE

This study was funded by the WSL-internal COSMIC project (5233.00148.001.01), the ETHZ (Laboratory of Ion Beam Physics), the Swiss National Science Foundation (SNF Grant 200021L_157187/1), and as the Czech Republic Grant Agency project no. 17-22102s.Though tree-ring chronologies are annually resolved, their dating has never been independently validated at the global scale. Moreover, it is unknown if atmospheric radiocarbon enrichment events of cosmogenic origin leave spatiotemporally consistent fingerprints. Here we measure the 14C content in 484 individual tree rings formed in the periods 770–780 and 990–1000 CE. Distinct 14C excursions starting in the boreal summer of 774 and the boreal spring of 993 ensure the precise dating of 44 tree-ring records from five continents. We also identify a meridional decline of 11-year mean atmospheric radiocarbon concentrations across both hemispheres. Corroborated by historical eye-witness accounts of red auroras, our results suggest a global exposure to strong solar proton radiation. To improve understanding of the return frequency and intensity of past cosmic events, which is particularly important for assessing the potential threat of space weather on our society, further annually resolved 14C measurements are needed.Publisher PDFPeer reviewe

The relevance of ion optics for the development of small AMS facilities

An ion optics program is presented, which addresses some of the specific problems of accelerator mass spectrometry (AMS). Ion beams having a phase space with angular distributions based on small angle scattering and with energy distributions caused by the straggling in foils or stripper gas can be included in transmission calculations. As an example, a new design for 10Be measurements with the 600 kV AMS system at ETH Zurich including a silicon nitride degrader foil is discussed, which will allow competitive measurements of this cosmogenic radionuclide at low energies. This system should also improve background suppression for other AMS nuclides. © 2009 Elsevier B.V.This work was supported by the Swiss National Science Foundation.Peer Reviewe

Online radiocarbon measurements of small samples using Elemental Analyzer and MICADAS gas ion source

An on-line measurement system was installed at the MICADAS in Zurich, using an elemental analyzer (EA) as a combustion unit to enable direct radiocarbon measurement of samples containing carbon in the range of 5-100 g possible with minimum effort. The samples are combusted in small capsules and the gaseous combustion products are separated by the EA. The carbon dioxide leaving the EA in a high helium flow is concentrated on a small external trap containing X13 zeolite adsorber material. This new concept, avoiding a cryogenic trapping for the enrichment step, allows the construction of a very compact system able to work even with the smallest samples. Concentrated on the external trap, the carbon dioxide is flushed into the gas-tight syringe of our gas inlet system using a low helium stream. The gas mixture is measured with the MICADAS gas ion source. Several different sample capsules were analyzed to minimize the major blank contribution coming from the sample vessel. The best results were achieved with 25-L tin capsules, which contained only 0.34 0.13 g carbon at 65 pMC. This work describes the development of the on-line system and the protocol for measurement runs. Results are presented for on-line measurements of reference materials and a comparison is performed with typical dating samples measured previously as graphite targets. Finally, relevance and limitations of on-line measurements are discussed.The Radiocarbon archives are made available by Radiocarbon and the University of Arizona Libraries. Contact [email protected] for further information.Migrated from OJS platform February 202