The light-oxygen effect in biological cells enhanced by highly localized surface plasmon-polaritons

Here at the first time we suggested that the surface plasmon-polariton phenomenon which it is well described in metallic nanostructures could also be used for explanation of the unexpectedly strong oxidative effects of the low-intensity laser irradiation in living matters (cells, tissues, organism). We demonstrated that the narrow-band laser emitting at 1265 nm could generate significant amount of the reactive oxygen species (ROS) in both HCT116 and CHO-K1 cell cultures. Such cellular ROS effects could be explained through the generation of highly localized plasmon-polaritons on the surface of mitochondrial crista. Our experimental conditions, the low-intensity irradiation, the narrow spectrum band (<4 nm) of the laser and comparably small size bio-structures (~10 μm) were shown to be sufficient for the plasmon-polariton generation and strong laser field confinement enabling the oxidative stress observed

Nucleation Controlled by Non-Fickian Fractional Diffusion

Kinetic models of aggregation and dissolution of clusters in disordered heterogeneous materials based on subdiffusive equations containing fractional derivatives are studied. Using the generalized fractional Fick law and fractional Fokker–Planck equation for impurity diffusion with localization, we consider modifications of the classical models of Ham, Aaron–Kotler, and Lifshitz–Slezov for nucleation and decomposition of solid solutions. The asymptotic time dependencies of supersaturation degree, average cluster size, and other characteristics at the stages of subdiffusion-limited nucleation and coalescence are calculated and analyzed

Fractional Derivative Phenomenology of Percolative Phonon-Assisted Hopping in Two-Dimensional Disordered Systems

Anomalous advection-diffusion in two-dimensional semiconductor systems with coexisting energetic and structural disorder is described in the framework of a generalized model of multiple trapping on a comb-like structure. The basic equations of the model contain fractional-order derivatives. To validate the model, we compare analytical solutions with results of a Monte Carlo simulation of phonon-assisted tunneling in two-dimensional patterns of a porous nanoparticle agglomerate and a phase-separated bulk heterojunction. To elucidate the role of directed percolation, we calculate transient current curves of the time-of-flight experiment and the evolution of the mean squared displacement averaged over medium realizations. The variations of the anomalous advection-diffusion parameters as functions of electric field intensity, levels of energetic, and structural disorder are presented

Memory Effect and Fractional Differential Dynamics in Planar Microsupercapacitors Based on Multiwalled Carbon Nanotube Arrays

The development of portable electronic devices has greatly stimulated the need for miniaturized power sources. Planar supercapacitors are micro-scale electrochemical energy storage devices that can be integrated with other microelectronic devices on a chip. In this paper, we study the behavior of microsupercapacitors with in-plane interdigital electrodes of carbon nanotube array under sinusoidal excitation, step voltage input and sawlike voltage input. Considering the anomalous diffusion of ions in the array and interelectrode space, we propose a fractional-order equivalent circuit model that successfully describes the measured impedance spectra. We demonstrate that the response of the investigated micro-supercapacitors is linear and the system is time-invariant. The numerical inversion of the Laplace transforms for electric current response in an equivalent circuit with a given impedance leads to results consistent with potentiostatic measurements and cyclic voltammograms. The use of electrodes based on an ordered array of nanotubes reduces the role of nonlinear effects in the behavior of a supercapacitor. The effect of the disordering of nanotubes with increasing array height on supercapacitor impedance is considered in the framework of a distributed-order subdiffusion model

Resonant amplification of surface plasmon polaritons with an electric current in a single-walled carbon nanotube lying on a spatially modulated substrate

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Fractional Differential Generalization of the Single Particle Model of a Lithium-Ion Cell

The effect of anomalous diffusion of lithium on the discharge curves and impedance spectra of lithium-ion batteries (LIB) is studied within the fractional differential generalization of the single-particle model. The distribution of lithium ions in electrolyte and electrode particles is expressed through the Mittag&ndash;Leffler function and the L&eacute;vy stable density. Using the new model, we generalize the equivalent circuit of LIB. The slope of the low-frequency rectilinear part of the Nyquist diagram does not always unambiguously determine the subdiffusion index and can be either larger or smaller than the slope corresponding to normal diffusion. The new aspect of capacity degradation related to a change in the type of ion diffusion in LIB components is discussed

Investigation of Side Wall Roughness Effect on Optical Losses in a Multimode Si3N4 Waveguide Formed on a Quartz Substrate

This article presents the results of the study of the influence of the most significant parameters of the side wall roughness of an ultra-thin silicon nitride lightguide layer of multimode integrated optical waveguides with widths of 3 and 8 microns. The choice of the waveguide width was made due to the need to provide multimode operation for telecommunication wavelengths, which is necessary to ensure high integration density. Scattering in waveguide structures was measured by optical frequency domain reflectometry (OFDR) of a backscattering reflectometer. The finite difference time domain method (FDTD) was used to study the effect of roughness parameters on optical losses in fabricated waveguides, the roughness parameters that most strongly affect optical scattering were determined, and methods of its significant reduction were specified. The prospects for implementing such structures on a quartz substrate are justified

Amplification and Generation of Frequency-Modulated Soliton Pulses in Nonuniform Active Fiber Configurations

We report on the theoretical and numerical analysis of the nonlinear Schr&ouml;dinger equation describing the dynamical evolution of frequency-modulated (FM) optical signals propagating through the fiber configuration comprising active fibers with the anomalous dispersion nonuniformly distributed over the fiber length. In our consideration, a single active fiber section including segments with initially increasing and then decreasing dispersion is used for amplification and compression of an external FM pulse resulting in an increase of ~6 orders of magnitude in the pulse peak power and a 100-fold narrowing of the pulse duration down to a few picoseconds. Moreover, we demonstrate that, with a ~1 mW weakly modulated continuous wave input signal, the fiber configuration comprising two active fiber sections with different dispersion profiles is able to generate a strongly periodic pulse train, resulting in a pulse repetition rate &gt;100 GHz, a pulse duration ~0.5 ps, and peak power up to ~1 kW. An evolution of optical signals governed by modulation instability in both fiber configurations is explored

Influence of the Surface Roughness of a Silicon Disk Resonator on Its Q-Factor

This article presents a silicon disk resonator of the whispering-gallery-mode (WGM) type. The calculated Q-factor of the silicon WGM resonator was 107. Two methods of studying the surface roughness of a silicon WGM resonator with a nonlinear profile by means of Helios 650 scanning electron microscope and Bruker atomic force microscope (AFM) are presented. The results obtained by the two methods agreed well with each other. A comparison of the surface roughness values of WGM resonators manufactured using different technological approaches is presented. Based on the obtained data, a preliminary estimated Q-factor calculation of the resonators was performed, which was refined by numerical calculation using the finite-difference time-domain (FDTD) method. The effect of the surface roughness of the resonator on its Q-factor was found. Reducing the surface roughness of the resonator from 30 nm to 1–2 nm led to an increase in its Q-factor from 104 to 107