Shock metamorphism of the Coconino Sandstone at Meteor Crater, Arizona

A study of the shocked Coconino sandstone from Meteor Crater, Arizona, was undertaken to examine the role of porosity in the compression of rocks and in the formation of highpressure phases. A suite of shocked Coconino specimens collected at the crater is divided into five classes, arranged in order of decreasing quartz content. The amounts of coesite, stishovite (measured by quantitative X‐ray diffraction), and glass vary systematically with decreasing quartz content. Coesite may comprise 1/3 by weight of some rocks, whereas the stishovite content does not exceed 1%. The five classes of rocks have distinct petrographic properties, correlated with the presence of regions containing coesite, stishovite, or fused silica. Very few occurrences of diaplectic glass are observed. In the lowest stages of shock metamorphism (class 1), the quartz grains are fractured, and the voids in the rock are filled with myriads of small chips derived from neighboring grains. The fracture patterns in the individual quartz grains are controlled by the details of the initial morphology of the colliding grains. In one weakly shocked rock, it was possible to map the general direction of shock passage by recording the apparent direction of collision of individual grains. The principal mechanism of energy deposition by a shock wave in a porous material is the reverberation of shock and rarefaction waves through grains due to collisions with other grains. A one‐dimensional model of the impact process can predict the average pressure, volume, and temperature of the rock if no phase changes occur but cannot predict the observed nonuniformity of energy deposition. In all rocks shocked to higher pressure than was necessary to close the voids, high‐pressure and/or high‐temperature phases are present. Locally high pressures enduring for microseconds and high temperatures enduring for milliseconds controlled the phases of SiO_2 that formed in the rock. Collapsing pore walls became local hot spots into which initial deposition of energy was focused. Microcrystalline coesite in class 2 rocks occurs in symplektic regions on quartz grain boundaries that were regions of initial stress and energy concentration, or in sheared zones within the grains. The occurrence and morphology of the coesite‐rich regions can be explained only if the transformation from quartz to coesite proceeds slowly in the shock wave. In class 3 rocks, microcrystalline coesite occurs in opaque regions that surround nearly isotropic cores of cryptocrystalline coesite. The cores are interpreted to be the products of the inversion of stishovite (or a glass with Si in sixfold coordination) that initially formed in the shock front in regions of grains shocked to pressures near 300 kb. Stishovite is preserved only in the opaque regions, which are believed to have been cooler than the cores. In class 4 rocks vesicular glass occurs in core regions surrounded by opaque regions containing coesite. The relation of the glass to the coesite and quartz suggests that the glass was formed by inversion of stishovite formed above 350 kb on release to lower pressure. Class 5 rocks are composed almost entirely of glass, with vesicles uniformly distributed in the glass. These vesicles were probably formed by exsolution of water that had been dissolved in melted SiO_2 during passage of the shock

Laboratory studies of volcanic jets

The study of the fluid dynamics of violent volcanic eruptions by laboratory experiment is described, and the important fluid-dynamic processes that can be examined in laboratory models are discussed in detail. In preliminary experiments, pure gases are erupted from small reservoirs. The gases used are Freon 12 and Freon 22, two gases of high molecular weight and high density that are good analogs of heavy and particulate-laden volcanic gases; nitrogen, a moderate molecular weight, moderate density gas for which the thermodynamic properties are well known; and helium, a low molecular weight, lowdensity gas that is used as a basis for comparison with the behavior of the heavier gases and as an analog of steam, the gas that dominates many volcanic eruptions. Transient jets erupt from the reservoir into the laboratory upon rupture of a thin diaphragm at the exit of a convergent nozzle. The gas accelerates from rest in the reservoir to high velocity in the jet. Reservoir pressures and geometries are such that the fluid velocity in the jets is initially supersonic and later decays to subsonic. The measured reservoir pressure decreases as the fluid expands through repetitively reflecting rarefaction waves, but for the conditions of these experiments, a simple steady-discharge model is sufficient to explain the pressure decay and to predict the duration of the flow. Density variations in the flow field have been visualized with schlieren and shadowgraph photography. The observed structure of the jet is correlated with the measured pressure history. The starting vortex generated when the diaphragm ruptures becomes the head of the jet. Though the exit velocity is sonic, the flow head in the helium jet decelerates to about one-third of sonic velocity in the first few nozzle diameters, the nitrogen head decelerates to about three-fourths of sonic velocity, while Freon maintains nearly sonic velocity. The impulsive acceleration of reservoir fluid into the surrounding atmosphere produces a compression wave. The strength of this wave depends primarily on the sound speed of the fluid in the reservoir but also, secondarily with opposite effect, on the density: helium produces a relatively strong atmospheric shock while the Freons do not produce any optically observable wave front. Well-formed N waves are detected with a microphone far from the reservoir. Barrel shocks, Mach disks, and other familiar features of steady underexpanded supersonic jets form inside the jet almost immediately after passage of the flow head. These features are maintained until the pressure in the reservoir decays to sonic conditions. At low pressures the jets are relatively structureless. Gas-particle jets from volcanic eruptions may behave as pseudogases if particle concentrations and mass and momentum exchange between the components are sufficiently small. The sound speed of volcanic pseudogases can be as large as 1000 m s^(−1) or as small as a few tens of meters per second depending on the mass loading and initial temperature. Fluids of high sound speed produce stronger atmospheric shock waves than do those of low sound speed. Therefore eruption of a hot gas lightly laden with particulates should produce a stronger shock than eruption of a cooler or heavily laden fluid. An empirical expression suggests that the initial velocity of the head of supersonic volcanic jets is controlled by the sound speed and the ratio of the density of the erupting fluid to that of the atmosphere. The duration of gas or pseudogas eruptions is controlled by the sound speed of the fluid and the ratio of reservoir volume to vent area

Erosional furrows formed during the lateral blast at Mount St. Helens, May 18, 1980

Nearly horizontal, quasi-periodic erosional features of 7-m average transverse wavelength and of order 100-m length occur in scattered locations from 3.5 to 9 km from the crater at Mount St. Helens under deposits of the lateral blast of May 18, 1980. We attribute the erosional features to scouring by longitudinal vortices resulting from flow instabilities induced by complex topography, namely, by streamline curvature in regions of reattachment downstream of sheltered regions, and by the cross-flow component of flow subparallel to ridge crests. The diameter of the vortices and their transverse spacing, inferred from the distance between furrows, are taken to be of the order of the boundary layer thickness. The inferred boundary layer thickness (≈14 m at 9 km from the source of the blast) is consistent with the running length from the mountain to the furrow locations. By using knowledge of ablation patterns on bodies and lofting of dust in high-speed flow, we are able to infer some features of the flow field within the blast. Within the furrows the erosion rate was of the order of 9 kg m^(−2) s^(−1), about 4 times greater than that expected from laboratory data obtained in flow free of longitudinal vortices. The orientation of furrows induced by the cross-flow instability can be used to measure the upwash angle and estimate the flow Mach number: at the central ridge of Spirit Lake the Mach number is inferred to have been about 2.5, and the flow velocity approximately 235 m/s. The similarities and differences between the furrows reported here and channels observed at other volcanoes are discussed

Shock metamorphism of the Coconino Sandstone at Meteor Crater, Arizona

A study of the shocked Coconino sandstone from Meteor Crater, Arizona, was undertaken to examine the role of porosity in the compression of rocks and in the formation of highpressure phases. A suite of shocked Coconino specimens collected at the crater is divided into five classes, arranged in order of decreasing quartz content. The amounts of coesite, stishovite (measured by quantitative X‐ray diffraction), and glass vary systematically with decreasing quartz content. Coesite may comprise 1/3 by weight of some rocks, whereas the stishovite content does not exceed 1%. The five classes of rocks have distinct petrographic properties, correlated with the presence of regions containing coesite, stishovite, or fused silica. Very few occurrences of diaplectic glass are observed. In the lowest stages of shock metamorphism (class 1), the quartz grains are fractured, and the voids in the rock are filled with myriads of small chips derived from neighboring grains. The fracture patterns in the individual quartz grains are controlled by the details of the initial morphology of the colliding grains. In one weakly shocked rock, it was possible to map the general direction of shock passage by recording the apparent direction of collision of individual grains. The principal mechanism of energy deposition by a shock wave in a porous material is the reverberation of shock and rarefaction waves through grains due to collisions with other grains. A one‐dimensional model of the impact process can predict the average pressure, volume, and temperature of the rock if no phase changes occur but cannot predict the observed nonuniformity of energy deposition. In all rocks shocked to higher pressure than was necessary to close the voids, high‐pressure and/or high‐temperature phases are present. Locally high pressures enduring for microseconds and high temperatures enduring for milliseconds controlled the phases of SiO_2 that formed in the rock. Collapsing pore walls became local hot spots into which initial deposition of energy was focused. Microcrystalline coesite in class 2 rocks occurs in symplektic regions on quartz grain boundaries that were regions of initial stress and energy concentration, or in sheared zones within the grains. The occurrence and morphology of the coesite‐rich regions can be explained only if the transformation from quartz to coesite proceeds slowly in the shock wave. In class 3 rocks, microcrystalline coesite occurs in opaque regions that surround nearly isotropic cores of cryptocrystalline coesite. The cores are interpreted to be the products of the inversion of stishovite (or a glass with Si in sixfold coordination) that initially formed in the shock front in regions of grains shocked to pressures near 300 kb. Stishovite is preserved only in the opaque regions, which are believed to have been cooler than the cores. In class 4 rocks vesicular glass occurs in core regions surrounded by opaque regions containing coesite. The relation of the glass to the coesite and quartz suggests that the glass was formed by inversion of stishovite formed above 350 kb on release to lower pressure. Class 5 rocks are composed almost entirely of glass, with vesicles uniformly distributed in the glass. These vesicles were probably formed by exsolution of water that had been dissolved in melted SiO_2 during passage of the shock