2,382 research outputs found
[4-(2-tert-Butoxy-2-oxoethoxy)naphthalen-1-yl]diphenylsulfonium trifluoromethanesulfonate
In the cation of the title salt, C28H27O3S+·CF3O3S−, the dihedral angle between the naphthalene ring system and the –C(=O)—O– plane is 80.39 (9)°. The three methyl groups of the tert-butyl group are each disordered over two orientations with an occupancy ratio of 0.712 (18):0.288 (18)
The Chevrel phase In4.07Mo15S11.87Se7.13 with mixed chalcogenide occupancy
The single-crystal of the title compound, indium pentadecamolybdenum nonadeca(sulfide/selenide), was obtained by solid state reaction with an S/Se mixture. It adopts the structure type of In3Mo15Se19 and In3.7Mo15S19, which are non-substituted Chevrel phases in the space group P63/m. The Mo, one S/Se and two In sites have point symmetry m.. and two S/Se and one In atoms are in 3.. sites. This compound contains isolated Mo6 and Mo9 clusters. The shapes of clusters are octahedral and confacial bioctahedral, respectively, face-capped by chalcogen atoms over each triangle face. The Mo—X bonds (X = S, Se) play an important role for the constitution of the framework. The Mo—X distances of 2.479 (2)–2.6687 (9) Å are within the ranges of average values of Mo—S and Mo—Se distances. The In atoms located on sites with m.. symmetry are partially occupied
5,5′-[1,4-Phenylenebis(methylenesulfanediyl)]bis[1,3,4-thiadiazol-2(3H)-one] dimethyl sulfoxide disolvate
The asymmetric unit of the title compound, C12H10N4O2S4·2C2H6OS, contains one half of the p-xylene molecule and one dimethyl sulfoxide molecule. The p-xylene molecule is located about a crystallographic inversion centre. In the molecule, the thiadiazole and benzene rings are almost perpendicular to one another, with a dihedral angle of 88.95 (6)°. In the crystal, an N—H⋯O hydrogen bond is observed between the two components. The dimethyl sulfoxide molecule is disordered over two orientations with an occupancy ratio of 0.879 (1):0.121 (1)
N-(2,5-Dimethoxyphenyl)-N′-(4-hydroxyphenethyl)urea
In the title compound, C17H20N2O4, the 2,5-dimethoxyphenyl unit is almost planar, with an r.m.s. deviation of 0.015 Å. The dihedral angle between the 2,5-dimethoxyphenyl ring and the urea plane is 20.95 (8)°. The H atoms of the urea NH groups are positioned syn to each other. The molecular structure is stabilized by a short intramolecular N—H⋯O hydrogen bond. In the crystal, intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules into a three-dimensional network
1-[3-(Hydroxymethyl)phenyl]-3-phenylurea
In the title compound, C14H14N2O2, the dihedral angle between the benzene rings is 23.6 (1)°. The H atoms of the urea NH groups are positioned syn to each other. In the crystal, intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules into a three-dimensional network
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