Flattened 1D fragments of fullerene C₆₀ that exhibit robustness toward multi-electron reduction

フラーレンに迫る電子受容能をもつ平坦な一次元π共役炭化水素の開発. 京都大学プレスリリース. 2023-05-15.Flat fullerene fragments attractive to electrons. 京都大学プレスリリース. 2023-06-01.Fullerenes are compelling molecular materials owing to their exceptional robustness toward multi-electron reduction. Although scientists have attempted to address this feature by synthesizing various fragment molecules, the origin of this electron affinity remains unclear. Several structural factors have been suggested, including high symmetry, pyramidalized carbon atoms, and five-membered ring substructures. To elucidate the role of the five-membered ring substructures without the influence of high symmetry and pyramidalized carbon atoms, we herein report the synthesis and electron-accepting properties of oligo(biindenylidene)s, a flattened one-dimensional fragment of fullerene C₆₀. Electrochemical studies corroborated that oligo(biindenylidene)s can accept electrons up to equal to the number of five-membered rings in their main chains. Moreover, ultraviolet/visible/near-infrared absorption spectroscopy revealed that oligo(biindenylidene)s exhibit enhanced absorption covering the entire visible region relative to C₆₀. These results highlight the significance of the pentagonal substructure for attaining stability toward multi-electron reduction and provide a strategy for the molecular design of electron-accepting π-conjugated hydrocarbons even without electron-withdrawing groups

Mitigating the impact of fiber assignment on clustering measurements from deep galaxy redshift surveys

We examine the impact of fiber assignment on clustering measurements from fiber-fed spectroscopic galaxy surveys. We identify new effects which were absent in previous, relatively shallow galaxy surveys such as Baryon Oscillation Spectroscopic Survey . Specifically, we consider deep surveys covering a wide redshift range from z=0.6 to z=2.4, as in the Subaru Prime Focus Spectrograph survey. Such surveys will have more target galaxies than we can place fibers on. This leads to two effects. First, it eliminates fluctuations with wavelengths longer than the size of the field of view, as the number of observed galaxies per field is nearly fixed to the number of available fibers. We find that we can recover the long-wavelength fluctuation by weighting galaxies in each field by the number of target galaxies. Second, it makes the preferential selection of galaxies in under-dense regions. We mitigate this effect by weighting galaxies using the so-called individual inverse probability. Correcting these two effects, we recover the underlying correlation function at better than 1 percent accuracy on scales greater than 10 Mpc/h.Comment: 17 pages, 11 figure

One-dimensional fragments of fullerene C60 that exhibit robustness toward multi-electron reduction and pronounced light absorption

Fullerenes are compelling molecular materials owing to their exceptional robustness toward multi-electron reduction. Although scientists have attempted to address this feature by synthesizing various fragment molecules, the origin of this electron affinity remains unclear. Several structural factors have been suggested, including high symmetry, curved structures, and five-membered ring substructures. To elucidate the role of the five-membered ring substructures without the influence of high symmetry and curved structure, we herein report the synthesis and electron-accepting properties of oligo(biindenylidene)s, a one-dimensional fragment of fullerene C60. Electrochemical studies corroborated that oligo(biindenylidene)s accept electrons equal to the number of five-membered rings in their main chains. Moreover, ultraviolet/visible/near-infrared absorption spectroscopy revealed that oligo(biindenylidene)s exhibit significantly enhanced absorption covering the entire visible region in relation to C60. These results highlight the significance of the pentagonal substructure for attaining stability toward multi-electron reduction and provide a new strategy for the molecular design of electron-accepting -conjugated hydrocarbons