3,288 research outputs found
Dynamics and correlation length scales of a glass-forming liquid in quiescent and sheared conditions
We numerically study dynamics and correlation length scales of a colloidal
liquid in both quiescent and sheared conditions to further understand the
origin of slow dynamics and dynamic heterogeneity in glass-forming systems. The
simulation is performed in a weakly frustrated two-dimensional liquid, where
locally preferred order is allowed to develop with increasing density. The
four-point density correlations and bond-orientation correlations, which have
been frequently used to capture dynamic and static length scales in a
quiescent condition, can be readily extended to a system under steady shear in
this case. In the absence of shear, we confirmed the previous findings that the
dynamic slowing down accompanies the development of dynamic heterogeneity. The
dynamic and static length scales increase with -relaxation time
as power-law with . In the
presence of shear, both viscosity and have power-law dependence
on shear rate in the marked shear thinning regime. However, dependence of
correlation lengths cannot be described by power laws in the same regime.
Furthermore, the relation between length scales
and dynamics holds for not too strong shear where thermal fluctuations and
external forces are both important in determining the properties of dense
liquids. Thus, our results demonstrate a link between slow dynamics and
structure in glass-forming liquids even under nonequilibrium conditions.Comment: 9 pages, 17 figures. Accepted by J. Phys.: Condens. Matte
Structure, compressibility factor and dynamics of highly size-asymmetric binary hard-disk liquids
By using event-driven molecular dynamics simulation, we investigate effects
of varying the area fraction of the smaller component on structure,
compressibility factor and dynamics of the highly size-asymmetric binary
hard-disk liquids. We find that the static pair correlations of the large disks
are only weakly perturbed by adding small disks. The higher-order static
correlations of the large disks, by contrast, can be strongly affected. The
compressibility factor of the system first decreases and then increases upon
increasing the area fraction of the small disks and separating different
contributions to it allows to rationalize this non-monotonic phenomenon.
Furthermore, adding small disks can influence dynamics of the system in
quantitative and qualitative ways. For the large disks, the structural
relaxation time increases monotonically with increasing the area fraction of
the small disks at low and moderate area fractions of the large disks. In
particular, "reentrant" behavior appears at sufficiently high area fractions of
the large disks, strongly resembling the reentrant glass transition in
short-ranged attractive colloids and the inverted glass transition in binary
hard spheres with large size disparity. By tuning the area fraction of the
small disks, relaxation process for the small disks shows concave-to-convex
crossover and logarithmic decay behavior, as found in other binary mixtures
with large size disparity. Moreover, diffusion of both species is suppressed by
adding small disks. Long-time diffusion for the small disks shows
power-law-like behavior at sufficiently high area fractions of the small disks,
which implies precursors of a glass transition for the large disks and a
localization transition for the small disks. Therefore, our results demonstrate
the generic dynamic features in highly size-asymmetric binary mixtures.Comment: 9 pages, 12 figure
Anticipating Daily Intention using On-Wrist Motion Triggered Sensing
Anticipating human intention by observing one's actions has many
applications. For instance, picking up a cellphone, then a charger (actions)
implies that one wants to charge the cellphone (intention). By anticipating the
intention, an intelligent system can guide the user to the closest power
outlet. We propose an on-wrist motion triggered sensing system for anticipating
daily intentions, where the on-wrist sensors help us to persistently observe
one's actions. The core of the system is a novel Recurrent Neural Network (RNN)
and Policy Network (PN), where the RNN encodes visual and motion observation to
anticipate intention, and the PN parsimoniously triggers the process of visual
observation to reduce computation requirement. We jointly trained the whole
network using policy gradient and cross-entropy loss. To evaluate, we collect
the first daily "intention" dataset consisting of 2379 videos with 34
intentions and 164 unique action sequences. Our method achieves 92.68%, 90.85%,
97.56% accuracy on three users while processing only 29% of the visual
observation on average
Diffusive redistribution of small spheres in crystallization of highly asymmetric binary hard-sphere mixtures
We report a molecular dynamics study of crystallization in highly asymmetric
binary hard-sphere mixtures, in which the large spheres can form a crystal
phase while the small ones remain disordered during the crystallization process
of the large spheres. By taking advantage of assisting crystal nucleation with
a patterned substrate, direct evidence is presented that there is a close link
between the diffusive redistribution of the small spheres and the crystal
formation of the large spheres. Although the addition of a second component
with large size disparity will not alter the crystal structure formed by the
large spheres, the density profile of the small spheres displays corresponding
changes at different crystallization stages and closely relates to the crystal
growth, suggesting possible effect of small spheres on the crystallization
kinetics.Comment: 5 pages, 5 figure
Redetermination of 2,4′-methylenediphenol
In the previous determination [Finn & Musti (1950 ▶). J. Soc. Chem. Ind. (London), 69, S849] of the title compound, C13H12O2, the three-dimensional coordinates and displacement parameters were not reported. This redetermination at room temperature reveals that the dihedral angle between the benzene rings is 79.73 (6)°. In the crystal, intermolecular O—H⋯O hydrogen bonds between adjacent molecules result in two-dimensional wave-like supramolecular motifs parallel to the ab plane
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