Microscopic Description of Band Structure at Very Extended Shapes in the A ~ 110 Mass Region

Recent experiments have confirmed the existence of rotational bands in the A \~ 110 mass region with very extended shapes lying between super- and hyper-deformation. Using the projected shell model, we make a first attempt to describe quantitatively such a band structure in 108Cd. Excellent agreement is achieved in the dynamic moment of inertia J(2) calculation. This allows us to suggest the spin values for the energy levels, which are experimentally unknown. It is found that at this large deformation, the sharply down-sloping orbitals in the proton i_{13/2} subshell are responsible for the irregularity in the experimental J(2), and the wave functions of the observed states have a dominant component of two-quasiparticles from these orbitals. Measurement of transition quadrupole moments and g-factors will test these findings, and thus can provide a deeper understanding of the band structure at very extended shapes.Comment: 4 pages, 3 eps figures, final version accepted by Phys. Rev. C as a Rapid Communicatio

Kinetics of dissociative chemisorption of methane and ethane on Pt(110)-(1X2)

The initial probability of dissociative chemisorption Pr of methane and ethane on the highly corrugated, reconstructed Pt(110)‐(1×2) surface has been measured in a microreactor by counting the number of carbon atoms on the surface following the reaction of methane and ethane on the surface which was held at various constant temperatures between 450 and 900 K during the reaction. Methane dissociatively chemisorbs on the Pt(110)‐(1×2) surface with an apparent activation energy of 14.4 kcal/mol and an apparent preexponential factor of 0.6. Ethane chemisorbs dissociatively with an apparent activation energy of 2.8 kcal/mol and an apparent preexponential factor of 4.7×10^(−3). Kinetic isotope effects were observed for both reactions. The fact that P_r is a strong function of surface temperature implies that the dissociation reactions proceed via a trapping‐mediated mechanism. A model based on a trapping‐mediated mechanism is used to explain the observed kinetic behavior. Kinetic parameters for C–H bond dissociation of the thermally accommodated methane and ethane are extracted from the model

Triaxial projected shell model approach

The projected shell model analysis is carried out using the triaxial Nilsson+BCS basis. It is demonstrated that, for an accurate description of the moments of inertia in the transitional region, it is necessary to take the triaxiality into account and perform the three-dimensional angular-momentum projection from the triaxial Nilsson+BCS intrinsic wavefunction.Comment: 9 pages, 2 figure

Isospin-symmetry breaking in superallowed Fermi beta-decay due to isospin-nonconserving forces

We investigate isospin-symmetry breaking effects in the sd-shell region with large-scale shell-model calculations, aiming to understand the recent anomalies observed in superallowed Fermi beta-decay. We begin with calculations of Coulomb displacement energies (CDE's) and triplet displacement energies (TDE's) by adding the T=1,J=0 isospin nonconserving (INC) interaction into the usual isospin-invariant Hamiltonian. It is found that CDE's and TDE's can be systematically described with high accuracy. A total number of 122 one- and two-proton separation energies are predicted accordingly, and locations of the proton drip-line and candidates for proton-emitters are thereby suggested. However, attempt to explain the anomalies in the superallowed Fermi beta-decay fails because these well-fitted T=1,J=0 INC interactions are found no effects on the nuclear matrix elements. It is demonstrated that the observed large isospin-breaking correction in the 32Cl beta-decay, the large isospin-mixing in the 31Cl beta-decay, and the small isospin-mixing in the 23Al beta-decay can be consistently understood by introducing additional T=1,J=2 INC interactions related to the s1/2 orbit.Comment: 7 pages, 3 figures, accepted in Phys. Lett.