2 research outputs found
TetraÂkis(4-aminoÂpyridine-κN 1)dichloridoÂcopper(II) monohydrate
The asymmetric unit of the title compound, [CuCl2(C5H6N2)4]·H2O, contains two crystallographically independent complex molÂecules and two water molÂecules. The CuII ion in each molÂecule is six-coordinated in an elongated octaÂhedral geometry, with the equatorial plane defined by four pyridine N atoms of four aminoÂpyridine ligands and the axial positions occupied by two Cl atoms. In the crystal structure, molÂecules are linked into a three-dimensional framework by C—H⋯Cl, O—H⋯Cl, N—H⋯O, N—H⋯Cl and N—H⋯N hydrogen bonds and C/N—H⋯π interÂactions involving the pyridine rings