2,010 research outputs found
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Rapid precipitation in an Al<inf>0.5</inf>CrFeCoNiCu high entropy alloy
The effect of cooling rate on the microstructural evolution of Al0.5CrFeCoNiCu has been studied
using differential scanning calorimetry and scanning electron microscopy. As-cast
Al0.5CrFeCoNiCu contained three phases; Cr-Fe-Co-Ni solid solution dendrites, Cu-rich
interdendritic material and L12 precipitates. During cooling at rates between 10 and 50ËšC.min-1
, an
additional exothermic event, at ~1010ËšC, was observed in the heat flow curves. Microstructural
examination after cooling revealed the presence of two distinct populations of intragranular
precipitates not present in the as-cast material. Energy dispersive X-ray spectroscopy indicated that
Cu-rich precipitates formed within the dendrites, whilst a Cr-Fe-Co rich phase formed in the
interdendritic constituent. Precipitation during cooling at rates approaching 1ËšC.s-1 indicates that the
diffusion kinetics of Al0.5CrFeCoNiCu are not, as previously suggested, sluggish.authors would like to acknowledge support from the EPSRC / Rolls-Royce Strategic Partnership under EP/H500375/1, EP/M005607/1 (NGJ & HJS) and EP/H022309/1 (KAC).This is the final version of the article. It first appeared from Maney via http://dx.doi.org/10.1179/1743284715Y.000000000
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Fine-scale precipitation in the high-entropy alloy Al<inf>0.5</inf>CrFeCoNiCu
The high-entropy alloy Al0:5CrFeCoNiCu has been shown to consist of two stable, face-centred cubic solid solutions at temperatures approaching its solidus;
one rich in Cr, Fe, Co & Ni (dendritic) and the other rich in Cu (interdendritic).
Whilst some studies have suggested that the high-temperature microstructure
may be metastably retained to room temperature through rapid cooling, evidence of phase decomposition has also been reported. In this study, fine-scale
precipitation has been observed in samples of Al0:5CrFeCoNiCu that have been
rapidly cooled after casting, and water quenched following ageing for 1000 h
at 1000°C. Contrary to previous reports, in the as-cast state, the two face-
centred cubic phases, as well as an L12 phase, were found in both dendritic and
interdendritic areas, with the dendritic areas having undergone a spinodal decomposition. After ageing and quenching, L12 precipitates were found in both
dendritic and interdendritic areas, and precipitates of the Cr-, Fe-, Co- and
Ni-enriched face-centred cubic phase were found in the Cu-rich interdendritic
regions. Given the nature of the heat treatments applied, the results suggest
that precipitation in the alloy is rapid and cannot be avoided, even when the
material is cooled quickly to room temperature.The authors acknowledge funding from Rolls-Royce plc and the EPSRC under the Rolls-Royce/EPSRC Strategic Partnership (EP/H022309/1).This is the final version of the article. It first appeared from Elsevier via http://dx.doi.org/10.1016/j.msea.2015.08.01
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Discontinuous precipitation of Co3V in a complex Co-based alloy
Discontinuous precipitation of chromium-rich Co3V lamellae has been found in a Co-based alloy containing 2 wt% V after prolonged ageing at 800 {\degr}C. This discontinuous precipitation is associated with a noticeable redistribution of alloying elements in the alloy relative to those parts of the aged alloy that preserve the c.c.p.-L12 microstructure found in the as-cast and homogenized condition. The orientation relationship between the c.c.p. Co-rich matrix and these hexagonal phase chromium-rich Co3V precipitates is shown to be || and [1 1 1]Co || , i.e. || and [1 1 1]Co || in the four-index notation. 3 × 3 transformation matrices relating directions and planes in the two phases have been established. The observed orientation relationship between the two phases is consistent with low lattice misfit between the two phases.We would also like to acknowledge the EPSRC/Rolls-Royce plc Strategic
Partnership (EP/H500375/1) for funding this work.This is the author accepted manuscript. The final version can be found on the publisher's website at: http://www.tandfonline.com/doi/abs/10.1080/14786435.2013.861946#.U8fYa_ldXH
The influence of Al: Nb ratio on the microstructure and mechanical response of quaternary Ni-Cr-Al-Nb alloys
The influence of Al:Nb ratio on the microstructure and properties of Ni–Cr–Al–Nb alloys has been investigated following long-term exposure at elevated temperatures. The γ′ volume fraction, size and lattice misfit were seen to increase with a larger Al:Nb ratio, although these changes resulted in reduced hardness. The change in the critical resolved shear stress (CRSS) associated with strong dislocation coupling was determined to be the dominant strengthening mechanism and increased with decreasing Al:Nb ratio. A distribution of tertiary γ′ was observed to be necessary in maximising the mechanical properties of these alloys.This work was supported by the EPSRC/Rolls-Royce Strategic Partnership (EP/H022309/1 and EP/H500375/1).This is the final published version, which can also be found on the Elsevier website at: http://www.sciencedirect.com/science/article/pii/S0921509314007369
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On the time-temperature-transformation behaviour of a new dual-superlattice nickel-base superalloy
Recent research has identified compositions of nickel-based superalloys with microstructures containing appreciable and comparable volume fractions of γ′ and γ″ precipitates. In this work, an alloy capable of forming such a dual-superlattice microstructure was subjected to a range of thermal exposures between 873 and 1173 K (600 and 900 ˚C) for durations of 1 to 1000 hours. The microstructures and nature of the precipitating phases were characterised using synchrotron X-ray diffraction and electron microscopy. These data have enabled the construction of a T-T-T diagram for the precipitating phases. Hardness measurements following each thermal exposure have identified the age-hardening behaviour of this alloy and allowed preliminary mechanical properties to be assessed.The authors would like to thank K. Roberts and S. Rhodes for experimental assistance, and acknowledge funding through the EPSRC/Rolls-Royce strategic partnership EP/M005607/1 and EP/H022309/1 as well as from the Diamond Light Source for the provision of beam time (EE9270)
Probabilistic design of a molybdenum-base alloy using a neural network
An artificial intelligence tool is exploited to discover and characterize a new molybdenum-base alloy that is the most likely to simultaneously satisfy targets of cost, phase stability, precipitate content, yield stress, and hardness. Experimental testing demonstrates that the proposed alloy fulfills the computational predictions, and furthermore the physical properties exceed those of other commercially available Mo-base alloys for forging-die applications.The authors acknowledge the financial support of Rolls-Royce plc, EPSRC under EP/H022309/1 and EP/H500375/1, the Royal Society, and Gonville & Caius College
A new approach to the analysis of short-range order in alloys using total scattering
In spite of its influence on a number of physical properties, short-range order in crystalline alloys has received little recent attention, largely due to the complexity of the experimental methods involved. In this work, a novel approach that could be used for the analysis of ordering transitions and short-range order in crystalline alloys using total scattering and reverse Monte Carlo (RMC) refinements is presented. Calculated pair distribution functions representative of different types of short-range order are used to illustrate the level of information contained within these experimentally accessible functions and the insight into ordering which may be obtained using this new method. Key considerations in the acquisition of data of sufficient quality for successful analysis are also discussed. It is shown that the atomistic models obtained from RMC refinements may be analysed to identify directly the Clapp configurations that are present. It is further shown how these configurations can be enhanced compared with a random structure, and how their degradation pathways and the distribution of Warren-Cowley parameters, can then be used to obtain a detailed, quantitative structural description of the short-range order occurring in crystalline alloys.Science and Technology Facilities CouncilThis is the author accepted manuscript. The final version is available from Elsevier via http://dx.doi.org/10.1016/j.actamat.2016.05.03
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Microstructural evolution of a delta containing nickel-base superalloy during heat treatment and isothermal forging
The next generation of aerospace gas turbine engines need to operate at higher temperatures and stresses to improve their efficiency and reduce emissions. These operating conditions are beyond the capability of existing nickel-base superalloys requiring the development of new high temperature materials. Controlling the microstructures of these new materials is key to obtaining the required properties and therefore, it is critical to understand how these alloys respond to processing and heat treatment. Here, the microstructural evolution of V207M, a new δ containing, nickel-base superalloy, has been investigated following heat treatment and forging. The solvus temperatures of the γ′ and δ phases, determined by differential scanning calorimetry and microscopy, were found to be ~ 985 and ~ 1060 ˚C respectively. Isothermal forging of the alloy was conducted at 1000, 1050 and 1100 ˚C, corresponding to different volume fractions of retained δ. Considerable softening was observed prior to steady state flow when forging at 1000 ˚C, whilst only steady state flow occurred at 1050 and 1100 ˚C. The steady state flow process was believed to be dominated by dynamic recovery in the γ phase, with an activation energy of 407 kJ.mol-1. Samples that exhibited flow softening also showed a significant change in the orientation of the δ precipitates, preferentially aligning normal to the forging axis, and this reorientation was thought to be the cause of the observed flow softening.The authors would like to acknowledge M. Shakib for assistance with the forging and the EPSRC/Rolls-Royce Strategic Partnership for supporting this work through EP/H022309/1 and EP/H500375/1.This is the final published version. It first appeared at http://www.sciencedirect.com/science/article/pii/S0921509314013252#
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