(Acetato-κO)(2,2′-bipyridine-κ2 N,N′)trimethyl­platinum(IV) monohydrate

In the title hydrate, [Pt(CH3)3(CH3COO)(C10H8N2)]·H2O, the PtIV atom exhibits a distorted octa­hedral coordination geometry built up by three methyl ligands in a facial arrangement, a bipyridine ligand and a monodentately bound acetate ligand. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds are observed between the water mol­ecule and the platinum complex, which link the mol­ecules into chains along the c axis

(OC-6-33)-(2,2′-Bipyridine-κ2 N,N′)trimeth­yl(2-methyl­sulfanyl-2-thia­zoline-κN)platinum(IV) tetra­fluoridoborate

The asymmetric unit of the title complex, [Pt(CH3)3(C10H8N2)(C4H7NS2)]BF4, contains two crystallographically independent mol­ecules. The PtIV atom in each complex cation exhibits a distorted octa­hedral coordination geometry, built up by three methyl ligands in a facial binding fashion, a bipyridine ligand and a monodentately N-bound 2-methyl­sulfanyl-2-thia­zoline ligand (configuration index: OC-6–33). In the crystal structure, weak inter­molecular C—H⋯F hydrogen bonds are found between the complex cations and BF4 − anions

Chlorido[1-diphenyl­phosphanyl-3-(phenyl­sulfan­yl)propane-κ2 P,S](η5-penta­methyl­cyclo­penta­dien­yl)iridium(III) chloride monohydrate

The crystal structure of the title compound, [Ir(C10H15)Cl(C21H21PS)]Cl·H2O, consists of discrete [Ir(η5-C5Me5)Cl{Ph2P(CH2)3SPh-κP,κS}]+ cations, chloride anions and water mol­ecules. The IrIII atom is coordinated by an η5-C5Me5 ligand, a chloride and a Ph2P(CH2)3SPh-κP,κS ligand, leading to a three-legged piano-stool geometry. In the crystal, two water molecules and two chloride anions are linked by weak O—H⋯Cl hydrogen bonding into tetra­mers that are located on centers of inversion. The H atoms of one of the methyl groups are disordered and were refined using a split model

[3-Meth­oxy-1-(phenyl­sulfan­yl)prop­yl]triphenyl­tin(IV) benzene 0.17-solvate

In the title compound, [Sn(C6H5)3(C10H13OS)]·0.17C6H6, the SnIV atom exhibits a slightly distorted tetra­hedral coordination geometry built up by four C atoms, which are the three ipso-C atoms of the phenyl rings and the α-C atom of the deprotonated γ-O-functionalized propyl phenyl sulfide. The benzene mol­ecule lies about a threefold rotoinversion axis

Bis[1,2-bis­(dimethyl­phosphino)ethane-κ2 P,P′]rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclo­octa­diene]rhodium(I)

In the title complex, [Rh(C6H16P2)2][RhCl2(C8H12)], the asymmetric unit contains two [Rh(dmpe)2] [dmpe = 1,2-bis­(dimethyl­phosphino)ethane] half-cations, lying on inversion centers, and an [RhCl2(cod)]− (cod = 1,5-cyclo­octa­diene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclo­octa­diene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual inter­actions

Tris(propane-1,2-diamine-κ2 N,N′)nickel(II) tetra­cyanidoplatinate(II)

In the title compound, [Ni(C3H10N2)3][Pt(CN)4], the [Pt(CN)4]2− anion with the environment of the PtII atom, lying on a mirror plane, is square planar, whereas the NiII atom in the [Ni(C3N2H10)3]2+ cation, also lying on a mirror plane, has a slightly distorted octa­hedral coordination geometry. Three chiral 1,2-diamino­propane mol­ecules, which are disordered equally over two sets of positions, adopt Δ(δδδ) and Δ(λλλ) configurations. The average Ni—N and Pt—C bond lengths are 2.131 (10) and 1.988 (10) Å, respectively. The cations and anions are connected by N—H⋯N hydrogen bonds

Dichlorido(9-methyl­adenine-κN 7)(η5-penta­methyl­cyclo­penta­dien­yl)iridium(III) dichloromethane solvate

In the title complex, [Ir(C10H15)Cl2(C6H7N5)]·CH2Cl2 or [Ir(η5-C5Me5)Cl2(9-MeAde-κN 7)]·CH2Cl2 (9-MeAde = 9-methyl­adenine), the coordination geometry of the IrIII atom approximates to a three-legged piano stool. The 9-methyl­adenine ligand is coordinated in a monodentate fashion to the Ir centre through its N-7 atom. The crystal structure contains centrosymmetric pairs of mol­ecules, inter­acting through two N—H⋯N hydrogen bonds. An intra­molecular N—H⋯Cl hydrogen bond is formed between the H atom of an NH2 group and a chlorido ligand. Further short intra- and inter­molecular C—H⋯Cl contacts are observed