40 research outputs found
Alternativni modeli za složeno opuÅ”tanje niskoenergijskih pobuÄenja u sustavima s valovima gustoÄe
We apply the Palmer, Stein, Abrahams and Anderson (PSAA) model of hierarchically constrained dynamics for glassy relaxation to the complex thermal relaxation at very low temperatures in density wave systems. Alternatively, we simulate various experimental conditions in a simple, intuitive model of an electrical RC line and find some relations with the PSAA parameters.Primjenjujemo model Palmera, Steina, Abrahamsa i Andersona (PSAA) za hijerarhijski zaprijeÄenu dinamiku opuÅ”tanja u staklima na kompleksno opuÅ”tanje topline na vrlo niskim temperaturama u sistemima s valovima gustoÄe. Jednako tako, pomoÄu jednostavnog modela slijeda elektriÄnih RC (otpor ā kapacitet) krugova oponaÅ”amo razliÄite eksperimentalne uvjete i nalazimo neke odnose s dobivenim PSAA parametrima
Bimodal energy relaxations in quasi-one-dimensional systems
We show that the low temperature ( K) time dependent non-exponential
energy relaxation of quasi-one-dimensional (quasi-1D) compounds strongly differ
according to the nature of their modulated ground state. For incommensurate
ground states, such as in (TMTSF)PF the relaxation time distribution is
homogeneously shifted to larger time when the duration of the heat input is
increased, and exhibits in addition a scaling between the width and the
position of the peak in the relaxation time distribution,
. For a commensurate ground state, as in
(TMTTF)PF, the relaxation time spectra show a bimodal character with a
weight transfer between well separated slow and fast entities. Our
interpretation is based on the dynamics of defects in the modulated structure,
which depend crucially on the degree of commensurability.Comment: 4 pages, 4 figure
Charge-Density-Wave like Behavior in the One-Dimensional Charge-Ordered Semiconductor (NbSe4)3I
We report on broadband dielectric spectroscopy on the one-dimensional
semiconductor (NbSe4)3I. Below the structural phase transition close to 270 K
we observe colossal dielectric constants with a frequency and temperature
dependence very similar to what is observed in canonical charge-density wave
systems. Guided by structural details we interpret this structural phase
transition as driven by complex charge-order processes.Comment: 4 pages, 3 figure
A Raman study of the Charge-Density-Wave State in AMoO (A = K,Rb)
We report a comparative Raman spectroscopic study of the
quasi-one-dimensional charge-density-wave systems \ab (A = K, Rb). The
temperature and polarization dependent experiments reveal charge-coupled
vibrational Raman features. The strongly temperature-dependent collective
amplitudon mode in both materials differ by about 3 cm, thus revealing the role
of alkali atom. We discus the observed vibrational features in terms of
charge-density-wave ground state accompanied by change in the crystal symmetry.
A frequency-kink in some modes seen in \bb between T = 80 K and 100 K supports
the first-order lock-in transition, unlike \rb. The unusually sharp Raman
lines(limited by the instrumental response) at very low temperatures and their
temperature evolution suggests that the decay of the low energy phonons is
strongly influenced by the presence of the temperature dependent charge density
wave gap.Comment: 13 pages, 7 figure
Fractional power-law susceptibility and specific heat in low temperature insulating state of o-TaS_{3}
Measurements of the magnetic susceptibility and its anisotropy in the
quasi-one-dimensional system o-TaS_{3} in its low-T charge density wave (CDW)
ground state are reported. Both sets of data reveal below 40 K an extra
paramagnetic contribution obeying a power-law temperature dependence
\chi(T)=AT^{-0.7}. The fact that the extra term measured previously in specific
heat in zero field, ascribed to low-energy CDW excitations, also follows a
power law C_{LEE}(0,T)=CT^{0.3}, strongly revives the case of random exchange
spin chains. Introduced impurities (0.5% Nb) only increase the amplitude C, but
do not change essentially the exponent. Within the two-level system (TLS)
model, we estimate from the amplitudes A and C that there is one TLS with a
spin s=1/2 localized on the chain at the lattice site per cca 900 Ta atoms. We
discuss the possibility that it is the charge frozen within a soliton-network
below the glass transition T_{g}~40 K determined recently in this system.Comment: 7 pages, 3 figures, submitted to Europhysics Letter
Multiferroicity in an organic charge-transfer salt: Electric-dipole-driven magnetism
Multiferroics, showing simultaneous ordering of electrical and magnetic
degrees of freedom, are remarkable materials as seen from both the academic and
technological points of view. A prominent mechanism of multiferroicity is the
spin-driven ferroelectricity, often found in frustrated antiferromagnets with
helical spin order. There, similar to conventional ferroelectrics, the
electrical dipoles arise from an off-centre displacement of ions. However,
recently a different mechanism, namely purely electronic ferroelectricity,
where charge order breaks inversion symmetry, has attracted considerable
interest. Here we provide evidence for this exotic type of ferroelectricity,
accompanied by antiferromagnetic spin order, in a two-dimensional organic
charge-transfer salt, thus representing a new class of multiferroics. Quite
unexpectedly for electronic ferroelectrics, dipolar and spin order arise nearly
simultaneously. This can be ascribed to the loss of spin frustration induced by
the ferroelectric ordering. Hence, here the spin order is driven by the
ferroelectricity, in marked contrast to the spin-driven ferroelectricity in
helical magnets.Comment: 8 pages, 9 figures (including 4 pages and 6 figures in supplementary
information). Version 2 with minor errors corrected (legend of Fig. 3c and
definition of vectors e and Q
Colossal dielectric constants in transition-metal oxides
Many transition-metal oxides show very large ("colossal") magnitudes of the
dielectric constant and thus have immense potential for applications in modern
microelectronics and for the development of new capacitance-based
energy-storage devices. In the present work, we thoroughly discuss the
mechanisms that can lead to colossal values of the dielectric constant,
especially emphasising effects generated by external and internal interfaces,
including electronic phase separation. In addition, we provide a detailed
overview and discussion of the dielectric properties of CaCu3Ti4O12 and related
systems, which is today's most investigated material with colossal dielectric
constant. Also a variety of further transition-metal oxides with large
dielectric constants are treated in detail, among them the system La2-xSrxNiO4
where electronic phase separation may play a role in the generation of a
colossal dielectric constant.Comment: 31 pages, 18 figures, submitted to Eur. Phys. J. for publication in
the Special Topics volume "Cooperative Phenomena in Solids: Metal-Insulator
Transitions and Ordering of Microscopic Degrees of Freedom