Photodegradation of 2,4-Dichlorophenol in Aqueous Systems under Simulated and Natural Sunlight

The work presents results of studies on 2,4-dichlorophenol (2,4-DCP) degradation in aqueous solutions using photochemically initiated processes by simulated and natural sunlight. A number of possible substrate photodegradation routes were investigated, by both direct photolysis and photosensitized oxidation process. The major role of singlet oxygen in 2,4-DCP photodegradation was proved. Rose Bengal and derivatives of porphine and phthalocyanine were used as sensitizers. The influences of various process parameters on the reaction rate were investigated. On the basis of experimental data reaction rate constants of 2,4-DCP photosensitized oxidation were determined. The possibility of using natural sunlight to degrade 2,4-DCP in water in the middle latitudes was stated. The acute toxicity bioassay was conducted with the marine bacterium Vibrio fischeri as a bioluminescent indicator. The obtained results encourage further research on this process

Mathematical modeling of the integrated process of mercury bioremediation in the industrial bioreactor

The mathematical model of the integrated process of mercury contaminated wastewater bioremediation in a fixed-bed industrial bioreactor is presented. An activated carbon packing in the bioreactor plays the role of an adsorbent for ionic mercury and at the same time of a carrier material for immobilization of mercury-reducing bacteria. The model includes three basic stages of the bioremediation process: mass transfer in the liquid phase, adsorption of mercury onto activated carbon and ionic mercury bioreduction to Hg(0) by immobilized microorganisms. Model calculations were verified using experimental data obtained during the process of industrial wastewater bioremediation in the bioreactor of 1 m3 volume. It was found that the presented model reflects the properties of the real system quite well. Numerical simulation of the bioremediation process confirmed the experimentally observed positive effect of the integration of ionic mercury adsorption and bioreduction in one apparatus

Recent Achievements in Dyes Removal Focused on Advanced Oxidation Processes Integrated with Biological Methods

In the last 3 years alone, over 10,000 publications have appeared on the topic of dye removal, including over 300 reviews. Thus, the topic is very relevant, although there are few articles on the practical applications on an industrial scale of the results obtained in research laboratories. Therefore, in this review, we focus on advanced oxidation methods integrated with biological methods, widely recognized as highly efficient treatments for recalcitrant wastewater, that have the best chance of industrial application. It is extremely important to know all the phenomena and mechanisms that occur during the process of removing dyestuffs and the products of their degradation from wastewater to prevent their penetration into drinking water sources. Therefore, particular attention is paid to understanding the mechanisms of both chemical and biological degradation of dyes, and the kinetics of these processes, which are important from a design point of view, as well as the performance and implementation of these operations on a larger scale

The Non-Stationary Heat Transport inside a Shafted Screw Conveyor Filled with Homogeneous Biomass Heated Electrically

The non-stationary heat transfer inside a cylindrical channel of a shafted screw conveyor, electrically heated, and filled with a moving biomass was analyzed. The problem of non-stationary heat transport is encountered in the processes of biomass pyrolysis and food products’ sterilization. To solve the heat conduction equation with initial and boundary conditions, the methods of the expansion of the given and unknown functions into a Fourier series in the angular coordinate, and Fourier and Laplace integral transforms in the axial coordinate and time, respectively, were used. As a result of solving this problem, it is shown that the temperature in the reactor consists of two main terms. The first of them is proportional to time, and the second is a superposition of quasi-monochromatic heat pulses decaying with time. Numerical analysis of the temperature distribution in space and time depending on various specific parameters of the system was carried out. The obtained numerical results were compared with those corresponding to the cases of heat sources in the form of a spiral or a shaftless helical screw

Recent Achievements in Dyes Removal Focused on Advanced Oxidation Processes Integrated with Biological Methods

In the last 3 years alone, over 10,000 publications have appeared on the topic of dye removal, including over 300 reviews. Thus, the topic is very relevant, although there are few articles on the practical applications on an industrial scale of the results obtained in research laboratories. Therefore, in this review, we focus on advanced oxidation methods integrated with biological methods, widely recognized as highly efficient treatments for recalcitrant wastewater, that have the best chance of industrial application. It is extremely important to know all the phenomena and mechanisms that occur during the process of removing dyestuffs and the products of their degradation from wastewater to prevent their penetration into drinking water sources. Therefore, particular attention is paid to understanding the mechanisms of both chemical and biological degradation of dyes, and the kinetics of these processes, which are important from a design point of view, as well as the performance and implementation of these operations on a larger scale

Analysis of non-stationary temperature field generated by a shaftless screw conveyor heated by Joule-Lenz effect

The non-stationary problem of temperature distribution in a circular cylindrical channel of infinite length filled with a homogeneous biomass material moving with a constant velocity in the axial direction was investigated. The heat source was a shaftless helical screw (or auger), which was heated with an electric current due to the Joule–Lenz effect and rotated uniformly around the axis of symmetry of the channel. Similar problems arise in the thermal processing of biomaterials using screw conveyor in pyrolysis and mass sterilization and pasteurization of food products. The problem is solved using the expansion of given and required functions in Fourier series over angular coordinate and integral Fourier and Laplace transforms over axial coordinate and time, respectively. As a result, the temperature field is obtained as the sum of two components, one of which, global, is proportional to time, and the other, which forms the microstructure of the temperature profile, is given by Fourier–Bessel series. The coefficients of the series are determined by the integrals calculated using the Romberg method. Based on the numerical calculations, the analysis of the space-time microstructure of the temperature field in the canal was performed. A significant dependence of the features of this microstructure on the geometric, kinematic and thermodynamic characteristics of the filling biomass and the screw was revealed

MOBIL CONTAINER UNIT FOR SEWAGE SLUDGE UTILIZATION FROM SMALL AND MEDIUM WASTWATER TREATMENT PLANTS

The most wastewater treatment plants in Poland are small and medium plants of flow capacity below 1000 m3/d. These plants are not able to build sludge incineration plants and the transportation costs to the nearest plants increase the total costs of wastewater treatment. Polish company Metal Expert together with the French company ETIA and Lodz University of Technology proposed mobile unit for integrated drying and pyrolysis of sewage sludge in a pilot bench scale with capacity of 100 kg/h of dewatered sludge. The pilot plant was mounted in a typical mobile container which could provide service to small and medium wastewater treatment plants offering thermal processing of sewage sludge. This unit consists of KENKI contact dryer and „Spirajoule”® pyrolyser supplied with electricity utilizing the Joule effect, and a boiler, wherein the pyrolysis gases and volatile products are burned producing steam sent to the contact dryer. The bio-char produced during sludge pyrolysis could be utilized for agriculture purposes. During preliminary experiments and short-term exploitation of the unit at Elbląg Wastewater Treatment Plant the obtained results allowed us to make a mass and energy balance depended on the process conditions in the pyrolysis temperature range of 400÷800 °C. Based on the obtained results a calculator was created in the Excel , which enables assessment of pyrolysis products content and making mass and energy balances depended on process parameters such as initial moisture of sludge, pyrolysis temperature and installation output