Polypyrrole Coated PET Fabrics for Thermal Applications

Polypyrrole can be chemically synthesized on PET fabrics, giving rise to textiles with high electric conductivity. These textiles are suitable for several applications from antistatic films to electromagnetic interference shielding devices. Here we discuss the thermal-electric performance and the heat generation of polypyrrole coated PET fabric samples, previously studied because of their electric conductivity and electromagnetic interference shielding effectiveness. The measured Seebeck effect is comparable with that of metallic thermocouples. Since polypyrrole shows extremely low thermal diffusivities regardless of the electrical conductivity, the low thermal conductivity gives significant advantage to the thermoelectric figure-of-merit ZT, comparable with that of some traditional inorganic thermoelectric materials. The heat generation is also investigated for possible heating textile devices. The results confirm polypyrrole as a prom- ising material for thermal electric applications due to its easy preparation in low cost processin

Static splay-stripes in a hybrid aligned nematic layer

A usual aperiodic hybrid alignment can appear in a nematic layer with weak anchoring only if the cell thickness is greater than a critical value dh, below which a static periodic pattern instead of the hybrid aperiodic structure could be preferred, if the energy cost for a three dimensional deformation, involving twist, is less than the cost for the two-dimensional deformation of splay-bend type. We have studied the occurrence of the mechanical instability leading to the static periodic splay-stripes, i. e. in the case of the tilt anchoring stronger at the one of the walls, in which the anchoring is planar, for several values of the twist anchoring strengths. Here the behavior of the threshold d for the periodic stripes is presented and discussed as a function of the anchoring energies and of the ratio of nematic bulk elastic constants, in the frame of the usual continuum theory

Texture transitions in the liquid crystalline alkyloxybenzoic acid 6OBAC

The 4,n-alkyloxybenzoic acid 6OBAC has a very rich variety of crystalline structures and two nematic sub-phases, characterised by different textures. It is a material belonging to a family of liquid crystals formed by hydrogen bonded molecules, the 4,n-alkyloxybenzoic acids indicates the homologue number). The homologues with n ranging from 7 to 13 display both smectic C and N phases. In spite of the absence of a smectic phase, 6OBAC exhibits two sub-phases with different textures, as it happens in other materials of the homologue series which possess the smectic phase. This is the first material that exhibits a texture transition in a nematic phase directly originated from a crystal phase. Here we present the results of an image processing assisted optical investigation to characterise the textures and the transitions between textures. This processing is necessary to discriminate between crystal modifications and nematic sub-phases.Comment: 12 pages, 10 figure

Hybrid aligned nematics and second order elasticity

The effect of the second order elasticity on the critical thickness of Hybrid Aligned Nematic cells possessing either weak planar or weak homeotropic anchoring has been analysed. It is found that the critical thickness of such cells is strictly dependent on the surface elastic constant K13 and on the second order bulk elastic constant K*. Moreover, an experimental method for an indirect measurement of K13 and K* is proposed

Thermal electric effects and heat generation in polypyrrole coated PET fabrics

Polypyrrole chemically synthesized on PET gives rise to textiles with a high electric conductivity, suitable for several applications from antistatics to electromagnetic interference shielding devices. Here, we discuss investigations on thermal electric performances of the polypyrrole coated PET in a wide range of temperatures above room temperature. The Seebeck coefficient turns out to be comparable with that of metal thermocouple materials. Since polypyrrole shows extremely low thermal diffusivities regardless of the electrical conductivity, the low thermal conductivity gives significant advantage to the thermoelectric figure-of-merit ZT, comparable with that of some traditional inorganic thermoelectric materials. The heat generation is also investigated for possible heating textile devices.Comment: 12 pages and 9 figure

Saddle-splay and periodic instability in a hybrid aligned nematic layer subjected to a normal magnetic field

A nematic layer with opposite boundary conditions (unidirectional planar and homeotropic) is considered, having strong anchoring at the planar wall. It is known that a periodic deformation of splay-type can intervene between the aperiodic hybrid alignment and undistorted planar state as one decreases the film thickness. This periodic state occurs due to the fact that the energetic cost for a mixed twist-splay can be lower than the surface energetic cost at the homeotropic wall in the case of undistorted planar alignment. Such a situation may also be achieved for nematics which have a bulk elastic isotropy. In this paper, the saddle-splay elastic constant K24 is shown to influence strongly the occurrence of the periodic pattern of splay-type, also in the presence of an external magnetic field normal to the cell plates, and the role of the geometrical anchoring in wedge-shaped cells is discussed

Polypyrrole Coated PET Fabrics for Thermal Applications

Polypyrrole can be chemically synthesized on PET fabrics, giving rise to textiles with high electric conductivity. These textiles are suitable for several applications from antistatic films to electromagnetic interference shielding devices. Here we discuss the thermal-electric performance and the heat generation of polypyrrole coated PET fabric samples, previously studied because of their electric conductivity and electromagnetic interference shielding effectiveness. The measured Seebeck effect is comparable with that of metallic thermocouples. Since polypyrrole shows extremely low thermal diffusivities regardless of the electrical conductivity, the low thermal conductivity gives significant advantage to the thermoelectric figure-of-merit ZT, comparable with that of some traditional inorganic thermoelectric materials. The heat generation is also investigated for possible heating textile devices. The results confirm polypyrrole as a prom- ising material for thermal electric applications due to its easy preparation in low cost processin

Image segmentation and 3D reconstruction for improved prediction of the sublimation rate during freeze drying

In a freeze drying process, the freezing step determines the pore size distribution within the product, which, in turn, affects the sublimation rate. Traditionally, pore analysis is carried out on SEM images by means of a manual, time-consuming approach. Here, an image segmentation technique was used to automatize this process and improve its reliability. A 3D structure of the cake was then reconstructed from the distribution of the super-pixels. We show that the approach herein proposed can remarkably improve prediction of the sublimation rate with respect to traditional methods

Electromagnetic shielding with polypyrrole-coated fabrics

Several shielding applications, to protect human health and electronic devices against dangerous effects of electromagnetic radiation, require solutions that fabrics can suitably fulfill. Here, we will investigate the electromagnetic interference shielding effectiveness of polypyrrole-coated polyester textiles, in the frequency range 100-1000 MHz. Insertion losses for several conductive fabrics with different surface resistivity ranging from 40 Ohm till the very low value of 3 Ohm were evaluated with a dual-tem cell. Correlations between the shielding effectiveness and the conductivity of composites are also discussed.Comment: 6 pages, 6 figure