Nanogranular BaTiO3–CoFe2O4 thin films deposited by pulsed laser ablation

Detailed structural and magnetic measurements were performed on nanostructured composite thin films of cobalt ferrite (CoFe2O4 - magnetostrictive) dispersed in a barium titanate (BaTiO3 - piezoelectric) matrix, with different CoFe2O4 concentrations (ranging from x=20% to x=70%). The films were deposited by laser ablation on platinum covered Si(100). Their structure was studied by X-ray diffraction and Raman spectroscopy. The magnetic properties were measured with a SQUID magnetometer. The nanocomposite films were polycrystalline and composed by a mixture of tetragonal-BaTiO3 and CoFe2O4 with the cubic spinel structure. The lattice parameter of the CoFe2O4 phase varied from 8.26Å (x=20%) to 8.35Å (x=70%), and, comparing with bulk CoFe2O4, it was under compressive stress that relaxed as its concentration progressively increased. In the tetragonal-BaTiO3 phase, the lattice parameter a was contracted relative to the bulk phase and decreases with x. The lattice parameter c increased from 4.088 Å (x=20%) to 4.376 Å (x=70%), so that the BaTiO3 c axes was increasingly expanded as the quantity of the barium titanate phase was reduced. This behavior was the opposite of that observed in CoFe2O4. The magnetic measurements showed that the coercive fields decreased from 6.6 kOe (x=20%) to 2.3 kOe (x=70%) which was attributed to the progressive relaxation of the stress in the films as well as to the increase of particle agglomeration in bigger polycrystalline clusters with increasing cobalt ferrite concentration. For higher temperatures T=300 K the reduction of magnetocrystalline anisotropy induced a strong reduction of the coercive field.This work has been financially supported by the Portuguese Foundation for Science and Technology (FCT), through the project POCI/CTM/60181/2004

Chaos and Synchronized Chaos in an Earthquake Model

We show that chaos is present in the symmetric two-block Burridge-Knopoff model for earthquakes. This is in contrast with previous numerical studies, but in agreement with experimental results. In this system, we have found a rich dynamical behavior with an unusual route to chaos. In the three-block system, we see the appearance of synchronized chaos, showing that this concept can have potential applications in the field of seismology.Comment: To appear in Physical Review Letters (13 pages, 6 figures

Electrical current-driven pinhole formation and insulator-metal transition in tunnel junctions

Current Induced Resistance Switching (CIS) was recently observed in thin tunnel junctions (TJs) with ferromagnetic (FM) electrodes and attributed to electromigration of metallic atoms in nanoconstrictions in the insulating barrier. The CIS effect is here studied in TJs with two thin (20 \AA) non-magnetic (NM) Ta electrodes inserted above and below the insulating barrier. We observe resistance (R) switching for positive applied electrical current (flowing from the bottom to the top lead), characterized by a continuous resistance decrease and associated with current-driven displacement of metallic ions from the bottom electrode into the barrier (thin barrier state). For negative currents, displaced ions return into their initial positions in the electrode and the electrical resistance gradually increases (thick barrier state). We measured the temperature (T) dependence of the electrical resistance of both thin- and thick-barrier states ($R_b$ and R$_B$ respectively). Experiments showed a weaker R(T) variation when the tunnel junction is in the $R_b$ state, associated with a smaller tunnel contribution. By applying large enough electrical currents we induced large irreversible R-decreases in the studied TJs, associated with barrier degradation. We then monitored the evolution of the R(T) dependence for different stages of barrier degradation. In particular, we observed a smooth transition from tunnel- to metallic-dominated transport. The initial degradation-stages are related to irreversible barrier thickness decreases (without the formation of pinholes). Only for later barrier degradation stages do we have the appearance of metallic paths between the two electrodes that, however, do not lead to metallic dominated transport for small enough pinhole radius.Comment: 10 pages, 3 figure

A mechanistic-empirical based overlay design method for reflective cracking

This paper describes a new and innovative mechanistically based pavement overlay design method that considers the most predominant type of overlay distress observed in the field: Reflective cracking above old cracks in the underlying pavement surface. Both dense-graded hot mix asphalt and gap-graded asphalt rubber (wet process) mixes were studied, in the laboratory and in the field, to derive the necessary mechanistic relationships and statistically based equations. The models proposed are based on a finite element model that closely approximates actual field phenomena. Many field test sections, in Arizona, California and Portugal, were studied during the course of the research. Other HMA mixes used for overlays may also be calibrated and used through the proposed method. However, the relevant mix properties of any additional materials or environmental zones must first be determined. The two mix types studied are mainly used in the desert southwest region of Arizona and California. The overlay design program is available from the Rubber Pavements Association or Arizona Department of Transportation in the form of an Excel spreadsheet with an easy-to-use visual basic computer program (macro)

Exponential Distributions in a Mechanical Model for Earthquakes

We study statistical distributions in a mechanical model for an earthquake fault introduced by Burridge and Knopoff [R. Burridge and L. Knopoff, {\sl Bull. Seismol. Soc. Am.} {\bf 57}, 341 (1967)]. Our investigations on the size (moment), time duration and number of blocks involved in an event show that exponential distributions are found in a given range of the paramenter space. This occurs when the two kinds of springs present in the model have the same, or approximately the same, value for the elastic constants. Exponential distributions have also been seen recently in an experimental system to model earthquake-like dynamics [M. A. Rubio and J. Galeano, {\sl Phys. Rev. E} {\bf 50}, 1000 (1994)].Comment: 11 pages, uuencoded (submitted to Phys. Rev. E

Love kills: Simulations in Penna Ageing Model

The standard Penna ageing model with sexual reproduction is enlarged by adding additional bit-strings for love: Marriage happens only if the male love strings are sufficiently different from the female ones. We simulate at what level of required difference the population dies out.Comment: 14 pages, including numerous figure

Structural and magnetic properties of nanogranular BaTiO3-CoFe2O4 thin films deposited by laser ablation on Si/Pt substrates

Thin film nanocomposites of cobalt ferrite (CoFe2O4) dispersed in barium titanate (BaTiO3) matrix, have been deposited with different cobalt ferrite concentrations (from 20% to 70% CoFe2O4), as well as pure barium titanate and cobalt ferrite thin films (end members). The films were prepared by pulsed laser ablation on platinum covered Si(001) substrates. The films structure was studied by X-ray diffraction and their surface was examined by scanning electron microscopy (SEMI). The magnetic properties were measured in a SQUID magnetometer. The results show that the deposited films are polycrystalline with a slight (111) barium titanate phase orientation and (311) COFe2O4 phase orientation. The grain sizes measured from the X-ray diffraction peak widths, for both phases. arc in the range 40nm to 100nm. However. as the concentration of the cobalt ferrite increases. the grain size of the BaTiO3 phase decreases, from 100nm to 30nm, up to 40% CoFe2O4 concentration beyond which the BaTiO3 grain size has an approximately constant value near 30nm. On the other hand the cobalt ferrite grain size does not show a clear trend with increasing cobalt ferrite concentration. fluctuating in the range 20nm to 30nm. The magnetic measurements show an increase of the magnetic moment from the low concentration region where the, magnetic grains are more isolated and their magnetic interaction is small, towards the bulk value at higher CoFe2O4 concentrations. Also, a strong reduction of the magnetization with increasing temperature was observed, due to the corresponding decrease of the magnetocristalline anisotropy of the cobalt ferrite.This work has been financially supported by the Portuguese Foundation for Science and Technology (FCT), through the project POCI/CTM/60181/2004