Investigation of No2/No, So2, Co and Volatile Organic Compounds Emission from Solid Waste in Ogbomoso

Emissions from burning of solid waste have been a major source of air pollutions in Ogbomoso Township in the last few years. This research work estimate the emissions of nitrogen oxides (NO2/NO), carbon(II)oxide, sulphur (iv) oxide and volatile organic compounds from solid waste in Ogbomoso as a measure of control using the emission factors approach. Determination of the solid waste generation potential using per capita approach was combined with the appropriate emission factors for the estimation. On the average, nylon has the least generation potential with 8.85% while solid (glass, metal, tin and sand) has the highest with 44.825%. These generation potentials increased from 44,073 tonnes/annum in the year 2002 to 63,822.88 tonnes/annum in the year 2011 with the population of 242,167 to 350,627 per capita respectively. However, results obtained from nitrogen oxides (NO2/NO), carbon (II) oxide, sulphur (iv) oxide and volatile organic compounds emissions rate shows an increased trend of 132.22 to 191.47, 1851.3 to 2680.6, 19.3 to 27.1 and 947.58 to 1372.19 tonnes/annum respectively in the year 2002 to 2011. The emission rate of NO/NO2, SO2, CO and volatile organic compounds must be controlled because of their adverse effect on the environment. The controlled could be by converting them for energy production owing to the high calorific value of the solid waste in Ogbomoso. Another controlled technique that can be employed in addition to conversion for energy production is by burning the waste in an incinerator since the solid waste consist of high percentage of combustible materials. Keywords: Emission factor, Solid wast

Application of the triangular model in quantifying landfill gas emission from municipal solid wastes

Municipal solid waste landfills are significant parts of anthropogenic greenhouse gas emissions. The emission of significant amount of landfill gas has generated considerable interest in quantifying such emissions. The chemical composition of the organic constituents and potential amount of landfill gas that can be derived from the waste were determined. The chemical formulae for the rapidly biodegradable waste (RBW) and slowly biodegradable waste (SBW) were determined as C39H62O27N and C36H56O20N, respectively. The triangular method was used to calculate landfill gas obtainable from rapidly biodegradable waste over a 5-year period and for slowly biodegradable waste over a 15-year period. A plot was obtained for a landfill life span of 20 years. The volume of methane and carbon dioxide from RBW were 12.60 m3 and 11.76 m3 respectively while those from SBW were 6.60 m3 and 5.48 m3 respectively at STP. For the initial deposit of 2002 the highest landfill gas emission rate occurred in 2007 at 0.2829 Gg/yr with an average cumulative emission of 0.3142 Gg while for a landfill closed after five years the highest landfill gas emission rate was in 2010 at 1.2804 Gg/yr with an average cumulative emission of 1.5679 Gg while this cumulative emission will start declining by the year 2029

Dispersion Modelling of Air Emission from a Rice Milling Plant

The study investigated the air quality impacts of Rice Mill using the ISC-AERMOD View. Contributions of steam boiler and electric power generators in the mill to ground level concentrations of criteria air emissions were established.The maximum ground level concentrations of air pollutants presently emitted by the steam boiler are 1-hour averaging period concentrations of 1.4 – 177.3 µg/m3 with 24-hour level of 0.3 – 43.5 µg/m3 . Simultaneous operations of the steam boiler and electric power generators give 1-hour averaging period concentrations of 29.7 – 257.8 µg/m3 with 24-hour levels of 8.8 – 95.8 µg/m3 . The simultaneous operations of the steam boiler and the electric power generators add about 0.41 – 84.78% of the respective investigated air pollutants limits to the ambient air quality of the host environment. Occasionally the daily NOX limits from this scenario 2 could breach the ambient limit whenever all the three electric power generators are simultaneously operated with the steam boile

Atmospheric particulate fractions from Nigerian crude oil spillage

Laboratory simulations of the spill behaviors of three different Nigerian crude oil samples over three media (fresh water, sea water and soil) were carried out with a view to determining the effect of crude oil spillage on emission of fine (PM 2.5 ) and inhalable particulates fractions (PM 10 ). The spillage experiments were carried out in an environmental test box fitted with equipment to regulate the micro climatic conditions (temperature and Relative humidity). The maximum concentrations of PM 2.5 were 711, 689 and 680 μgm − 3 while those of PM 10 were 972, 946 and 940 μgm − 3 for sample A, B and C respectively. These peak concentrations were obtained for spill conditions corresponding to fresh water at 45 °C and 49% relative humidity. The least concentrations of PM 2.5 and PM 10 emitted across all samples were 63 μgm − 3 and 256 μgm − 3 respectively and these corresponded to spillage over sea water at 15 °C and 80% relative humidity. These concentrations clearly exceeded the short time averaging period (24 h) standards set for PM 2.5 and PM 10 by the United States Environmental Protection Agency. Incessant crude oil spillages in the Nigerian oil fields are therefore predicted to cause degradation of air quality within a short duration from the spill

Investigation of Air Emissions from Artisanal Petroleum Refineries in the Niger-Delta Nigeria

The increase in price of the available refined petroleum products for local consumption in Nigeria had led to the emergence of indigenous technology for petroleum refining in some parts of the Niger Delta region. This study, therefore characterized and quantified artisanal refineries’ gaseous emissions for possible air pollutants based on various unit operations involved and evaluated their impacts. It measured the emissions directly from source using E8500 Portable Combustion Analyzer. It also categorized oven sizes/processing capacity of the refineries into various ranges in order to estimate emissions according to processing capacity. The result revealed that; pollutants emission varied significantly between the unit operations and increased with increase in processing capacity. When the emissions were compared with daily limits set by the Environmental Guidelines and Standard for Petroleum Industry in Nigeria (EGASPIN) 2002, the emissions (CO, NOx, and SO2) breached the available set limits. While with the Federal Environmental Protection Agency (FEPA), 1991 set limits for emissions from stationary source; HC and CO breached their limits. SO2 and H2S breached their lower limits but were below the upper limit, while NOx emissions were found within its set limit. The study concluded that, Nigeria Artisanal Petroleum Refineries are sources of air pollution, as they impact the host environment

Impact of elemental composition of particulate matter in the airshed of a University Farm on the local air quality.

The impact of particulate matter on the ambient air quality of Landmark University Farm was assessed using deposition fluxes of Trace elements (TEs) in the airshed of the farm. Deposition gauges were employed to collect both dry and wet deposition samples of particulate matter between 2018 and 2019. Elemental compositions of particulates collected during the sampling period were analyzed using Energy Dispersive X-ray Fluorescence Spectroscopy (ED-XRF). The deposition fluxes of crustal and anthropogenic trace elements were also determined using standard methods. Results showed that in dry season, iron has the highest mean concentration (3283.61 mg/kg), while chromium has the lowest (0.023 mg/kg). On the other hand, in wet season, silicon and nickel have the highest and lowest mean concentrations of 159.34 mg/kg and 0.01 mg/kg respectively. Although the concentrations of these metals were higher in the dry season than wet season, there was no statistical significant difference between the mean concentrations of the elements measured in each season of the year (p > 0.05). The compositions of some of the elements in the particulate matters were found to be far above the recommended exposure limits prescribed by OSHA. The study concluded that the elemental composition of particulate matter in the airshed of the University Farm adversely impacts the ambient air quality of the Communit

Impact of Trace Gaseous Emission from Fuelwood Species on Ground Level Air Quality

Nigeria’s energy supply in the form of electricity has been erratic and unreliable in recent time that people now depend on their own power generation in order to meet demands. Thus majority of the populace have to depend on traditional fuelwood for cooking without knowing the impacts of air emissions from it. This study estimated the ground-level concentrations of the air pollutants emitted from the fuelwoods using the American Meteorological Society-Environmental Protection Agency Regulatory Model (AERMOD). The maximum 24 h averaging ground-level concentrations were 6.378–87.319, 1.546–75.164, 0.079–2.759, and 0–0.164 μg/m3, respectively for CO, HC, NO, and SO2. With this all stakeholders will be properly guided on the usage of fuelwood with minimal negative impact

GASEOUS EMISSIONS CHARACTERIZATION FROM POTASSIUM NITRATE-BASED ROCKET COMPOSITE PROPELLANT COMBUSTION

This paper reports the gaseous compositions produced from the combustion of a laboratory-synthesized potassium nitrate (KNO3)-based rocket composite propellant. The exhaust emissions produced from the combustion of 10 different propellant formulations were analyzed using an E8500 portable industrial emission analyzer. The concentrations, emission factor, and emission rates of the gaseous pollutants were computed. The measured concentrations were then compared with the stationary source limit by the Federal Ministry of Environment standard (Nigeria) to establish their impact on air quality. The obtained concentrations were as follows: hydrocarbon (HC) ranged from 56 to 290 mg/m3, with an the average concentration of 145.72 ± 20.12 mg/m3; carbon monoxide (CO) ranged from 234 to 2030 mg/m3, with an average concentration of 1177.3 ± 154.2 mg/m3; nitrogen oxides ranged from 19.8 to 53.7 mg/m3, with an average concentration of 33.9 ± 4.18 mg/m3; sulfur dioxide ranged from 8.2 to 156.8 mg/m3, with an average concentration of 25.4 ± 14.67 mg/m3; and hydrogen sulfide ranged from 1 to 6 mg/m3, with an average concentration of 2.44 ± 0.50 mg/m3. The results indicate that HC and CO emissions from the combustion of KNO3-based composite propellant represent a great threat and concern in relation to air quality. Thus, the proper management and control of rocket launches using KNO3-based composite propellants needs to be immediately addressed; otherwise, such emissions could have negative effects on the atmospheric environment of rocket routers