Microstructure and Texture Evolution during Superplastic Deformation of SP700 Titanium Alloy

The superplastic tensile test was carried out on SP700 (Ti-4.5Al-3V-2Mo-2Fe) titanium alloy sheet at 760 °C by the method of maximum m value, and the microstructure characteristics were investigated to understand the deformation mechanism. The results indicated that the examined alloy showed an extremely fine grain size of ~1.3 μm and an excellent superplasticity with fracture elongation of up to 3000%. The grain size and the volume fraction of the β phase increased as the strain increased, accompanied by the elements’ diffusion. The β-stabilizing elements (Mo, Fe, and V) were mainly dissolved within the β phase and diffused from α to β phase furthermore during deformation. The increase in strain leads to the accumulation of dislocations, which results in the increase in the proportion of low angle grain boundaries by 15%. As the deformation process, the crystal of α grains rotated, and the texture changed, accompanied by the accumulation of dislocations. The phase boundary (α/β) sliding accommodated by dislocation slip was the predominant mechanism for SP700 alloy during superplastic deformation

0.1wt% Boron addition Effect on dynamic compressive mechanical properties of Ti-6Al-4V alloy

0.1wt% Boron addition effect on dynamic compression properties of Ti-6Al-4V (Ti-64A) alloy are investigated by Split Hopkinson Pressure Bar (SHPB). In the study, and relative damage mechanism is also analyzed. The results show that, as-cast microstructure is refined due to 0.1% Boron addition and also to lower the non-uniform distribution of strain, stress or local concentration due to inharmonic deformation. As well as both dynamic strain and average dynamic flow stress is improved with a reduction of the sensitivity of adiabatic shear behavior. As deformation microstructure loaded at high strain rate with 0.1wt% boron addition, Dynamic strain and maximum absorbed energy is decrease 10%~30% compare with Ti-64A alloy. Both Ti-64A and Ti-6Al-4V-0.1B (Ti-64B), average dynamic flow stress is close. At high speed impact load, it exhibits a damage of adiabatic shear and TiB phases bear loading during fracture. Adiabatic shear band ismain reason of Ti-64A and Ti-64B alloys fracture failure through the deformed specimens’ microstructure observation. Adiabatic shear band formation and expansion is a precursor of material shear fracture failure. Deformation cavity can be formation between TiB phase and matrix during the deformation process, but not the main reason of material fracture failure

0.1wt% Boron addition Effect on dynamic compressive mechanical properties of Ti-6Al-4V alloy

0.1wt% Boron addition effect on dynamic compression properties of Ti-6Al-4V (Ti-64A) alloy are investigated by Split Hopkinson Pressure Bar (SHPB). In the study, and relative damage mechanism is also analyzed. The results show that, as-cast microstructure is refined due to 0.1% Boron addition and also to lower the non-uniform distribution of strain, stress or local concentration due to inharmonic deformation. As well as both dynamic strain and average dynamic flow stress is improved with a reduction of the sensitivity of adiabatic shear behavior. As deformation microstructure loaded at high strain rate with 0.1wt% boron addition, Dynamic strain and maximum absorbed energy is decrease 10%~30% compare with Ti-64A alloy. Both Ti-64A and Ti-6Al-4V-0.1B (Ti-64B), average dynamic flow stress is close. At high speed impact load, it exhibits a damage of adiabatic shear and TiB phases bear loading during fracture. Adiabatic shear band ismain reason of Ti-64A and Ti-64B alloys fracture failure through the deformed specimens’ microstructure observation. Adiabatic shear band formation and expansion is a precursor of material shear fracture failure. Deformation cavity can be formation between TiB phase and matrix during the deformation process, but not the main reason of material fracture failure

A study on microstructural evolution and detwinning behavior of Ti–3Al–2.5V cold-rolled tube during annealing

Near alpha titanium alloys have been widely used in the aerospace industry owing to their high special strength, low-density and excellent corrosion resistance. Ti–3Al–2.5V is a typical near alpha titanium alloy that was usually used in the form of a tube in aircraft due to its excellent cold workability. In the present study, the microstructural evolution and detwinning behavior of cold-rolled Ti–3Al–2.5V alloy tubes during annealing were investigated. Upon annealing, the microstructure evolution strongly depends on the annealing temperature and holding time, which play important roles in the kinetics of the static recovery and recrystallization. In addition, there are two independent detwinning mechanisms involved during annealing. The first one is that detwinning occurs along the twin shear direction at grain boundaries, resulting in a shortening effect. The second one is that detwinning occurs in the center of twins, resulting in a thinning effect of twins. The understanding of the detwinning behavior and microstructural evolution during annealing helps with the tube processing and their applications in aircraft

Equivalent Heat Treatments and Mechanical Properties in Cold-Rolled TiNiFe Shape-Memory Alloys

Heat treatments after cold rolling for TiNiFe shape-memory alloys have been compared. After EBSD analysis and as calculated by the Avrami model and Arrhenius equation, the relationship between the heat-treatment temperature and manufacturing time of TiNiFe alloys is established. Through calculation, it can be found that TiNiFe alloys can obtain similar microstructures under the annealing processes of 823 K for 776 min, 827 K for 37 min, and 923 K for 12.5 min. And the recrystallization fractions are all around 50%. Nevertheless, the tensile properties and recovery stress of the alloys show almost similar values. And based on the feasibility of the annealing process, it is believed that annealing at 873 K for 37 min is the optimal choice to obtain a recrystallization fraction φR = 50%

Effect of ‘Q’ Ratio on Texture Evolution of Ti-3Al-2.5V Alloy Tube during Rolling

Ti-3Al-2.5V alloy was usually the α phase of HCP structure at room temperature which had obvious anisotropy. During tube rolling, α grain would be influenced by stress-strain state, deformation amount, ‘Q’ ratio to result the preferred orientation and formed texture. In order to obtain radial texture tube by rolling and improve the service quality of tube in the pipeline system, Φ25 mm Ti-3Al-2.5V alloy tubes was selected as billet for the experiment, and four kinds of tubes with outer diameter of Φ16mm was produced by single pass cold rolling with ‘Q’ ratios ranging from 0.65 to 2.0. The effect of ‘Q’ ratio on the texture of Ti-3Al-2.5V tube was studied. The result indicted that the initial texture of the tube is radial-circumferential equally distributed, and the radial basal texture enhances gradually with increasing ‘Q’ ratio. Since the angle between the C-axis of grain and the radial axis of RD decreases, the C-axis of grain distributes to the radial direction, and the more grain orientation from {112X} pyramidal to {0001} basal plane. The different ‘Q’ ratio would lead to different strain along the radial direction, circumferential direction, axial direction, thus affected the crystal orientation and distribution during tube rolling deformation. When ‘Q’ > 1, the tube mainly produced radial basal texture. By comparison with ‘Q’ < 1, the tube mainly produced circumferential basal texture. As a result, when the initial texture of the tube is radial-circumferential equally distributed, the ideal radial texture of the tube can be obtained by choosing rolling process with ‘Q’ > 2.0

Effects of Co Addition on the Microstructure and Properties of Elastic Cu-Ni-Si-Based Alloys for Electrical Connectors

The properties and microstructure evolution of quaternary Cu-Ni-Co-Si alloys with different Ni/Co mass ratios were investigated. The microstructure and morphological characteristics of the precipitates were analyzed by using electron backscatter diffraction (EBSD), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). The mechanical properties and conductivity of the alloys were significantly improved after the addition of Co. The grains presented an obvious growth trend with an increase in Ni/Co mass ratios, and the appropriate Co accelerated the recrystallization process. The δ-(Ni, Co)2Si phases of the Cu-Ni-Co-Si alloys and δ-Ni2Si phases of the Cu-Ni-Si alloys shared the same crystal structure and orientation relationships with the matrix, which had two variant forms: δ1 and δ2 phases. The precipitates preferential grew along with the direction of the lowest energy and eventually exhibited two different morphologies. Compared with that of the Cu-Ni-Si alloy, the volume fraction of precipitates in the alloys with Co was significantly improved, accompanied by an increase in the precipitated phase size. The addition of Co promoted the precipitation of the precipitated phase and further purified the matrix. A theoretical calculation was conducted for different strengthening mechanisms, and precipitation strengthening was the key reinforcement mechanism. Moreover, the kinetic equations of both alloys were obtained and coincided well with the experimental results