Prediction of Run-Off Road Crash Severity in South Korea’s Highway through Tree Augmented Naïve Bayes Learning

The run-off road crash (RORC) is a representative type of lethal crash. The severity of RORC has increased owing to a combination of factors, such as roadside geometry, traffic conditions, and weather/climatic conditions. In this study, a model for estimating the RORC severity was developed based on various factors, including fixed objects, roadway geometry, traffic conditions, and road traffic environment. To develop the model, the accident data of crashes with roadside fixed objects on highways, as well as information on fixed object-related variables and roadway geometry-related variables, were collected. To improve the model in terms of implementing a close reflection of the real world, a learning method with tree augmented naïve Bayes (TAN), which takes into account the causal links between variables, was applied. The results of the analysis showed that the severity of crashes with roadside fixed objects increased sharply when the vertical slope was ≥4%, the radius of the curve was ≥250 m, the distance between the fixed object and the roadway was less than 3 m, or the density of fixed objects installation was greater than 2 for every 10 m. The proposed model allows for an analysis of sections with a high RORC severity on the roadways in operation and provides improvement measures to reduce the severity of RORC

Open Access Facile synthesis of uniform large-sized InP nanocrystal quantum dots using tris(tertbutyldimethylsilyl)phosphine

Colloidal III-V semiconductor nanocrystal quantum dots [NQDs] have attracted interest because they have reduced toxicity compared with II-VI compounds. However, the study and application of III-V semiconductor nanocrystals are limited by difficulties in their synthesis. In particular, it is difficult to control nucleation because the molecular bonds in III-V semiconductors are highly covalent. A synthetic approach of InP NQDs was presented using newly synthesized organometallic phosphorus [P] precursors with different functional moieties while preserving the P-Si bond. Introducing bulky side chains in our study improved the stability while facilitating InP formation with strong confinement at a readily low temperature regime (210°C to 300°C). Further shell coating with ZnS resulted in highly luminescent core-shell materials. The design and synthesis of P precursors for high-quality InP NQDs were conducted for the first time, and we were able to control the nucleation by varying the reactivity of P precursors, therefore achieving uniform large-sized InP NQDs. This opens the way for the large-scale production of high-quality Cd-free nanocrystal quantum dots