87 research outputs found
Absence of Magnetism in Hcp Iron-Nickel at 11 K
Synchrotron Mössbauer spectroscopy (SMS) was performed on an hcp-phase alloy of composition Fe92Ni8 at a pressure of 21 GPa and a temperature of 11 K. Density functional theoretical calculations predict antiferromagnetism in both hcp Fe and hcp Fe-Ni. For hcp Fe, these calculations predict no hyperfine magnetic field, consistent with previous experiments. For hcp Fe-Ni, however, substantial hyperfine magnetic fields are predicted, but these were not observed in the SMS spectra. Two possible explanations are suggested. First, small but significant errors in the generalized gradient approximation density functional may lead to an erroneous prediction of magnetic order or of erroneous hyperfine magnetic fields in antiferromagnetic hcp Fe-Ni. Alternately, quantum fluctuations with periods much shorter than the lifetime of the nuclear excited state would prohibit the detection of moments by SMS
Energy dispersive x-ray diffraction of charge density waves via chemical filtering
Pressure tuning of phase transitions is a powerful tool in condensed matter physics, permitting high-resolution studies while preserving fundamental symmetries. At the highest pressures, energy dispersive x-ray diffraction (EDXD) has been a critical method for geometrically confined diamond anvil cell experiments. We develop a chemical filter technique complementary to EDXD that permits the study of satellite peaks as weak as 10^(-4) of the crystal Bragg diffraction. In particular, we map out the temperature dependence of the incommensurate charge density wave diffraction from single-crystal, elemental chromium. This technique provides the potential for future GPa pressure studies of many-body effects in a broad range of solid state systems
Temperature and Pressure Dependence of the Fe-specific Phonon Density of States in Ba(Fe(1-x)Co(x))2As2
The {57}Fe-specific phonon density of states of Ba(Fe(1-x)Co(x))2As2 single
crystals (x=0.0, 0.08) was measured at cryogenic temperatures and at high
pressures with nuclear-resonant inelastic x-ray scattering. Measurements were
conducted for two different orientations of the single crystals, yielding the
orientation-projected {57}Fe-phonon density of states (DOS) for phonon
polarizations in-plane and out-of-plane with respect to the basal plane of the
crystal structure. In the tetragonal phase at 300 K, a clear stiffening was
observed upon doping with Co. Increasing pressure to 4 GPa caused a marked
increase of phonon frequencies, with the doped material still stiffer than the
parent compound. Upon cooling, both the doped and undoped samples showed a
stiffening, and the parent compound exhibited a discontinuity across the
magnetic and structural phase transition. These findings are generally
compatible with the changes in volume of the system upon doping, increasing
pressure, or increasing temperature, but an extra softening of high-energy
modes occurs with increasing temperature. First-principles computations of the
phonon DOS were performed and showed an overall agreement with the experimental
results, but underestimate the Grueneisen parameter. This discrepancy is
explained in terms of a magnetic Grueneisen parameter, causing an extra phonon
stiffening as magnetism is suppressed under pressure
Temperature and pressure dependence of the Fe-specific phonon density of states in Ba(Fe_(1−x)Co_x)_2As_2
The ^(57)Fe-specific phonon density of states (DOS) of Ba(Fe_(1−x)Co_x)_2As_2 single crystals (x=0.0,0.08) was measured at cryogenic temperatures and at high pressures with nuclear-resonant inelastic x-ray scattering. Measurements were conducted for two different orientations of the single crystals, yielding the orientation-projected ^(57)Fe-phonon density of states for phonon polarizations in-plane and out-of-plane with respect to the basal plane of the crystal structure. In the tetragonal phase at 300 K, a clear stiffening was observed upon doping with Co. Increasing pressure to 4 GPa caused a marked increase of phonon frequencies, with the doped material still stiffer than the parent compound. Upon cooling, both the doped and undoped samples showed a stiffening and the parent compound exhibited a discontinuity across the magnetic and structural phase transitions. These findings are generally compatible with the changes in volume of the system upon doping, increasing pressure, or increasing temperature, but an extra softening of high-energy modes occurs with increasing temperature. First-principles computations of the phonon DOS were performed and showed an overall agreement with the experimental results, but underestimate the Grüneisen parameter. This discrepancy is explained in terms of a magnetic Grüneisen parameter, causing an extra phonon stiffening as magnetism is suppressed under pressure
Effects of vacancies on phonon entropy of B2 FeAl
The phonon density of states (DOS) and phonon entropy of B2 FeAl were determined as functions of the Fe site vacancy concentration using several scattering techniques and were computed from first principles. Measurements at elevated temperature and pressure were performed to explore volume effects, test the usefulness of the quasiharmonic (QH) approximation, and provide comparison for the first-principles calculations. The average temperature and pressure dependencies of phonons were consistent with the QH model. The decrease in specific volume associated with the introduction of vacancies causes a stiffening of the DOS that was captured well with the experimentally determined Grüneisen parameter. Features associated with vacancies in the DOS are not well explained by this model, however, especially in the gap between the acoustic and optic branches. First-principles calculations indicated that these modes are primarily associated with vibrations of Al atoms in the first-nearest-neighbor shell of the vacancy, with some vibration amplitude also involving the second-nearest-neighbor Fe atoms. At the vacancy concentrations of study, the phonon entropy of vacancy formation was found to be approximately −1.7k_B/atom, about half as large and of opposite sign as the configurational entropy of vacancy formation
Melting of tantalum at high pressure determined by angle dispersive x-ray diffraction in a double-sided laser-heated diamond-anvil cell
The high pressure and high temperature phase diagram of Ta has been studied
in a laser-heated diamond-anvil cell (DAC) using x-ray diffraction measurements
up to 52 GPa and 3800 K. The melting was observed at nine different pressures,
being the melting temperature in good agreement with previous laser-heated DAC
experiments, but in contradiction with several theoretical calculations and
previous piston-cylinder apparatus experiments. A small slope for the melting
curve of Ta is estimated (dTm/dP = 24 K/GPa at 1 bar) and a possible
explanation for this behaviour is given. Finally, a P-V-T equation of states is
obtained, being the temperature dependence of the thermal expansion coefficient
and the bulk modulus estimated.Comment: 31 pages, 8 figures, to appear in J.Phys.:Cond.Matte
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