Insights on Structural Evolution and Charge Storage Mechanism of Na4Mn9O18 as Active Material for Aqueous Rechargeable Sodium-Ion Storage Systems

As a renewable and sustainable energy storage technology, aqueous rechargeable sodium-ion storage systems have raised great interest due to environmental friendliness, safety and low cost. Unlike conventional lithium-ion batteries, aqueous sodium-ion systems have some distinct advantages for large-scale stationary electric storage, such as the abundant natural resource of Na and the possibility to achieve long-term stability and reversibility. In addition, aqueous electrolytes are inherently safer and more eco-friendly than organic electrolytes [1]. On the other hand, the use of aqueous electrolytes poses significant challenges in the selection of electrode materials. First, their redox potentials should be within the electrochemical stability window of water. Second, the side reactions between electrode materials and H2O or residual O2 may tremendously affect their cyclic stability [2]. Among the different eligible materials, channeled structure Na4Mn9O18 (NMO) is still one of the most promising candidate as cathodic material for aqueous Na-ion storage systems, because of its abundance, low price ($7.6 kg-1[3]), relatively high theoretical capacity (121 mAh g-1), non-toxicity, and simple synthesis by different routes. However, this material has yet to be characterized in detail in terms of its storage mechanisms and stability performance in aqueous environment. In this study, we undertake an in depth characterization of the kinetics of NMO electrode processes in 1 M Na2SO4 electrolyte, within its safe potential window in thiselectrolyte, namely 0.25-1.1 VSHE, as defined in the present work. We use cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) to deconvolve the complex behavior of this system and discriminate the different contributions of double-layer capacitance, pseudocapacitance and sodium ion insertion to charge/discharge at varying potential. First, by the power law analysis of voltammetry we identify kinetic processes and make an evaluation of their respective contribution; then, the analysis and modeling of EIS measurements, performed at varying potential after equilibration of the system, allow us to calculate the currents associated with the above processes at varying potential and as a function of the frequency. In particular, the EIS method proves that the diffusional or intercalation contribution is dominant over the entire safe potential window. The latter methodology holds great promise to be a powerful tool for an effective deconvolution of the complex behavior of the NMO / aqueous electrolyte system, enabling an in depth understanding of the role of different processes in its dynamic performance

Hierarchical microchannel architecture in chitosan/bioactive glass scaffolds via electrophoretic deposition positive-replica

One of the main challenges in the design of scaffolds for cortical bone regeneration is mimicking the highly oriented, hierarchical structure of the native tissue in an efficient, simple, and consistent way. As a possible solution to this challenge, positive replica based on electrophoretic deposition (EPD) was here evaluated as a technique to produce organic/inorganic scaffolds with oriented micro-porosities mimicking Haversian canals diameter and spacing. Two different sizes of 45S5 bioactive glass (BG) powders were chosen as inclusions and loaded in a chitosan matrix via EPD on micro-patterned cathodes. Self-standing chitosan scaffolds, with a homogeneous dispersion of BG particles and regularly-oriented micro-channels (ϕ = 380 ± 50 μm, inter-channel spacing = 600 ± 40 μm), were obtained. In vitro analysis in simulated body fluid (SBF) revealed the ability to induce a deposition of a homogenous layer of hydroxyapatite (HA), with Ca/P nucleation reactions appearing kinetically favored by smaller BG particles. Cell interaction with hybrid scaffolds was evaluated in vitro with bone osteosarcoma cells (SAOS-2). The osteoconductive potential of EPD structures was assessed by evaluating cells proliferation, viability and scaffold colonization. Results indicate that EPD is a simple yet extremely effective technique to prepare composite micro-patterned structures and can represent a platform for the development of a new generation of bone scaffolds. © 2019 Wiley Periodicals, Inc. J Biomed Mater Res Part A, 2019