Crystal structure of a mixed-ligand dinuclear Ba—Zn complex with 2-methoxyethanol having triphenylacetate and chloride bridges

The dinuclear barium–zinc complex, μ-chlorido-1:2κ2Cl:Cl-chlorido-2κCl-bis(2-methoxyethanol-1κO)bis(2-methoxyethanol-1κ2O,O′)bis(μ-triphenylacetato-1:2κ2O:O′)bariumzinc, [BaZn(C20H15O2)2Cl2(C3H8O2)4], has been synthesized by the reaction of barium triphenylacetate, anhydrous zinc chloride and 2-methoxyethanol in the presence of toluene. The barium and zinc metal cations in the dinuclear complex are linked via one chloride anion and carboxylate O atoms of the triphenylacetate ligands, giving a Ba...Zn separation of 3.9335 (11) Å. The irregular nine-coordinate BaO8Cl coordination centres comprise eight O-atom donors, six of them from 2-methoxyethanol ligands (four from two bidentate O,O′-chelate interactions and two from monodentate interactions), two from bridging triphenylacetate ligands and one from a bridging Cl donor. The distorted tetrahedral coordination sphere of zinc comprises two O-atom donors from the triphenylacetate ligands and two Cl donors (one bridging and one terminal). In the crystal, O—H...Cl, O—H...O and C—H...Cl intermolecular interactions form a layered structure, lying parallel to (001)

New members in the [Mn10] supertetrahedron family

Two manganese complexes, [MnII4MnIII6Cl4(CH3OCH2CH2O)12 O4][MnII3TiIVCl6(CH3OCH2CH2O)6] (1) and [MnII4MnIII6Cl4(CH3OCH2CH2O)12O4] [Mn4II Cl10(CH3OCH2CH2OH)4]∙0.5CH3OCH2CH2OH, (2) have been obtained and characterized by single-crystal X-ray diffraction. Both structures consist of the decametallic dicationic [MnII4MnIII6Cl4(CH3OCH2CH2O)12O4]2 + core constructed by four vertex-sharing [MnIII3MnIIO]9 + tetrahedra. Also, these compounds contain the different tetrametallic dianions: [MnII3TiIVCl6(CH3OCH2CH2O)6]2 − (in complex 1) and [Mn4IICl10(CH3OCH2CH2OH)4]2 − (in complex 2). Magnetic dc and ac susceptibility measurements for compound (1) show that the dicationic decanuclear magnetic cluster possesses an S = 12 ± 1 spin ground-state