Continental growth histories revealed by detrital zircon trace elements: a case study from India

published_or_final_versio

Applications and limitations of U-Pb thermochronology to middle and lower crustal thermal histories

Volume diffusion of Pb occurs over micron length scales in apatite and rutile at temperatures relevant to the evolution of the middle and lower crust. Continuous thermal history information can be resolved from inversion of intracrystalline U-Pb date profiles preserved within individual grains. Recent developments in microbeam analysis permit rapid measurement of these age profiles at sub-micron spatial resolution, thus heralding a new era for U-Pb thermochronology. Here, we review the theoretical, experimental and empirical basis for U-Pb thermochronology and show that rutile, in particular, presents an exceptional opportunity to obtain high-resolution thermal history information from the deep crust. We present a Bayesian procedure that is well suited to the inversion of U-Pb date profile datasets and balances computational efficiency with a full search of thermal history coordinate space. Complications relevant to accurate application of U-Pb thermochronology are discussed i) theoretically and ii) empirically, using a rutile U-Pb dataset from the lower crust of the Grenville orogeny. Purely diffusive date profiles are shown to be the exception to uniform, or step-like, young profiles, suggesting that processes other than thermally-activated volume diffusion may control U-Pb systematics in rutile residing in the lower crust. However, the data obtained from apparent diffusive profiles systematically match cooling histories inferred from other thermochronometers. This result emphasises the importance of integrating microtextural observations, and trace-element concentrations, with U-Pb age data in order to discriminate between diffusive and non-diffusive Pb transport mechanisms in accessory phases and thus minimize the risk of generating spurious thermal histories

Noble gases recycled into the mantle through cold subduction zones

Subduction of hydrous and carbonated oceanic lithosphere replenishes the mantle volatile inventory. Substantial uncertainties exist on the magnitudes of the recycled volatile fluxes and it is unclear whether Earth surface reservoirs are undergoing net-loss or net-gain of H2O and CO2. Here, we use noble gases as tracers for deep volatile cycling. Specifically, we construct and apply a kinetic model to estimate the effect of subduction zone metamorphism on the elemental composition of noble gases in amphibole – a common constituent of altered oceanic crust. We show that progressive dehydration of the slab leads to the extraction of noble gases, linking noble gas recycling to H2O. Noble gases are strongly fractionated within hot subduction zones, whereas minimal fractionation occurs along colder subduction geotherms. In the context of our modelling, this implies that the mantle heavy noble gas inventory is dominated by the injection of noble gases through cold subduction zones. For cold subduction zones, we estimate a present-day bulk recycling efficiency, past the depth of amphibole breakdown, of 5–35% and 60–80% for 36Ar and H2O bound within oceanic crust, respectively. Given that hotter subduction dominates over geologic history, this result highlights the importance of cooler subduction zones in regassing the mantle and in affecting the modern volatile budget of Earth's interior

Noble gases recycled into the mantle through cold subduction zones

Subduction of hydrous and carbonated oceanic lithosphere replenishes the mantle volatile inventory. Substantial uncertainties exist on the magnitudes of the recycled volatile fluxes and it is unclear whether Earth surface reservoirs are undergoing net-loss or net-gain of H2O and CO2. Here, we use noble gases as tracers for deep volatile cycling. Specifically, we construct and apply a kinetic model to estimate the effect of subduction zone metamorphism on the elemental composition of noble gases in amphibole – a common constituent of altered oceanic crust. We show that progressive dehydration of the slab leads to the extraction of noble gases, linking noble gas recycling to H2O. Noble gases are strongly fractionated within hot subduction zones, whereas minimal fractionation occurs along colder subduction geotherms. In the context of our modelling, this implies that the mantle heavy noble gas inventory is dominated by the injection of noble gases through cold subduction zones. For cold subduction zones, we estimate a present-day bulk recycling efficiency, past the depth of amphibole breakdown, of 5–35% and 60–80% for 36Ar and H2O bound within oceanic crust, respectively. Given that hotter subduction dominates over geologic history, this result highlights the importance of cooler subduction zones in regassing the mantle and in affecting the modern volatile budget of Earth's interior