41 research outputs found
Interface Ferromagnetism in a SrMnO3/LaMnO3 Superlattice
Resonant soft x-ray absorption measurements at the O K edge on a
SrMnO3/LaMnO3 superlattice show a shoulder at the energy of doped holes, which
corresponds to the main peak of resonant scattering from the modulation in the
doped hole density. Scattering line shape at the Mn L3,2 edges has a strong
variation below the ferromagnetic transition temperature. This variation has a
period equal to half the superlattice superperiod and follows the development
of the ferromagnetic moment, pointing to a ferromagnetic phase developing at
the interfaces. It occurs at the resonant energies for Mn3+ and Mn4+ valences.
A model for these observations is presented, which includes a double-exchange
two-site orbital and the variation with temperature of the hopping frequency
tij between the two sites.Comment: 8.1 pages, 6 figure
Graded Orbital Occupation near Interfaces in a La2NiO4 - La2CuO4 Superlattice
X-ray absorption spectroscopy and resonant soft x-ray reflectivity show a
non-uniform distribution of oxygen holes in a La2NiO4 - La2CuO4 (LNO-LCO)
superlattice, with excess holes concentrated in the LNO layers. Weak
ferromagnetism with Tc = 160 K suggests a coordinated tilting of NiO6
octahedra, similar to that of bulk LNO. Ni d3z2-r2 orbitals within the LNO
layers have a spatially variable occupation. This variation of the Ni valence
near LNO-LCO interfaces is observed with resonant soft x-ray reflectivity at
the Ni L edge, at a reflection suppressed by the symmetry of the structure, and
is possible through graded doping with holes, due to oxygen interstitials taken
up preferentially by inner LNO layers. Since the density of oxygen atoms in the
structure can be smoothly varied with standard procedures, this orbital
occupation, robust up to at least 280 K, is tunable.Comment: 11 pages, 8 figure
Distinct oxygen hole doping in different layers of superlattices
X-ray absorption in (SCO-LCO)
superlattices shows a variable occupation with doping of a hole state different
from holes doped for in bulk
and suggests that this hole state is on apical oxygen atoms and polarized in
the plane. Considering the surface reflectivity gives a good qualitative
description of the line shapes of resonant soft X-ray scattering. The
interference between superlattice and surface reflections was used to
distinguish between scatterers in the SCO and the LCO layers, with the two hole
states maximized in different layers of the superlattice
Anomalous Enhancement of the Superconducting Transition Temperature in Electron-Doped Cuprate Heterostructures
The superconducting transition temperature of multilayers of
electron-doped cuprates, composed of underdoped (or undoped) and overdoped La%
CeCuO (LCCO) and PrCeCuO (PCCO) thin
films, is found to increase significantly with respect to the of the
corresponding single-phase films. By investigating the critical current density
of superlattices with different doping levels and layer thicknesses, we find
that the enhancement is caused by a redistribution of charge over an
anomalously large distance.Comment: 4 figures. To appear in PRB as a Rapid Communicatio
Two-step stabilization of orbital order and the dynamical frustration of spin in the model charge-transfer insulator KCuF3
We report a combined experimental and theoretical study of KCuF3, which
offers - because of this material's relatively simple lattice structure and
valence configuration (d9, i.e., one hole in the d-shell) - a particularly
clear view of the essential role of the orbital degree of freedom in governing
the dynamical coupling between the spin and lattice degrees of freedom. We
present Raman and x-ray scattering evidence that the phase behaviour of KCuF3
is dominated above the Neel temperature (T_N = 40 K) by coupled orbital/lattice
fluctuations that are likely associated with rotations of the CuF6 octahedra,
and we show that these orbital fluctuations are interrupted by a static
structural distortion that occurs just above T_N. A detailed model of the
orbital and magnetic phases of KCuF3 reveals that these orbital fluctuations -
and the related frustration of in-plane spin-order-are associated with the
presence of nearly degenerate low-energy spin-orbital states that are highly
susceptible to thermal fluctuations over a wide range of temperatures. A
striking implication of these results is that the ground state of KCuF3 at
ambient pressure lies near a quantum critical point associated with an
orbital/spin liquid phase that is obscured by emergent Neel ordering of the
spins; this exotic liquid phase might be accessible via pressure studies.Comment: 13 pages, 3 figure