Stability, Adsorption and Diffusion of CH4, CO2 and H2 in Clathrate Hydrates

We present a study of the adsorption and diffusion of CH4, CO2 and H2 molecules in clathrate hydrates using ab initio van der Waals density functional formalism [Dion et al. Phys. Rev. Lett. 92, 246401 (2004)]. We find that the adsorption energy is dominated by van der Waals interactions and that, without them, gas hydrates would not be stable. We calculate the maximum adsorption capacity as well as the maximum hydrocarbon size that can be adsorbed.The relaxation of the host lattice is essential for a good description of the diffusion activation energies, which are estimated to be of the order of 0.2, 0.4, and 1.0 eV for H2, CO2, and CH4, respectively.Comment: 4 pages, 4 figures, 3 table

The Road from Medical Injury to Claims Resolution: How No-Fault and Tort Differ

In the area of medical malpractice, no-fault has been offered as a response to the criticisms leveled against tort litigation for medical injuries. Five issues of no-fault are examined within the context of obstetrical malpractice

Force and energy dissipation variations in non-contact atomic force spectroscopy on composite carbon nanotube systems

UHV dynamic force and energy dissipation spectroscopy in non-contact atomic force microscopy were used to probe specific interactions with composite systems formed by encapsulating inorganic compounds inside single-walled carbon nanotubes. It is found that forces due to nano-scale van der Waals interaction can be made to decrease by combining an Ag core and a carbon nanotube shell in the Ag@SWNT system. This specific behaviour was attributed to a significantly different effective dielectric function compared to the individual constituents, evaluated using a simple core-shell optical model. Energy dissipation measurements showed that by filling dissipation increases, explained here by softening of C-C bonds resulting in a more deformable nanotube cage. Thus, filled and unfilled nanotubes can be discriminated based on force and dissipation measurements. These findings have two different implications for potential applications: tuning the effective optical properties and tuning the interaction force for molecular absorption by appropriately choosing the filling with respect to the nanotube.Comment: 22 pages, 6 figure

Dusty OB stars in the Small Magellanic Cloud - II: Extragalactic Disks or Examples of the Pleiades Phenomenon?

We use mid-infrared Spitzer spectroscopy and far-infrared Herschel photometry for a sample of twenty main sequence O9--B2 stars in the Small Magellanic Cloud (SMC) with strong 24 micron excesses to investigate the origin of the mid-IR emission. Either debris disks around the stars or illuminated patches of dense interstellar medium (ISM) can cause such mid-IR emission. In a companion paper, Paper I, we use optical spectroscopy to show that it is unlikely for any of these sources to be classical Be stars or Herbig Ae/Be stars. We focus our analysis on debris disks and cirrus hot spots. We find three out of twenty stars to be significantly extended in the mid-IR, establishing them as cirrus hot spots. We then fit the IR spectral energy distributions to determine dust temperatures and masses. We find the dust masses in the SMC stars to be larger than for any known debris disks, although this evidence against the debris disk hypothesis is circumstantial. Finally, we created a local comparison sample of bright mid-IR OB stars in the Milky Way (MW) by cross-matching the WISE and Hipparcos catalogs. All such local stars in the appropriate luminosity range that can be unambiguously classified are young stars with optical emission lines or are spatially resolved by WISE with sizes too large to be plausible debris disk candidates. We conclude that the very strong mid-IR flux excesses are most likely explained as cirrus hot spots, although we cannot rigorously rule out that a small fraction of the sample is made up of debris disks or transition disks. We present suggestive evidence that bow-shock heating around runaway stars may be a contributing mechanism to the interstellar emission. These sources, interpreted as cirrus hot spots, offer a new localised probe of diffuse interstellar dust in a low metallicity environment. (Abridged)Comment: Accepted for publication in ApJ, 23 pages, 11 figures, 8 table

Searching for magnetic monopoles trapped in accelerator material at the Large Hadron Collider

If produced in high energy particle collisions at the LHC, magnetic monopoles could stop in material surrounding the interaction points. Obsolete parts of the beam pipe near the CMS interaction region, which were exposed to the products of pp and heavy ion collisions, were analysed using a SQUID-based magnetometer. The purpose of this work is to quantify the performance of the magnetometer in the context of a monopole search using a small set of samples of accelerator material ahead of the 2013 shutdown.Comment: 11 page

A University Engagement Model for Achieving Technology Adoption and Performance Improvement in Healthcare, Manufacturing, and Government

The Purdue Technical Assistance Program (TAP) offers a model of university engagement and service that is achieving technology adoption and performance improvement impacts in health care, manufacturing, government, and other sectors. The TAP model focuses on understanding and meeting the changing and challenging needs of those served, always seeking to engage a mix of faculty, staff, students, and others that best meet these needs. Although the TAP mission is focused on the needs of those served, participating faculty and students have experienced significant benefits, and faculty rarely decline an opportunity to participate. This essay presents the evolution of Purdue University’s engagement and service missions, and their alignment with the current thinking of engagement scholars and practitioners. The operational model for TAP is described as an important part of Purdue’s engagement mission, along with the elements necessary for its success, examples of successful engagement, and future challenges and opportunities

Trap Target Studies

This research was sponsored by the National Science Foundation Grant NSF PHY-931478