Aleph System Seminar, de ExLibris, en Chipre

Sección: Noticias. Noticias externasDel 8 al 11 de Abril tuve la ocasión de asistir al Aleph System Seminar que cada dos años organiza la empresa productora de Aleph, ExLibris, que este año se ha celebrado en la ciudad chipriota de Limassol, en lugar de Tel-Aviv, como habitualmente, debido a razones obvias de seguridadN

Ebonex-Supported PtM Anode Catalysts for PEM Water Electrolysis

The work presents a research on the preparation of Pt-based bimetallic catalysts dispersed on commercial Magnelli phase titania (Ebonex@) by sol gel method and investigation of their activity toward the oxygen evolution reaction (OER) in polymer electrolyte membrane water electrolysis (PEMWE). The catalytic support is also used for preparation of a carbon-free gas diffusion layer (ET30) integrated in the oxygen electrode of the membrane electrode assembly (MEA). The performance characteristics of MEA with PtM/Ebonex on ET30 are investigated in a laboratory PEMWE and compared to those of MEA with commercial carbon-based GDL with the same anode catalyst. It is proven that the chemical nature and electron density of the second metal have an essential effect on the catalyst surface structure and properties, including the lattice parameter, particle size, and electronic surface state state which in turn, reflect on the electrochemical behavior and catalytic activity. The catalysts PtCr/Ebonex and PtMn/Ebonex having deficiency of electrons in the valent d-orbital do not form an alloy with Pt and have lower catalytic activity. In contrast, the metallic components in PtFe/Ebonex and PtCo/Ebonex form a solid solution which results in changes in the catalyst structure and surface electron state, leading to enhanced OER efficieny compared to pure Pt/Ebonex

Characterisation of MEAs for Electrochemical Energy Conversion Using an Easy Test Technique

The paper describes an EasyTest cell developed for simple, safe and inexpensive to run testing and optimisation of the active materials (catalysts, catalytic supports, polymer membrane electrolytes) and electrode structures utilized in PEM Fuel cells and Electrolysers. The main advantages of the new EasyTest technique are demonstrated by a comparative study on the performance of two types of membrane electrode assemblies for electrochemical energy conversion. Nafion and PBI-based polymer electrolyte membranes covered with catalytic layers containing 20 % Pt dispersed on carbon black (E-TEK, De Nora) are tested as hydrogen electrodes working in a fuel cell and an electrolyser mode at two characteristic temperatures, varying the total partial pressure in the cell. The PBI-based membrane electrode assembly (MEA) gives lower current densities compared to that containing Nafion, while its performance remains stable in a much broader potential range. At overpotentials of about = 300–350 mV the Nafion MEA reaches a limiting current density, while in the case of PBI-based MEA such an effect is not registered in the whole potential range tested

Nonlinear Coherent Magneto-Optical Response of a Single Chiral Carbon Nanotube

Published versio

The Hubble Constant from the Gravitational Lens B1608+656

We present a refined gravitational lens model of the four-image lens system B1608+656 based on new and improved observational constraints: (i) the three independent time-delays and flux-ratios from VLA observations, (ii) the radio-image positions from VLBA observations, (iii) the shape of the deconvolved Einstein Ring from optical and infrared HST images, (iv) the extinction-corrected lens-galaxy centroids and structural parameters, and (v) a stellar velocity dispersion, sigma_ap=247+-35 km/s, of the primary lens galaxy (G1), obtained from an echelle spectrum taken with the Keck--II telescope. The lens mass model consists of two elliptical mass distributions with power-law density profiles and an external shear, totaling 22 free parameters, including the density slopes which are the key parameters to determine the value of H_0 from lens time delays. This has required the development of a new lens code that is highly optimized for speed. The minimum-chi^2 model reproduces all observations very well, including the stellar velocity dispersion and the shape of the Einstein Ring. A combined gravitational-lens and stellar dynamical analysis leads to a value of the Hubble Constant of H_0=75(+7/-6) km/s/Mpc (68 percent CL; Omega_m=0.3, Omega_Lambda=0.7. The non-linear error analysis includes correlations between all free parameters, in particular the density slopes of G1 and G2, yielding an accurate determination of the random error on H_0. The lens galaxy G1 is ~5 times more massive than the secondary lens galaxy (G2), and has a mass density slope of gamma_G1=2.03(+0.14/-0.14) +- 0.03 (68 percent CL) for rho~r^-gamma', very close to isothermal (gamma'=2). (Abridged)Comment: 17 pages, 6 figures, 5 tables; revised version with correct fig.6 and clarified text based on referee report; conclusions unchange

Nature of Intra-night Optical Variability of BL Lacertae

We present the results of extensive multi-band intra-night optical monitoring of BL Lacertae during 2010--2012. BL Lacertae was very active in this period and showed intense variability in almost all wavelengths. We extensively observed it for a total for 38 nights; on 26 of them observations were done quasi-simultaneously in B, V, R and I bands (totaling 113 light curves), with an average sampling interval of around 8 minutes. BL Lacertae showed significant variations on hour-like timescales in a total of 19 nights in different optical bands. We did not find any evidence for periodicities or characteristic variability time-scales in the light curves. The intranight variability amplitude is generally greater at higher frequencies and decreases as the source flux increases. We found spectral variations in BL Lacertae in the sense that the optical spectrum becomes flatter as the flux increases but in several flaring states deviates from the linear trend suggesting different jet components contributing to the emission at different times.Comment: 12 Pages, 5 figures, 3 Tables, Accepted for Publication in MNRA

A novel non-carbon gas diffusion layer for PEM water electrolysis anodes

The work presents a research on the development of novel gas diffusion layer (GDL) suitable for application in PEM water electrolysis. The traditionally used carbon-based GDL is replaced by GDL containing sub-stoichiometry Mаgneli phase titanium oxide. The newly developed GDE is integrated in a membrane electrode assembly (MEA) containing highly active Pt catalyst and proton conductive polymer electrolyte membrane. The MEA performance is characterized in a laboratory PEM electrolyser at standard operative conditions by cyclic voltammetry and steady state polarization techniques. It is found that the new layer ensures excellent electrical conductivity and has very good stability at high anodic potentials. The determined morphology factors of the platinum catalyst however, show that further optimization of the porosity is required in order to improve the water transport to the reactive zone and the catalyst utilization

Analysis of the intra-night variability of BL Lacertae during its August 2020 flare

We present an analysis of the $BVRI$ photometry of the blazar BL Lacertae on diverse timescales from mid-July to mid-September 2020. We have used 11 different optical telescopes around the world and have collected data over 84 observational nights. The observations cover the onset of a new activity phase of BL Lacertae started in August 2020 (termed as the August 2020 flare by us), and the analysis is focused on the intra-night variability. On short-term timescales, (i) flux varied with ~2.2\,mag in $R$ band, (ii) the spectral index was found to be weakly dependent on the flux (i.e., the variations could be considered mildly chromatic) and (iii) no periodicity was detected. On intra-night timescales, BL Lacertae was found to show bluer-when-brighter chromatism predominantly. We also found two cases of significant inter-band time lags of the order of a few minutes. The duty cycle of the blazar during the August 2020 flare was estimated to be quite high (~90\% or higher). We decomposed the intra-night light curves into individual flares and determined their characteristics. On the basis of our analysis and assuming the turbulent jet model, we determined some characteristics of the emitting regions: Doppler factor, magnetic field strength, electron Lorentz factor, and radius. The radii determined were discussed in the framework of the Kolmogorov theory of turbulence. We also estimated the weighted mean structure function slope on intra-night timescales, related it to the slope of the power spectral density, and discussed it with regard to the origin of intra-night variability.Comment: 46 pages, 19 figures, 8 tables, accepted for publication in The Astrophysical Journal Supplement Series (manuscript version after proof correction