Fluctuation-induced Forces on Nanospheres in External Fields

We analyze the radiative forces between two dielectric nanospheres mediated via the quantum and thermal fluctuations of the electromagnetic field in the presence of an external drive. We generalize the scattering theory description of fluctuation forces to include external quantum fields, allowing them to be in an arbitrary quantum state. The known trapping and optical binding potentials are recovered for an external coherent state. We demonstrate that an external squeezed vacuum state creates similar potentials to a laser, despite its zero average intensity. Moreover, Schr\"odinger cat states of the field can enhance or suppress the optical potential depending on whether they are odd or even. Considering the nanospheres trapped by optical tweezers, we examine the total interparticle potential as a function of various experimentally relevant parameters, such as the field intensity, polarization, and phase of the trapping lasers. We demonstrate that an appropriate set of parameters could produce mutual bound states of the two nanospheres with potential depth as large as $\sim200$ K. Our results are pertinent to ongoing experiments with trapped nanospheres in the macroscopic quantum regime, paving the way for engineering interactions among macroscopic quantum systems

Collective radiation from distant emitters

Waveguides allow for direct coupling of emitters separated by large distances, offering a path to connect remote quantum systems. However, when facing the distances needed for practical applications, retardation effects due to the finite speed of light are often overlooked. Previous works studied the non-Markovian dynamics of emitters with retardation, but the properties of the radiated field remain mostly unexplored. By considering a toy model of two distant two-level atoms coupled through a waveguide, we observe that the spectrum of the radiated field exhibits non-Markovian features such as linewidth broadening beyond standard superradiance, or narrow Fano resonance-like peaks. We also show that the dipole-dipole interaction decays exponentially with distance as a result of retardation, with the range determined by the atomic linewidth. We discuss a proof-of-concept implementation of our results in a superconducting circuit platform.Comment: 13 pages, 6 figures, comments are welcom

Spontaneous Emission in the presence of Quantum Mirrors

Arrays of atoms coupled to waveguides can behave as mirrors. We consider an array of $\Lambda$-type three-level atoms wherein preparing the atoms in one ground state or another leads to reflection or transmission of the guided electromagnetic field; a superposition of the two ground states thus corresponds to a coherent superposition of mirror-like and transparent boundary conditions. We analyze the spontaneous emission of an excited two-level atom in the presence of such a quantum mirror, and inside a cavity formed by quantum mirrors, demonstrating that the resulting dynamics of the excited atom can exhibit exotic features, e.g., a superposition of Rabi cycle and exponential decay. Our results pave the way for exploring quantum electrodynamics (QED) phenomena in a paradigm wherein boundary conditions can exhibit quantum superpositions and correlations

Quantum Electrodynamics with Time-varying Dielectrics

We present a framework for quantization of electromagnetic field in the presence of dielectric media with time-varying optical properties. Considering a microscopic model for the dielectric as a collection of matter fields interacting with the electromagnetic environment, we allow for the possibility of dynamically varying light-matter coupling. We obtain the normal modes of the coupled light-matter degrees of freedom, showing that the corresponding creation and annihilation operators obey equal-time canonical commutation relations. We show that these normal modes can consequently couple to quantum emitters in the vicinity of dynamic dielectric media, and the resulting radiative properties of atoms are thus obtained. Our results are pertinent to time-varying boundary conditions realizable across a wide range of state-of-the-art physical platforms and timescales.Comment: 19 pages, 4 figure

Activating ZnO nanorods photoanodes in visible light by CdS surface sensitiser

Thin films of c-axis aligned uniform ZnO nanorods (NRs) were fabricated on to fluorine-doped tin oxide-coated soda lime glass substrate by a two-step chemical route. Thereafter ZnO NRs/CdS core shell structures were successfully synthesised by depositing CdS layer on top of vertically aligned ZnO NRs using less hazardous nanocrystal layer deposition technique. The presence of CdS in ZnO NRs/CdS core shell structures was confirmed by energy dispersive X-ray analysis. Examination of structure and morphology of the fabricated films by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) revealed that both films have one-dimensional hexagonal wurtzite structure. Optical properties evaluated from ultraviolet-visible and photoluminescence spectra demonstrated better photo response of ZnO NRs/CdS core shell structure with respect to bare ZnO NR structure. Optical to chemical conversion efficiency of ZnO NRs/CdS photoanode was found to be similar to 1.75 times higher than bare ZnO NRs photoanode in photo electrochemical water splitting under visible light

Scalar QED Model for Polarizable Particles in Thermal Equilibrium or in Hyperbolic Motion in Vacuum

We consider a scalar QED (quantum electrodynamics) model for the frictional force and the momentum fluctuations of a polarizable particle in thermal equilibrium with radiation or in hyperbolic motion in a vacuum. In the former case the loss of particle kinetic energy due to the frictional force is compensated by the increase in kinetic energy associated with the momentum diffusion, resulting in the Planck distribution when it is assumed that the average kinetic energy satisfies the equipartition theorem. For hyperbolic motion in vacuum the frictional force and the momentum diffusion are similarly consistent with an equilibrium with a Planckian distribution at the temperature T=ℏa/2πkBc. The quantum fluctuations of the momentum imply that it is only the average acceleration a that is constant when the particle is subject to a constant applied force

Radiative Properties of an Artificial Atom coupled to a Josephson Junction Array

We study the radiative properties -- the Lamb shift, Purcell decay rate and the spontaneous emission dynamics -- of an artificial atom coupled to a long, multimode cavity formed by an array of Josephson junctions. Introducing a tunable coupling element between the atom and the array, we demonstrate that such a system can exhibit a crossover from a perturbative to non-perturbative regime of light-matter interaction as one strengthens the coupling between the atom and the Josephson junction array (JJA). As a consequence, the concept of spontaneous emission as the occupation of the local atomic site being governed by a single complex-valued exponent breaks down. This breakdown, we show, can be interpreted in terms of formation of hybrid atom-resonator modes with radiative losses that are non-trivially related to the effective coupling between individual modes. We develop a singular function expansion approach for the description of the open quantum system dynamics in such a multimode non-perturbative regime. This modal framework generalizes the normal mode description of quantum fields in a finite volume, incorporating exact radiative losses and incident quantum noise at the delimiting surface. Our results are pertinent to recent experiments with Josephson atoms coupled to high impedance Josephson junction arrays

Activating ZnO nanorods photoanodes in visible light by CdS surface sensitiser

Thin films of c-axis aligned uniform ZnO nanorods (NRs) were fabricated on to fluorine-doped tin oxide-coated soda lime glass substrate by a two-step chemical route. Thereafter ZnO NRs/CdS core shell structures were successfully synthesised by depositing CdS layer on top of vertically aligned ZnO NRs using less hazardous nanocrystal layer deposition technique. The presence of CdS in ZnO NRs/CdS core shell structures was confirmed by energy dispersive X-ray analysis. Examination of structure and morphology of the fabricated films by X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) revealed that both films have one-dimensional hexagonal wurtzite structure. Optical properties evaluated from ultraviolet–visible and photoluminescence spectra demonstrated better photo response of ZnO NRs/CdS core shell structure with respect to bare ZnO NR structure. Optical to chemical conversion efficiency of ZnO NRs/CdS photoanode was found to be ∼1.75 times higher than bare ZnO NRs photoanode in photo electrochemical water splitting under visible light

Investigation of Mechanical and Tribological Behaviors of Aluminum Based Hybrid Metal Matrix Composite and Multi-Objective Optimization

Aluminum metal matrix composites are potential materials for aerospace and automobile industrial applications due to their enhanced mechanical and tribological properties. Aluminum reinforced with silicon carbide particles has been developed with enhanced mechanical and tribological behavior, but it lacks wettability between matrix and reinforcement causing weak bonding, which reduces the degree of enhancement. The objectives of this study were to fabricate aluminum-based metal matrix composites with enhanced wettability at varying stirring speeds (350, 450, 550 rpm), stirring time (5, 10, 15 min), weight percentage of SiC (0, 5, 10 wt.%), and weight percentage of MoS2 (0, 2, 4 wt.%). Nine samples were fabricated using stir casting based on Taguchi L9 orthogonal array. Hardness, tensile strength, and wear rate of the developed composite were investigated and analyzed as a single response characteristic using Taguchi’s signal-to-noise ratio and as a multi-response characteristic using hybrid Taguchi–grey relational analysis (HTGRA). The results revealed that the addition of SiC in the composite produced better hardness, tensile strength, and wear rate. The addition of MoS2 in the composite showed better hardness and tensile strength only up to 2 wt.% of MoS2, and in the case of wear rate, the addition of MoS2 in the composite up to 4% showed better wear resistance. Al–SiC–MoS2 hybrid composite shows better enhancement in hardness, tensile strength, and wear resistance than the Al–SiC composite