2,464 research outputs found

    Are the renormalized band widths in TTF-TCNQ of structural or electronic origin? - An angular dependent NEXAFS study

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    We have performed angle-dependent near-edge x-ray absorption fine structure measurements in the Auger electron yield mode on the correlated quasi-one-dimensional organic conductor TTF-TCNQ in order to determine the orientation of the molecules in the topmost surface layer. We find that the tilt angles of the molecules with respect to the one-dimensional axis are essentially the same as in the bulk. Thus we can rule out surface relaxation as the origin of the renormalized band widths which were inferred from the analysis of photoemission data within the one-dimensional Hubbard model. Thereby recent theoretical results are corroborated which invoke long-range Coulomb repulsion as alternative explanation to understand the spectral dispersions of TTF-TCNQ quantitatively within an extended Hubbard model.Comment: 6 pages, 5 figure

    Re-entrant spin glass and magnetoresistance in Co_{0.2}Zn_{0.8}Fe_{1.6}Ti_{0.4}O_4 spinel oxide

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    We have investigated the static and dynamic response of magnetic clusters in Co_{0.2}Zn_{0.8}Fe_{1.6}Ti_{0.4}O_4 spinel oxide, where a sequence of magnetic phase transitions, i.e., paramagnetic (PM) to ferromagnetic at T_{C} ≤\leq 270K and ferromagnetic to canted spin glass state at T_f \leq$ 125K is observed

    One-Electron Singular Branch Lines of the Hubbard Chain

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    The momentum and energy dependence of the weight distribution in the vicinity of the one-electron spectral-function singular branch lines of the 1D Hubbard model is studied for all values of the electronic density and on-site repulsion UU. To achieve this goal we use the recently introduced pseudofermion dynamical theory. Our predictions agree quantitatively for the whole momentum and energy bandwidth with the peak dispersions observed by angle-resolved photoelectron spectroscopy in the quasi-1D organic conductor TTF-TCNQ.Comment: Replaced with shortened version; 4 figure

    Profiling the interface electron gas of LaAlO3/SrTiO3 heterostructures by hard X-ray photoelectron spectroscopy

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    The conducting interface of LaAlO3_3/SrTiO3_3 heterostructures has been studied by hard X-ray photoelectron spectroscopy. From the Ti~2pp signal and its angle-dependence we derive that the thickness of the electron gas is much smaller than the probing depth of 4 nm and that the carrier densities vary with increasing number of LaAlO3_3 overlayers. Our results point to an electronic reconstruction in the LaAlO3_3 overlayer as the driving mechanism for the conducting interface and corroborate the recent interpretation of the superconducting ground state as being of the Berezinskii-Kosterlitz-Thouless type.Comment: 4 pages, 4 figure

    Muon-spin relaxation measurements on the dimerized spin-1/2 chains NaTiSi2O6 and TiOCl

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    We report muon spin relaxation (muSR) and magnetic susceptibility investigations of two Ti3+ chain compounds which each exhibit a spin gap at low temperature, NaTiSi2O6 and TiOCl. From these we conclude that the spin gap in NaTiSi2O6 is temperature independent, with a value of 2*Delta=660(50)K, arising from orbital ordering at Too = 210K; the associated structural fluctuations activate the muon spin relaxation rate up to temperatures above 270K. In TiOCl we find thermally activated spin fluctuations corresponding to a spin gap 2*Delta=420(40)K below Tc1=67K. We also compare the methods used to extract the spin gap and the concentration of free spins within the samples from muSR and magnetic susceptibility data.Comment: 4 pages, 3 figure

    Microscopic origin of the mobility enhancement at a spinel/perovskite oxide heterointerface revealed by photoemission spectroscopy

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    The spinel/perovskite heterointerface Îł\gamma-Al2_2O3_3/SrTiO3_3 hosts a two-dimensional electron system (2DES) with electron mobilities exceeding those in its all-perovskite counterpart LaAlO3_3/SrTiO3_3 by more than an order of magnitude despite the abundance of oxygen vacancies which act as electron donors as well as scattering sites. By means of resonant soft x-ray photoemission spectroscopy and \textit{ab initio} calculations we reveal the presence of a sharply localized type of oxygen vacancies at the very interface due to the local breaking of the perovskite symmetry. We explain the extraordinarily high mobilities by reduced scattering resulting from the preferential formation of interfacial oxygen vacancies and spatial separation of the resulting 2DES in deeper SrTiO3_3 layers. Our findings comply with transport studies and pave the way towards defect engineering at interfaces of oxides with different crystal structures.Comment: Accepted as Rapid Communications in Physical Review

    Electronic structure of the quasi-one-dimensional organic conductor TTF-TCNQ

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    We study the electronic structure of the quasi-one-dimensional organic conductor TTF-TCNQ by means of density-functional band theory, Hubbard model calculations, and angle-resolved photoelectron spectroscopy (ARPES). The experimental spectra reveal significant quantitative and qualitative discrepancies to band theory. We demonstrate that the dispersive behavior as well as the temperature-dependence of the spectra can be consistently explained by the finite-energy physics of the one-dimensional Hubbard model at metallic doping. The model description can even be made quantitative, if one accounts for an enhanced hopping integral at the surface, most likely caused by a relaxation of the topmost molecular layer. Within this interpretation the ARPES data provide spectroscopic evidence for the existence of spin-charge separation on an energy scale of the conduction band width. The failure of the one-dimensional Hubbard model for the {\it low-energy} spectral behavior is attributed to interchain coupling and the additional effect of electron-phonon interaction.Comment: 18 pages, 9 figure
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