Recent advances in metathesis-derived polymers containing transition metals in the side chain

This account critically surveys the field of side-chain transition metal-containing polymers as prepared by controlled living ring-opening metathesis polymerization (ROMP) of the respective metal-incorporating monomers. Ferrocene- and other metallocene-modified polymers, macromolecules including metal-carbonyl complexes, polymers tethering early or late transition metalcomplexes, etc. are herein discussed. Recent advances in the design and syntheses reported mainly during the last three years arehighlighted, with special emphasis on new trends for superior applications of these hybrid materials

ROMP synthesis of iron-containing organometallic polymers

The paper overviews iron-containing polymers prepared by controlled “living” ring-opening metathesis polymerization (ROMP). Developments in the design and synthesis of this class of organometallic polymers are highlighted, pinpointing methodologies and newest trends in advanced applications of hybrid materials based on polymers functionalized with iron motifs