TEXTURE ANALYSIS OF QUARTZITE BY WHOLE PATTERN DECONVOLUTION

The recently developed RITA concept combines algorithms of the Rietveld structure analysis with those from modern texture analysis in order to get texture information from d-spacing diffraction spectra. It is demonstrated for a low symmetry material (quartz) and a minimum pole sphere covering by the measured spectra. The quality of the results underlines the efficiency of this new approach especially for time-of-flight neutron diffraction studies where access to the beam is limited. New interesting aspects for crystal structure refinement are discussed

Elastic anisotropy modeling of Kimmeridge shale

Anisotropy of elastic properties in clay-rich sedimentary rocks has been of long-standing interest. These rocks are cap rocks of oil and gas reservoirs, as well as seals for carbon sequestration. Elasticity of shales has been approached by direct velocity measurements and by models based on microstructures. Here we are revisiting the classical Kimmeridge shale studied by Hornby (1998) by first quantifying microstructural features such as phase volume fractions, grain shapes and grain orientations, and pore distributions with advanced analytical methods and then using this information in different models to explain bulk elastic properties. It is shown that by application of a self-consistent algorithm based on Eshelby's (1957) model of inclusions in a homogeneous medium, it is possible to explain most experimental elastic constants, though some discrepancies remain which may be due to the interpretation of experimental data. Using a differential effective medium approach, an almost perfect agreement with experimental stiffness coefficients can be obtained, though the physical basis of this method may be questionable. The influence of single crystal elastic properties, grain shapes, preferred orientation, and volume and shapes of pores on elastic properties of shale is explored. © 2013. American Geophysical Union. All Rights Reserved

The influence of grain shape and volume fraction of sheet silicates on elastic properties of aggregates: Biotite platelets in an isotropic matrix

Elastic anisotropy of sheet-silicate-rich rocks such as shalesand slates strongly depends on the orientation distribution ofplatelet-shaped minerals, as well as shape and orientation ofpores. Bulk elastic anisotropy of the rock results in the anisotropywith respect to the propagation of elastic waves, and consequently,the fastest P-waves can travel with velocities exceedingthe slowest velocities by a factor of two or even greater. An importantfactor is the sheet-silicate's grain shapes.We approacheda model system of biotite platelets in an isotropic matrix withdifferent methods: A mean-field self-consistent method thatconsidered ellipsoidal particles in an effective anisotropic matrix,and a full-field method based on fast Fourier transformsthat considered the microstructure, the topology of the polycrystal,and local interactions. Both methods provided numericallyvery close results. Using these results, we predicted that the aggregatewith more oblate grain shape (thinner platelets) waselastically more anisotropic than the material with grains of lessoblate shape, but only for small volume fractions of orientedplatelets. For large fractions of platelets, the opposite was true.This switchover in the elastic anisotropy depended on texturestrength, platelet shape, and elastic properties of the isotropicmatrix