Pt/Pd Decorate MOFs Derived Co-N-C Materials as High-Performance Catalysts for Oxygen Reduction Reaction

We report here, a strategy to prepare Pt/Pd nanoparticles decorated with Co-N-C materials, where Co-N-C was obtained via pyrolysis of ZIF-67 directly. As-prepared Pt/Pd/Co-N-C catalysts showed excellent ORR performance, offered with a higher limit current density (6.6 mA cm−2) and similar half-wave potential positive (E1/2 = 0.84 V) compared with commercial Pt/C. In addition to an ORR activity, it also exhibits robust durability. The current density of Pt/Pd/Co-N-C decreased by only 9% after adding methanol, and a 10% current density loss was obtained after continuous testing at 36,000 s

Pt/Pd Decorate MOFs Derived Co-N-C Materials as High-Performance Catalysts for Oxygen Reduction Reaction

We report here, a strategy to prepare Pt/Pd nanoparticles decorated with Co-N-C materials, where Co-N-C was obtained via pyrolysis of ZIF-67 directly. As-prepared Pt/Pd/Co-N-C catalysts showed excellent ORR performance, offered with a higher limit current density (6.6 mA cm−2) and similar half-wave potential positive (E1/2 = 0.84 V) compared with commercial Pt/C. In addition to an ORR activity, it also exhibits robust durability. The current density of Pt/Pd/Co-N-C decreased by only 9% after adding methanol, and a 10% current density loss was obtained after continuous testing at 36,000 s

The Biomass of Pig-Blood-Derived Carbon as a Novel Electrode Material for Hydrogen Peroxide Electrochemical Sensing

In the work, a pig-blood-derived mesoporous carbon (BC) was prepared as a novel Fe-N-C material for the electrochemical sensor to detect hydrogen peroxide. Because of the unique nanostructure of Fe-BCs with rough surface structure, hierarchical pores, and high graphitization degree, the Fe-BCs, as a kind of advanced electrode material, exhibited remarkable performance in electrocatalysis. The sensor based on Fe-BCs exhibited an extra-long range from c and a detection limit of 0.046 μM (S/N = 3). The synthesis of low-cost, advanced carbon-based electrode materials from environmentally friendly pig blood for electrochemical sensor construction is a promising approach

Fe–Decorated Nitrogen–Doped Carbon Nanospheres as an Electrochemical Sensing Platform for the Detection of Acetaminophen

In this work, Fe–decorated nitrogen–doped carbon nanospheres are prepared for electrochemical monitoring of acetaminophen. Via a direct pyrolysis of the melamine–formaldehyde resin spheres, the well–distributed Fe–NC spheres were obtained. The as–prepared Fe–NC possesses enhanced catalysis towards the redox of acetaminophen for abundant active sites and high–speed charge transfer. The effect of loading Fe species on the electrochemical sensing of acetaminophen is investigated in detail. The synergistic effect of nitrogen doping along with the above–mentioned properties is taken advantage of in the fabrication of electrochemical sensors for the acetaminophen determination. Based on the calibration plot, the limits of detection (LOD) were calculated to be 0.026 μM with a linear range from 0–100 μM. Additionally satisfactory repeatability, stability, and selectivity are obtained

The Biomass of Pig-Blood-Derived Carbon as a Novel Electrode Material for Hydrogen Peroxide Electrochemical Sensing

In the work, a pig-blood-derived mesoporous carbon (BC) was prepared as a novel Fe-N-C material for the electrochemical sensor to detect hydrogen peroxide. Because of the unique nanostructure of Fe-BCs with rough surface structure, hierarchical pores, and high graphitization degree, the Fe-BCs, as a kind of advanced electrode material, exhibited remarkable performance in electrocatalysis. The sensor based on Fe-BCs exhibited an extra-long range from c and a detection limit of 0.046 μM (S/N = 3). The synthesis of low-cost, advanced carbon-based electrode materials from environmentally friendly pig blood for electrochemical sensor construction is a promising approach

Recent Advances on Heteroatom-Doped Porous Carbon—Based Electrocatalysts for Oxygen Reduction Reaction

Polymer electrolyte membrane fuel cells are considered one of the alternatives to fossil energy sources. The slow kinetics of the oxygen reduction reaction (ORR) at the cathode and the high price of Pt-based catalysts remain one of the key challenges for the commercial viability of proton exchange membrane fuel cells. However, their high cost and susceptibility to poisoning severely limit their use for large-scale commercial applications in fuel cells. Heteroatom-doped porous carbon has attracted extensive attention from scientists due to its advantages such as high specific surface area and the properties conferred by heteroatom doping. On the one hand, we discuss a variety of current methods for the preparation of heteroatom-doped porous carbons, including the template method and the activation method. On the other hand, we discuss the application of heteroatom-doped porous carbon in Pt catalysts, transition metal catalysts and metal-free catalysts. Finally, we also present the pre-existing and challenges of heteroatoms in ORR catalysis, which will drive the development of ORR catalysts