Physico-chemical properties of some polymer blended task specific novel S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflate and 1-(2-propoxy)- 3-methylimdazolium-borohydride room temperature ionic liquids

Two novel chiral ionic liquids S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflate and 1-(2-propoxy)-3-methylimdazolium-borohydride have been prepared using conventional metathesis reaction. These ionic liquids have been subjected to solution cast method followed by ultrasonication to obtain the corresponding ionic liquid gel polymer electrolytes with poly (vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP), free-standing, rubbery, dimensionally stable films with a high degree of transparency have been obtained. Thermo-gravimetric analysis confirms that the intermediate solvent, acetone used for mixing PVDF-HFP polymer with ionic liquid is completely evaporated after gelation and drying process. Further thermal properties have been analyzed by differential scanning calorimetry. Scanning electron microscopy micrographs show the different surface morphology of the gel electrolytes according to nature of the ionic liquid. The structural information has been extracted by X-ray diffraction. The ionic conductivities of both polymer-ionic liquid blends are in the order of 10-3 to 10-5 S cm-1. Electrochemical stability window of these polymer electrolytes ranges from 4.0 to 5.0 V. Various physicochemical properties and fast ion conduction in the gel polymer membranes show their promising characteristics as electrolytes in different ionic devices

Validity of abundances derived from spaxel spectra of the MaNGA survey

We measured the emission lines in the spaxel spectra of MaNGA galaxies in order to determine the abundance distributions therein. It has been suggested that the strength of the low-ionization lines, R_2, N_2, and S_2 may be increased (relative to Balmer lines) in (some) spaxel spectra of the MaNGA survey due to a contribution of the radiation of the diffuse ionized gas. Consequently, the abundances derived from the spaxel spectra through strong-line methods may suffer from large errors. We examined this expectation by comparing the behaviour of the line intensities and the abundances estimated through different calibrations for slit spectra of HII regions in nearby galaxies, for fibre spectra from the SDSS, and for spaxel spectra of the MaNGA survey. We found that the S_2 strength is increased significantly in the fibre and spaxel spectra. The mean enhancement changes with metallicity and can be as large as a factor of 2. The mean distortion of R_2 and N_2 is less than a factor of 1.3. This suggests that Kaufmann et al.'s demarcation line between AGNs and HII regions in the BPT diagram is a useful criterion to reject spectra with significantly distorted strengths of the N_2 and R_2 lines. We find that the three-dimensional R calibration, which uses the N_2 and R_2 lines, produces reliable abundances in the MaNGA galaxies. The one-dimensional N2 calibration produces either reliable or wrong abundances depending on whether excitation and N/O abundance ratio in the target region (spaxel) are close to or differ from those parameters in the calibrating points located close to the calibration relation. We then determined abundance distributions within the optical radii in the discs of 47 MaNGA galaxies. The optical radii of the galaxies were estimated from the surface brightness profiles constructed based on the MaNGA observations.Comment: 19 pages, 15 figures, accepted for publication in A&

Circumnuclear regions of different BPT types in star-forming MaNGA galaxies: AGN detectability

We consider the circumnuclear regions of MaNGA galaxies. The spectra are classified as AGN-like, HII-region-like (or SF-like), and intermediate (INT) spectra according to their positions on the BPT diagram. There are the following four configurations of the radiation distributions in the circumnuclear regions: 1) AGN+INT, the innermost region of the AGN-like radiation is surrounded by a ring of radiation of the intermediate type; 2) INT, the central area of radiation of the intermediate type; 3) SF+INT, the inner region of the HII-region-like radiation is surrounded by a ring of radiation of the intermediate type; and 4) SF, the HII-region-like radiation only. The LINERS of configurations 1 and 2 are examined. The spaxel spectra of the LINERs form a sequences on the BPT diagram. The line ratios change smoothly with radius, from AGN-like at the center to HII-region-like at larger distances. This is in agreement with the paradigm that the LINERs are excited by AGN activity. The AGN and INT radiation in the circumnuclear region is accompanied by an enhanced gas velocity dispersion, s_g. The radius of the area of the AGN and INT radiation is similar to the radius of the area with enhanced s_g, and the central s_g,c correlates with the luminosity of the AGN+INT area. We assume that the gas velocity dispersion can serve as an indicator of the AGN activity. The values of s_g,c for the SF-type centers partly overlap with those of the AGN-type centers. We find that there is a demarcation line between the positions of the AGN-type and SF-type objects on the s_g,c - central Halpha surface brightness diagram.Comment: 17 pages, 14 figures, accepted for publication in the A&

On the Ginzburg-Landau Analysis of the Upper Critical Field Hc2 in MgB2

Temperature dependence of the upper critical field Hc2 (T) for the superconducting magnesium diboride, MgB2, is studied in the vicinity of Tc by using a two-band Ginzburg-Landau (G-L) theory. The temperature dependence of Hc2 (T) near Tc exhibits a positive curvature. In addition, the calculated temperature dependence and its higher order derivatives are also shown to be in a good agreement with the experimental data. In analogy with the multi-band character of Eliashberg microscopic theory, the positive curvature of Hc2 (T) is described reasonably by solving the two-band of G-L theory.Comment: 14 pages, 2 figures, submitted to SUST November 200

Peculiar motions of the gas at the centre of the barred galaxy UGC 4056

We derive the circular velocity curves of the gaseous and stellar discs of UGC 4056, a giant barred galaxy with an active galactic nucleus (AGN). We analyse UGC 4056 using the 2D spectroscopy obtained within the framework of the Mapping Nearby Galaxies at APO (MaNGA) survey. Using images and the colour index g-r from the Sloan Digital Sky Survey (SDSS), we determined the tilt of the galaxy, which allows us to conclude that the galaxy rotates clockwise with trailing spiral arms. We found that the gas motion at the central part of the UGC 4056 shows peculiar features. The rotation velocity of the gaseous disc shows a bump within around three kiloparsecs while the rotation velocity of the stellar disc falls smoothly to zero with decreasing galactocentric distance. We demonstrate that the peculiar radial velocities in the central part of the galaxy may be caused by the inflow of the gas towards the nucleus of the galaxy. The unusual motion of the gas takes place at the region with the AGN-like radiation and can be explained by the gas response to the bar potential.Comment: 11 pages, 10 figures, 1 table, accepted for publication in A&

Coexistence of Superconductivity and Charge Density Wave in SrPt2As2

SrPt2As2 is a novel arsenide superconductor, which crystallizes in the CaBe2Ge2-type structure as a different polymorphic form of the ThCr2Si2-type structure. SrPt2As2 exhibits a charge-density-wave (CDW) ordering at about 470 K and enters into a superconducting state at Tc = 5.2 K. The coexistence of superconductivity and CDW refers to Peierls instability with a moderately strong electron-phonon interaction. Thus SrPt2As2 can be viewed as a nonmagnetic analog of iron-based superconductors, such as doped BaFe2As2, in which superconductivity emerges in close proximity to spin-density-wave ordering.Comment: 4 pages, 5 figure

Implications of reflectance measurements on the mechanism for superconductivity in MgB2_2

Recent optical studies in c-axis oriented superconducting MgB$_2$ films indicate that the electron-phonon coupling is weak [tu01]. We reinforce this conclusion by examining the raw reflectance data; its frequency dependence is incompatible with strong electron-phonon scattering. This is further strengthened by analysis of the real part of the conductivity, and by the temperature dependence of the effective Drude scattering rate. Using a realistic electron-phonon spectral shape [kong01], we find $\lambda_{\rm tr} \approx 0.15$, in agreement with Tu et al. [tu01]. To the extent that $\lambda_{\rm tr} \approx \lambda$, this disagrees sharply with model calculations [kong01,kortus01,an01], and is far too low to provide the means for $T_c = 39$ K. A simple model is constructed with coupling to a high frequency excitation, which is consistent with both the low frequency optical data and the high $T_c$.Comment: 4 pages, 4 figure