2,145 research outputs found
Physico-chemical properties of some polymer blended task specific novel S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflate and 1-(2-propoxy)- 3-methylimdazolium-borohydride room temperature ionic liquids
Two novel chiral ionic liquids S-(+)-2-3-dihydroxy-N, N, N-tributyl-propanaminiumtriflate and 1-(2-propoxy)-3-methylimdazolium-borohydride have been prepared using conventional metathesis reaction. These ionic liquids have been subjected to solution cast method followed by ultrasonication to obtain the corresponding ionic liquid gel polymer electrolytes with poly (vinylidene fluoride-co-hexafluoropropene) (PVDF-HFP), free-standing, rubbery, dimensionally stable films with a high degree of transparency have been obtained. Thermo-gravimetric analysis confirms that the intermediate solvent, acetone used for mixing PVDF-HFP polymer with ionic liquid is completely evaporated after gelation and drying process. Further thermal properties have been analyzed by differential scanning calorimetry. Scanning electron microscopy micrographs show the different surface morphology of the gel electrolytes according to nature of the ionic liquid. The structural information has been extracted by X-ray diffraction. The ionic conductivities of both polymer-ionic liquid blends are in the order of 10-3 to 10-5 S cm-1. Electrochemical stability window of these polymer electrolytes ranges from 4.0 to 5.0 V. Various physicochemical properties and fast ion conduction in the gel polymer membranes show their promising characteristics as electrolytes in different ionic devices
On the Ginzburg-Landau Analysis of the Upper Critical Field Hc2 in MgB2
Temperature dependence of the upper critical field Hc2 (T) for the
superconducting magnesium diboride, MgB2, is studied in the vicinity of Tc by
using a two-band Ginzburg-Landau (G-L) theory. The temperature dependence of
Hc2 (T) near Tc exhibits a positive curvature. In addition, the calculated
temperature dependence and its higher order derivatives are also shown to be in
a good agreement with the experimental data. In analogy with the multi-band
character of Eliashberg microscopic theory, the positive curvature of Hc2 (T)
is described reasonably by solving the two-band of G-L theory.Comment: 14 pages, 2 figures, submitted to SUST November 200
Surface effects in multiband superconductors. Application to MgB
Metals with many bands at the Fermi level can have different band dependent
gaps in the superconducting state. The absence of translational symmetry at an
interface can induce interband scattering and modify the superconducting
properties. We dicuss the relevance of these effects to recent experiments in
MgB
Coexistence of Superconductivity and Charge Density Wave in SrPt2As2
SrPt2As2 is a novel arsenide superconductor, which crystallizes in the
CaBe2Ge2-type structure as a different polymorphic form of the ThCr2Si2-type
structure. SrPt2As2 exhibits a charge-density-wave (CDW) ordering at about 470
K and enters into a superconducting state at Tc = 5.2 K. The coexistence of
superconductivity and CDW refers to Peierls instability with a moderately
strong electron-phonon interaction. Thus SrPt2As2 can be viewed as a
nonmagnetic analog of iron-based superconductors, such as doped BaFe2As2, in
which superconductivity emerges in close proximity to spin-density-wave
ordering.Comment: 4 pages, 5 figure
Superconductivity in the Ferroquadrupolar State in the Quadrupolar Kondo Lattice PrTiAl
The cubic compound PrTiAl is a quadrupolar Kondo lattice system
that exhibits quadrupolar ordering due to the non-Kramers ground
doublet and has strong hybridization between and conduction electrons. Our
study using high-purity single crystal reveals that PrTiAl exhibits
type-II superconductivity at mK in the nonmagnetic
ferroquadrupolar state. The superconducting critical temperature and field
phase diagram suggests moderately enhanced effective mass of
Theory of the Optical Conductivity in the Cuprate Superconductors
We present a study of the normal state optical conductivity in the cuprate
superconductors using the nearly antiferromagnetic Fermi liquid (NAFL)
description of the magnetic interaction between their planar quasiparticles. We
find that the highly anisotropic scattering rate in different regions of the
Brillouin zone, both as a function of frequency and temperature, a benchmark of
NAFL theory, leads to an average relaxation rate of the Marginal Fermi Liquid
form for overdoped and optimally doped systems, as well as for underdoped
systems at high temperatures. We carry out numerical calculations of the
optical conductivity for several compounds for which the input spin fluctuation
parameters are known. Our results, which are in agreement with experiment on
both overdoped and optimally doped systems, show that NAFL theory explains the
anomalous optical behavior found in these cuprate superconductors.Comment: REVTEX file, 8 PostScript figure
Fluctuation Study of the Specific Heat of MgB2
The specific heat of polycrystalline MgB has been measured with
high resolution ac calorimetry from 5 to 45 K at constant magnetic fields. The
excess specific heat above T is discussed in terms of Gaussian
fluctuations and suggests that MgB is a bulk superconductor with
Ginzburg-Landau coherence length \AA . The transition-width
broadening in field is treated in terms of lowest-Landau-level (LLL)
fluctuations. That analysis requires that \AA . The underestimate
of the coherence length in field, along with deviations from 3D LLL
predictions, suggest that there is an influence from the anisotropy of B
between the c-axis and the a-b plane.Comment: Phys. Rev. B 66, 134515 (2002
Magnetoresistivity and Complete in
Detailed magneto-transport data on dense wires of are reported for
applied magnetic fields up to 18 T. The temperature and field dependencies of
the electrical resistivity are consistent with behaving like a simple
metal and following a generalized form of Kohler's rule. In addition, given the
generally high values and narrow resistive transition widths associated
with synthesized in this manner, combined with applied magnetic fields
of up to 18 T, an accurate and complete curve could be determined.
This curve agrees well with curves determined from lower field measurements on
sintered pellets and wires of . is linear in over a wide
range of temperature (7 K 32 K) and has an upward curvature for
close to . These features are similar to other high , clean limit,
boron-bearing intermetallics: and .Comment: minor changes in styl
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