49 research outputs found

    Molecular Structure and Crystal Packing of n-Type Semiconducting Material 3\u27,3\u27-(1,4-Phenylene) bis {2\u27-(4-trifluoromethyl) phenyl} acrylonitrile

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    The exact molecular structure and the crystal packing of the n-type semiconducting material 3′,3′-(1,4-phenylene)bis{2′-(4-trifluoromethyl)phenyl}acrylonitrile was determined by a single crystal X-ray diffraction with twin treatment technique. The air-stable product was crystallized from dichloromethane-hexane mixed solution. The solid-state structure is the example of a typical π-π stacking with side intermolecular CN–H short contact networks

    A Steady Operation of n-Type Organic Thin-Film Transistors with Cyano-Substituted Distyrylbenzene Derivative

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    A novel n-type organic semiconductor, cyano-substituted distyrylbenzene derivative, 1,4-bis2-[4-(trifluoromethyl)phenyl]acrylonitorilebenzene, was synthesized by Knoevenagel condensation with aldehyde and acetonitrile derivatives. Fabricated thin-film transistors (TFTs) exhibited high electron field-effect mobility of 10-2?10-1 cm2 V-1 s-1, on/off current ratio of 6×105. Hysteresis-free n-type transport characteristics observed in this device promises a steady operation of organic logic circuit. Almost same TFT characteristic was observed even after 1 month storage in ambient condition. The findings indicate that the material has a good resistance to atmospheric oxidants

    Design Criterion of Reinforcement on Thick Soft Clay Foundations of Traditional Construction Method in Indonesia

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    It is commonplace that the ground near river is thickly covered with soft clay. Thus, in order to prevent it from the natural hazard, it is necessary that local people construct a robust embankment of countermeasure by constructing river bank in the soft ground, with low level of bearing capacity. To solve the problem aforementioned, local people are widely known to apply traditional method such as timber or bamboo pile. To establish this method, the Ministry of Public Works has published a technical guideline for reinforced soft ground before embankment. The guideline shows the process of mattress construction including: 1) cutting the ground for site preparation; 2) installing timber piles; 3) laying geo-grid on top of the piles and; 4) putting and compacting a granular material on the geo-grid. The guideline assists engineers to construct an embankment on the mattress. Unfortunately, the guideline never details a reasonable design based on geotechnical engineering. Hence, this paper aims to propose and discuss, a criterion of bearing capacity of reinforced soft clay using several empirical calculations. The model cases were simulated for small footings subjected by static loading on the mattress. As a result, the calculations will lead to the criterion of allowable bearing capacity of reinforced soft clay with timber pile

    Design Criterion of Reinforcement on Thick Soft Clay Foundations of Traditional Construction Method in Indonesia

    No full text
    It is commonplace that the ground near river is thickly covered with soft clay. Thus, in order to prevent it from the natural hazard, it is necessary that local people construct a robust embankment of countermeasure by constructing river bank in the soft ground, with low level of bearing capacity. To solve the problem aforementioned, local people are widely known to apply traditional method such as timber or bamboo pile. To establish this method, the Ministry of Public Works has published a technical guideline for reinforced soft ground before embankment. The guideline shows the process of mattress construction including: 1) cutting the ground for site preparation; 2) installing timber piles; 3) laying geo-grid on top of the piles and; 4) putting and compacting a granular material on the geo-grid. The guideline assists engineers to construct an embankment on the mattress. Unfortunately, the guideline never details a reasonable design based on geotechnical engineering. Hence, this paper aims to propose and discuss, a criterion of bearing capacity of reinforced soft clay using several empirical calculations. The model cases were simulated for small footings subjected by static loading on the mattress. As a result, the calculations will lead to the criterion of allowable bearing capacity of reinforced soft clay with timber pile
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