11,179 research outputs found
Origin of the Mosaicity in Graphene Grown on Cu(111)
We use low-energy electron microscopy to investigate how graphene grows on
Cu(111). Graphene islands first nucleate at substrate defects such as step
bunches and impurities. A considerable fraction of these islands can be
rotationally misaligned with the substrate, generating grain boundaries upon
interisland impingement. New rotational boundaries are also generated as
graphene grows across substrate step bunches. Thus, rougher substrates lead to
higher degrees of mosaicity than do flatter substrates. Increasing the growth
temperature improves crystallographic alignment. We demonstrate that graphene
growth on Cu(111) is surface diffusion limited by comparing simulations of the
time evolution of island shapes with experiments. Islands are dendritic with
distinct lobes, but unlike the polycrystalline, four-lobed islands observed on
(100)-textured Cu foils, each island can be a single crystal. Thus, epitaxial
graphene on smooth, clean Cu(111) has fewer structural defects than it does on
Cu(100).Comment: Article revised following reviewer comment
Local moment, itinerancy and deviation from Fermi liquid behavior in NaCoO for
Here we report the observation of Fermi surface (FS) pockets via the
Shubnikov de Haas effect in NaCoO for and 0.84,
respectively. Our observations indicate that the FS expected for each compound
intersects their corresponding Brillouin zones, as defined by the previously
reported superlattice structures, leading to small reconstructed FS pockets,
but only if a precise number of holes per unit cell is \emph{localized}. For
the coexistence of itinerant carriers and localized spins on a paramagnetic triangular superlattice leads at low temperatures
to the observation of a deviation from standard Fermi-liquid behavior in the
electrical transport and heat capacity properties, suggesting the formation of
some kind of quantum spin-liquid ground state.Comment: 4 pages, 4 figure
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