Preparation and Characterization of Stimuli-Responsive Magnetic Nanoparticles

In this work, the main attention was focused on the synthesis of stimuli-responsive magnetic nanoparticles (SR-MNPs) and the influence of glutathione concentration on its cleavage efficiency. Magnetic nanoparticles (MNPs) were first modified with activated pyridyldithio. Then, MNPs modified with activated pyridyldithio (MNPs-PDT) were conjugated with 2, 4-diamino-6-mercaptopyrimidine (DMP) to form SR-MNPs via stimuli-responsive disulfide linkage. Fourier transform infrared spectra (FTIR), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) were used to characterize MNPs-PDT. The disulfide linkage can be cleaved by reduced glutathione (GHS). The concentration of glutathione plays an important role in controlling the cleaved efficiency. The optimum concentration of GHS to release DMP is in the millimolar range. These results had provided an important insight into the design of new MNPs for biomedicine applications, such as drug delivery and bio-separation

Study on Stress Relief of Hard Roof Based on Presplitting and Deep Hole Blasting

For the problem that the hard roof causes wider end-mining coal pillar, and the roadway is greatly affected by mining, this paper took Shanxi Luning Coal Mine as the engineering background; based on the stress distribution characteristics of the coal pillar, the calculation method of the limit end-mining coal pillar size was given; considering the formation conditions and transmission forms of the advanced abutment stress, a method combining presplitting and deep hole blasting was proposed to weaken the advanced abutment stress. The numerical simulation was used to analyze the stress distribution of coal pillars, which was verified by on-site industrial tests. The results showed that the presplitting can achieve the blocking of stress. The closer it is to the peak of the abutment stress, the better the blocking effect. Deep hole blasting can weaken the source of the advanced abutment stress and reduce the peak of abutment stress. With the combination of the two blasting methods, the end-mining coal pillar size of Luning Coal Mine can be reduced to 60 m. The method combining presplitting and deep hole blasting can effectively reduce the end-mining coal pillar size and reduce the impact of mining on the deformation of the dip roadway

Analysis of Failure Characteristics and Strength Criterion of Coal-Rock Combined Body with Different Height Ratios

In underground mining and roadway support engineering of coal mine, the coal and rock layers bear loads together; therefore, the deformation and mechanical characteristics of the coal-rock combined bodies are not the same as those of the pure coal or rock bodies. In this paper, conventional triaxial compression tests of coal-rock combined bodies with different height ratios were conducted. And the stress and deformation characteristics of coal-rock combined body were studied and the experimental results were analyzed with different strength criteria. The results show that the peak stress, elastic modulus, and strength reduction coefficient of coal-rock combined body are negatively correlated with the ratio of coal to coal-rock combination height and positively correlated with the confining pressure; the coal-rock combination shows obvious ductility under 10 MPa confining pressure. Under the conventional triaxial condition, the shear failure was the main cause of the lateral deformation of the coal body in the coal-rock combination, which was much larger than that of the rock body. The circle deformation value, volume strain value, and the deformation rate in the postpeak stage of coal-rock combination are much higher than those in the prepeak stage. Mohr–Coulomb and general Hoek–Brown strength criterion fit the experimental results well

Study on the Porosity of Saturated Fragmentized Coals during Creep Process and Constitutive Relation

Pore abundance and deformation characteristics of saturated fragmentized coals during creep process are of significant meaning to the study on ground sediment in the mined-out area. The law of porosity variation of saturated fragmentized coals during creep process and its creep constitutive model were studied by using the self-developed multiphase coupling creep test device. And, results have indicated that the porosity logarithm of fragmentized coal during creep process shows a linear negative correlation with the time ln(n−a) = −ct + lnb, and the porosity decrease is evidently divided into three phases. In addition, when the stress level is relatively low, the porosity decreases slowly; when the stress level rises up, the porosity decreases quickly; when the stress level remains stable finally, the porosity is smaller. Under the equal stress, as the grain size of fragmentized coals decreases, the porosity tends to decrease, and as the grain size of fragmentized coal tends to be stable, the porosity tends to increase; the creep constitutive equation of fragmentized coals with different grain sizes was established by using the Kelvin–Voigt model, and the correlation analysis shows that the Kelvin–Voigt creep model of fragmentized coals is reasonable

Particle Flow Code Simulation of the Characteristics of Crack Evolution in Rock-Like Materials with Bent Cracks

The distribution and propagation of rock cracks have a significant impact on geotechnical engineering. Taking rock-like materials with bent cracks as the research object, the particle flow code in two dimensions numerical simulation method was used to study the impact of the bend number on rock-like materials strength and crack evolution. According to the results, when the bend number was 1, 3, and 7, the strength of the specimens gradually increased; the elasticity modulus did not change significantly with the crack bend number. Uniaxial compression generated tensile cracks in all the specimens with bent cracks, but in terms of failure mode, the specimens with 0 bend tended to suffer penetrating failure along the fracture strike, while the specimens with 1, 3, and 7 bend tended to suffer penetrating failure along the diagonal direction. Both the fractal dimension and bend number were positively correlated with strain; with the gradual increase of the stress percentage, the damage variable of the specimens gradually increased at a growing rate. The research results provide a reference for predicting the stability of the underground engineering surrounding rocks containing bent cracks

Competitive adsorption law of multi-component gases during CO2 displacement of CH4 in coal seams

The CO2 enhanced coal bed methane recovery technology provides an excellent way to mitigate the greenhouse effect and energy crisis. The features and mechanism of CO2/CH4 competitive adsorption in the coal rock matrix have a critical impact on the production of CBM. For CO2/CH4 competitive adsorption process components and pressure changes, a multi-component gases competitive adsorption experiment was carried out with CO2 and CH4 binary gases as the study objects, and a multi-component adsorption model was developed by the expanded Langmuir equation. Based on the principles of molecular dynamics and thermodynamics, important parameters such as the average free range of gas molecules and adsorption potential are introduced to explain the competitive adsorption behavior from multiple perspectives and explore the competitive adsorption law of CH4 and CO2 under multiple component conditions, so as to provide some theoretical basis and field guidance for improving the extraction effect of CH4 in coal seams. The results show that: Under two critical conditions (100%CO2 +0%CH4 and 0%CO2 +100%CH4), the Langmuir volumes of CO2 for HN 1/3 coking coal and HL weakly caking coal respectively are 2.21 and 3.01 times higher than those of CH4; the overall adsorption capacity of binary gas is in between the adsorption capacities of both critical conditions and increases with increasing CO2 concentration in the gas source ratio; using E-L equation for binary gas component partitioning, the CH4 partition curves were all below CO2, the concentration of free-phase CH4 was always higher than that in the adsorbed phase, and coal samples had stronger adsorption ability for CO2 than CH4. CO2 has a stronger adsorption potential at the surface for HL weakly caking coal. CH4 has a slightly stronger adsorption potential at the surface for HN 1/3 coking coal. The higher coalification degree of the coal sample, the stronger the adsorption ability for CH4 and the weaker the adsorption ability for CO2. The slope of the overall adsorption curve of multi-component gases is analogous to the slope of the component with a high ratio of gas or strong adsorption capacity; the capacity of one-component adsorption for dual gas is closely related to the partial pressure of the free-phase gas and the separation factor α21. When the concentration ratio of CH4/CO2 in free phase is y2/y1 =α21, the concentration of both gases in adsorption phase is 50%, and α21 correlation is weakened, then the free phase gas partial pressure is dominant and there is a threshold value makes CH4 and CO2 adsorption capacity equal; when y2/y1 α21, the coal preferentially adsorbs CH4 in the binary gas

Strengthening effects of Al element on strength and impact toughness in titanium alloy

Pure Ti and binary Ti–6Al alloy have been employed as the investigated targets of our research. The strengthening effects of Al element on strength and impact toughness in titanium alloy were systematically investigated. The experimental results indicated that the addition of Al element significantly improved the tensile strength while deteriorating the plasticity and impact toughness. Analysis of deformation mechanisms indicated that addition of Al element strongly inhibited the dislocation movement and deformation twinning in titanium alloy. The theoretical results demonstrated that the dissolution of Al atoms reset the atomic bond configurations and electronic structures of the α-Ti lattice. Therefore, the lattice resistance to dislocation nucleation and dislocation gliding was significantly improved which led to the strong strengthening effect of Al element in α-Ti. The lattice resistance to the shearing atomic motion of deformation twinning was also improved due to the dissolution of Al atoms. Moreover, the strengthening of Al element was revealed at the electronic level by employing the empirical electron theory (EET) of solids and molecules. The strengthening effects of Al element in titanium was also quantitatively evaluated according to the valence electron structure (VES) parameters. A prediction model for the tensile strength of α-type Ti-xAl alloys was proposed based on the quantitative strengthening of Al element. The high accuracy of the prediction model for strength of Ti-xAl alloy was verified by the average error (3.58%) between the computational strength and experimental results

Controlling the Deformation of a Small Coal Pillar Retaining Roadway by Non-Penetrating Directional Pre-Splitting Blasting with a Deep Hole: A Case Study in Wangzhuang Coal Mine

In longwall mining of coal mines, the large deformation of small pillar retaining roadways creates difficulties for the safe and efficient retreating of the mining panel. Based on the engineering background of a small coal pillar retaining roadway in Wangzhuang coal mine, pressure relief technology for non-penetrating directional pre-splitting blasting with a deep hole ahead was proposed. The influence of the non-penetrating fracture length on the pre-splitting effect was studied by numerical simulation. The results showed that the vertical stress in the coal pillar center, the small pillar retaining roadway deformation, and the energy accumulation on the pillar decreased with an increase in the non-penetrating fracture length. The vertical stress at the working face end increased with an increase in the non-penetrating fracture length. The field application and monitoring results indicated that non-penetrating directional pre-splitting blasting could effectively control the deformation of small pillar retaining roadways. The roof-to-floor and rib-to-rib maximum convergences of the 6208 tail entry were reduced by 53.66% and 52.62%, respectively, compared to the results with no blasting. The roadway section met the demands of mining panel high-efficiency retreating, thereby demonstrating the rationality of the technical and numerical simulation results. The research results shed light on the improvement of small coal pillar retaining roadway maintenance theory and technology