Transition of amorphous to crystalline oxide film in initial oxide overgrowth on liquid metals

It is important to understand the mechanism of oxidation in the initial stage on the free surface of liquid metals. Mittemeijer and co-workers recently developed a thermodynamic model to study the oxide overgrowth on a solid metal surface. Based on this model, we have developed a thermodynamic model to analyse the thermodynamic stability of oxide overgrowth on liquid metals. The thermodynamic model calculation revealed that the amorphous oxide phase is thermodynamically preferred up to 1.3 and 0.35 nm respectively, in the initial oxide overgrowth on liquid Al and Ga at the corresponding melting point. However, the amorphous phase is thermodynamically unstable in the initial oxide overgrowth on liquid Mg. The thermodynamic stability of amorphous phase in the Al and Ga oxide systems is attributed to lower sums of surface and interfacial energies for amorphous phases, compared to that of the corresponding crystalline phases.Financial support under grant EP/H026177/1 from the EPSRC was used

Digital Accessibility in Iran: An Investigation Focusing on Iran\u27s National Policies on Accessibility and Disability Support

Digital accessibility has become an important topic in the field of HCI, but when looking at accessibility on a global scale, we find that the representation of accessibility research is mostly centered in the Global North with countries that are WEIRD (Western, Educated, Industrialized, Rich, and Democratic). Our paper explores digital accessibility in Iran, focusing exclusively on its national policies on accessibility. Iran is a non-WEIRD country located in the Global South, with no reports on its digital accessibility status from the Global Initiative for Inclusive Information and Communication Technologies (G3ict). We found that there is not enough focus on accessibility in Iran\u27s regulations and we conclude our paper by recommending directions for improving this situation such as HCI and disability organizations in Iran cooperating with G3ict

Exploring Accessibility Features and Plug-ins for Digital Prototyping Tools

Many digital systems are found to be inaccessible and a large part of the issue is that accessibility is not considered early enough in the design process. Digital prototyping tools are a powerful resource for designers to quickly explore both low and high fidelity design mockups during initial stages of product design and development. We evaluated 10 popular prototyping tools to understand their built-in and third-party accessibility features. We found that accessible design support is largely from third-party plug-ins rather than prototyping tools\u27 built-in features, and the availability of accessibility support varies from tool to tool. There is potential to improve accessible design by increasing the potential for accessibility to be consider earlier in the design process

Website Builders Still Contribute To Inaccessible Web Design

Website builders enable individuals without design or technical skills to create websites. However, it is unclear if modern websites created by website builders meet accessibility standards. We reviewed six popular website building platforms and found a lack of accessibility support. Wix provided the most comprehensive accessibility documentation and robust accessibility features. However, during an accessibility audit of 90 Wix webpages, we found many accessibility issues, raising concerns about how users are supported

Global Optical Control of a Quantum Spin Chain

Quantum processors which combine the long decoherence times of spin qubits together with fast optical manipulation of excitons have recently been the subject of several proposals. I show here that arbitrary single- and entangling two-qubit gates can be performed in a chain of perpetually coupled spin qubits solely by using laser pulses to excite higher lying states. It is also demonstrated that universal quantum computing is possible even if these pulses are applied {\it globally} to a chain; by employing a repeating pattern of four distinct qubit units the need for individual qubit addressing is removed. Some current experimental qubit systems would lend themselves to implementing this idea.Comment: 5 pages, 3 figure

Phase transitions of a tethered surface model with a deficit angle term

Nambu-Goto model is investigated by using the canonical Monte Carlo simulations on fixed connectivity surfaces of spherical topology. Three distinct phases are found: crumpled, tubular, and smooth. The crumpled and the tubular phases are smoothly connected, and the tubular and the smooth phases are connected by a discontinuous transition. The surface in the tubular phase forms an oblong and one-dimensional object similar to a one-dimensional linear subspace in the Euclidean three-dimensional space R^3. This indicates that the rotational symmetry inherent in the model is spontaneously broken in the tubular phase, and it is restored in the smooth and the crumpled phases.Comment: 6 pages with 6 figure

Particle Acceleration and Magnetic Dissipation in Relativistic Current Sheet of Pair Plasmas

We study linear and nonlinear development of relativistic and ultrarelativistic current sheets of pair plasmas with antiparallel magnetic fields. Two types of two-dimensional problems are investigated by particle-in-cell simulations. First, we present the development of relativistic magnetic reconnection, whose outflow speed is an order of the light speed c. It is demonstrated that particles are strongly accelerated in and around the reconnection region, and that most of magnetic energy is converted into "nonthermal" part of plasma kinetic energy. Second, we present another two-dimensional problem of a current sheet in a cross-field plane. In this case, the relativistic drift kink instability (RDKI) occurs. Particle acceleration also takes place, but the RDKI fast dissipates the magnetic energy into plasma heat. We discuss the mechanism of particle acceleration and the theory of the RDKI in detail. It is important that properties of these two processes are similar in the relativistic regime of T > mc^2, as long as we consider the kinetics. Comparison of the two processes indicates that magnetic dissipation by the RDKI is more favorable process in the relativistic current sheet. Therefore the striped pulsar wind scenario should be reconsidered by the RDKI.Comment: To appear in ApJ vol. 670; 60 pages, 27 figures; References and typos are fixe

Controlling for Confounders in Multimodal Emotion Classification via Adversarial Learning

Various psychological factors affect how individuals express emotions. Yet, when we collect data intended for use in building emotion recognition systems, we often try to do so by creating paradigms that are designed just with a focus on eliciting emotional behavior. Algorithms trained with these types of data are unlikely to function outside of controlled environments because our emotions naturally change as a function of these other factors. In this work, we study how the multimodal expressions of emotion change when an individual is under varying levels of stress. We hypothesize that stress produces modulations that can hide the true underlying emotions of individuals and that we can make emotion recognition algorithms more generalizable by controlling for variations in stress. To this end, we use adversarial networks to decorrelate stress modulations from emotion representations. We study how stress alters acoustic and lexical emotional predictions, paying special attention to how modulations due to stress affect the transferability of learned emotion recognition models across domains. Our results show that stress is indeed encoded in trained emotion classifiers and that this encoding varies across levels of emotions and across the lexical and acoustic modalities. Our results also show that emotion recognition models that control for stress during training have better generalizability when applied to new domains, compared to models that do not control for stress during training. We conclude that is is necessary to consider the effect of extraneous psychological factors when building and testing emotion recognition models.Comment: 10 pages, ICMI 201

Electron spin coherence in metallofullerenes: Y, Sc and La@C82

Endohedral fullerenes encapsulating a spin-active atom or ion within a carbon cage offer a route to self-assembled arrays such as spin chains. In the case of metallofullerenes the charge transfer between the atom and the fullerene cage has been thought to limit the electron spin phase coherence time (T2) to the order of a few microseconds. We study electron spin relaxation in several species of metallofullerene as a function of temperature and solvent environment, yielding a maximum T2 in deuterated o-terphenyl greater than 200 microseconds for Y, Sc and La@C82. The mechanisms governing relaxation (T1, T2) arise from metal-cage vibrational modes, spin-orbit coupling and the nuclear spin environment. The T2 times are over 2 orders of magnitude longer than previously reported and consequently make metallofullerenes of interest in areas such as spin-labelling, spintronics and quantum computing.Comment: 5 pages, 4 figure

Liesegang patterns: Effect of dissociation of the invading electrolyte

The effect of dissociation of the invading electrolyte on the formation of Liesegang bands is investigated. We find, using organic compounds with known dissociation constants, that the spacing coefficient, 1+p, that characterizes the position of the n-th band as x_n ~ (1+p)^n, decreases with increasing dissociation constant, K_d. Theoretical arguments are developed to explain these experimental findings and to calculate explicitly the K_d dependence of 1+p.Comment: RevTex, 8 pages, 3 eps figure