Fabrication and magnetic properties of granular Co/porous InP nanocomposite materials

A novel Co/InP magnetic semiconductor nanocomposite was fabricated by electrodeposition magnetic Co nanoparticles into n-type porous InP templates in ethanol solution of cobalt chloride. The content or particle size of Co particles embedded in porous InP increased with increasing deposition time. Co particles had uniform distribution over pore sidewall surface of InP template, which was different from that of ceramic template and may open up new branch of fabrication of nanocomposites. The magnetism of such Co/InP nanocomposites can be gradually tuned from diamagnetism to ferromagnetism by increasing the deposition time of Co. Magnetic anisotropy of this Co/InP nanocomposite with magnetization easy axis along the axis of InP square channel was well realized by the competition between shape anisotropy and magnetocrystalline anisotropy. Such Co/InP nanocomposites with adjustable magnetism may have potential applications in future in the field of spin electronics

Facile synthesis of superhydrophobic surface of ZnO nanoflakes: chemical coating and UV-induced wettability conversion

This work reports an oriented growth process of two-dimensional (2D) ZnO nanoflakes on aluminum substrate through a low temperature hydrothermal technique and proposes the preliminary growth mechanism. A bionic superhydrophobic surface with excellent corrosion protection over a wide pH range in both acidic and alkaline solutions was constructed by a chemical coating treatment with stearic acid (SA) molecules on ZnO nanoflakes. It is found that the superhydrophobic surface of ZnO nanoflake arrays shows a maximum water contact angle (CA) of 157° and a low sliding angle of 8°, and it can be reversibly switched to its initial superhydrophilic state under ultraviolet (UV) irradiation, which is due to the UV-induced decomposition of the coated SA molecules. This study is significant for simple and inexpensive building of large-scale 2D ZnO nanoflake arrays with special wettability which can extend the applications of ZnO films to many other important fields

Fabrication and ultraviolet photoresponse characteristics of ordered SnOx (x ≈ 0.87, 1.45, 2) nanopore films

Based on the porous anodic aluminum oxide templates, ordered SnOx nanopore films (approximately 150 nm thickness) with different x (x ≈ 0.87, 1.45, 2) have been successfully fabricated by direct current magnetron sputtering and oxidizing annealing. Due to the high specific surface area, this ordered nanopore films exhibit a great improvement in recovery time compared to thin films for ultraviolet (UV) detection. Especially, the ordered SnOx nanopore films with lower x reveal higher UV light sensitivity and shorter current recovery time, which was explained by the higher concentration of the oxygen vacancies in this SnOx films. This work presents a potential candidate material for UV light detector

Morphology-dependent field emission properties and wetting behavior of ZnO nanowire arrays

The fabrication of three kinds of ZnO nanowire arrays with different structural parameters over Au-coated silicon (100) by facile thermal evaporation of ZnS precursor is reported, and the growth mechanism are proposed based on structural analysis. Field emission (FE) properties and wetting behavior were revealed to be strongly morphology dependent. The nanowire arrays in small diameter and high aspect ratio exhibited the best FE performance showing a low turn-on field (4.1 V/μm) and a high field-enhancement factor (1745.8). The result also confirmed that keeping large air within the films was an effective way to obtain super water-repellent properties. This study indicates that the preparation of ZnO nanowire arrays in an optimum structural model is crucial to FE efficiency and wetting behavior

Variable pitch approach for performance improving of straight-bladed VAWT at rated tip speed ratio

This paper presents a new variable pitch (VP) approach to increase the peak power coefficient of the straight-bladed vertical-axis wind turbine (VAWT), by widening the azimuthal angle band of the blade with the highest aerodynamic torque, instead of increasing the highest torque. The new VP-approach provides a curve of pitch angle designed for the blade operating at the rated tip speed ratio (TSR) corresponding to the peak power coefficient of the fixed pitch (FP)-VAWT. The effects of the new approach are exploited by using the double multiple stream tubes (DMST) model and Prandtl’s mathematics to evaluate the blade tip loss. The research describes the effects from six aspects, including the lift, drag, angle of attack (AoA), resultant velocity, torque, and power output, through a comparison between VP-VAWTs and FP-VAWTs working at four TSRs: 4, 4.5, 5, and 5.5. Compared with the FP-blade, the VP-blade has a wider azimuthal zone with the maximum AoA, lift, drag, and torque in the upwind half-cycle, and yields the two new larger maximum values in the downwind half-cycle. The power distribution in the swept area of the turbine changes from an arched shape of the FP-VAWT into the rectangular shape of the VP-VAWT. The new VP-approach markedly widens the highest-performance zone of the blade in a revolution, and ultimately achieves an 18.9% growth of the peak power coefficient of the VAWT at the optimum TSR. Besides achieving this growth, the new pitching method will enhance the performance at TSRs that are higher than current optimal values, and an increase of torque is also generated

Enhanced electrochemical performance of CuCo2S4/carbon nanotubes composite as electrode material for supercapacitors

CuCo2S4 is regarded as a promising electrode material for supercapacitor, but has inferior conductivity and poor cycle stability which restrict its wide-range applications. In this work, hierarchically hybrid composite of CuCo2S4/carbon nanotubes (CNTs) was synthesized using a facile hydrothermal and sulfuration process. The embedded CNTs in the CuCo2S4 matrix provided numerous effective paths for electron transfer and ion diffusion, and thus promoted the faradaic reactions of the CuCo2S4 electrode in the energy storage processes. The CuCo2S4/CNTs-3.2% electrode exhibited a significantly increased specific capacitance of 557.5 F g-1 compared with those of the pristine CuCo2S4 electrode (373.4 F g-1) and CuO/Co3O4/CNTs-3.2% electrode (356.5 F g-1) at a current density of 1 A g-1. An asymmetric supercapacitor (ASC) was assembled using the CuCo2S4/CNTs-3.2% as the positive electrode and the active carbon as the negative electrode, which exhibited an energy density of 23.2 Wh kg-1 at a power density of 402.7 W kg-1. Moreover, the residual specific capacitance of this ASC device retained 85.7 % of its original value after tested for 10000 cycles, indicating its excellent cycle stability

Development of a CFD-Based Wind Turbine Rotor Optimization Tool in Considering Wake Effects

In the present study, a computational fluid dynamic (CFD)-based blade optimization algorithm is introduced for designing single or multiple wind turbine rotors. It is shown that the CFD methods provide more detailed aerodynamics features during the design process. Because high computational cost limits the conventional CFD applications in particular for rotor optimization purposes, in the current paper, a CFD-based 2D Actuator Disc (AD) model is used to represent turbulent flows over wind turbine rotors. With the ideal case of axisymmetric flows, the simulation time is significantly reduced with the 2D method. The design variables are the shape parameters comprising the chord, twist, and relative thickness of the wind turbine rotor blades as well as the rotational speed. Due to the wake effects, the optimized blade shapes are different for the upstream and downstream turbines. The comparative aerodynamic performance is analyzed between the original and optimized reference wind turbine rotor. The results show that the present numerical optimization algorithm for multiple turbines is efficient and more advanced than conventional methods. The current method achieves the same accuracy as 3D CFD simulations, and the computational efficiency is not significantly higher than the Blade Element Momentum (BEM) theory. The paper shows that CFD for rotor design is possible using a high-performance single personal computer with multiple cores