Trace-element variations in an annually layered stalagmite as recorders of climatic changes and anthropogenic pollution in Central China

We analyzed variations in the Sr/Ca, Ba/Ca, REE/Ca (REE: rare earth element), Zn/Ca, and Pb/Ca ratios preserved in an annually layered stalagmite, XL21, from central China. The stalagmite record spans the 95 year period AD 1914&ndash;2008. The Sr/Ca and Ba/Ca ratios have a significant positive correlation with the stalagmite&#39;s growth rate, suggesting that they were primarily controlled by growth-rate variations. Variations in REE/Ca ratios are consistent with local temperature changes, suggesting temperature influenced REE concentrations in the stalagmite over decadal to annual timescales. Higher temperature in this humid area can increase vegetation cover, microbial activity, and organic decomposition in the soil, resulting in enhanced pCO2, organic matter concentration and reduced pH, and consequently increased REE mobilization from the overlying soil layer and host rock. Higher temperatures may also increase the natural Zn mobilization from the overlying soil mediated by organic matter and consequently may have led to increased Zn retention in XL21. An increasing trend is seen in the Pb/Ca ratios from XL21 since 1985, which is consistent with increased lead production in this area, and indicates an increase in mine-derived lead pollution in the local environment over the past 30 years.</p

Quantitative temperature reconstruction based on growth rate of annually-layered stalagmite: a case study from central China

We used the annual growth rate of a stalagmite (XL21) collected from Xianglong Cave, central China, to quantitatively reconstruct regional terrestrial temperature changes over the last 95 years (1912-2006 AD). Based on a significant positive correlation between the growth rate and the observed temperature, a transfer function was designed, and the temperature from the previous September to May (P-9-5) was reconstructed, with an explained variance of 43.5%. Our results show an increasing trend in temperature during the last century, and especially over the last 30 years. The temperature variability from central China recorded here bears a striking similarity to that in the Northern Hemisphere, and also to global trends. However, the cooling between the 1980s and the early 1990s seen in the stalagmite record, which interrupted the warming trend that began in the 1960s, is not observed in the mean conditions found in China, the Northern Hemisphere, neither globally. This methodology for reconstructing historical temperature from stalagmite growth rates overcomes the limitation of the short meteorological observation period and supports the potential of stalagmite lamina climatology.</p

Mysterious abrupt carbon-14 increase in coral contributed by a comet

A large and sudden increase in radiocarbon (C-14) around AD773 are documented in coral skeletons from the South China Sea. The C-14 increased by similar to 15 parts per thousand during winter, and remain elevated for more than 4 months, then increased and dropped down within two months, forming a spike of 45 parts per thousand high in late spring, followed by two smaller spikes. The C-14 anomalies coincide with an historic comet collision with the Earth&#39;s atmosphere on 17 January AD 773. Comas are known to have percent-levels of nitrogen by weight, and are exposed to cosmic radiation in space. Hence they may be expected to contain highly elevated C-14/C-12 ratios, as compared to the Earth&#39;s atmosphere. The significant input of C-14 by comets may have contributed to the fluctuation of C-14 in the atmosphere throughout the Earth&#39;s history, which should be considered carefully to better constrain the cosmic ray fluctuation.</p

Recent 121-year variability of western boundary upwelling in the northern South China Sea

Coastal upwelling is typically related to the eastern boundary upwelling system, whereas the powerful southwest Asian summer monsoon can also generate significant cold, nutrient-rich deep water in western coastal zones. Here we present a sea surface temperature record (A.D. 1876-1996) derived from coral Porites Sr/Ca for an upwelling zone in the northern South China Sea. The upwelling-induced sea surface temperature anomaly record reveals prominent multidecadal variability driven by Asian summer monsoon dynamics with an abrupt transition from warmer to colder conditions in 1930, and a return to warmer conditions after 1960. Previous studies suggest the expected increase in atmospheric CO2 for the coming decades may result in intensification in the eastern boundary upwelling system, which could enhance upwelling of CO2-rich deep water thus exacerbating the impact of acidification in these productive zones. In contrast, the weakening trend since 1961 in the upwelling time series from the northern South China Sea suggests moderate regional ocean acidification from upwelling thus a stress relief for marine life in this region.</p

Cyclic precipitation variation on the western Loess Plateau of China during the past four centuries

Precipitation variation on the Loess Plateau (LP) of China is not only important for rain-fed agriculture in this environmentally sensitive region, but also critical for the water and life securities over the whole Yellow River basin. Here we reconstruct high resolution precipitation variation on the western LP during the past 370 years by using two replicated, annually-laminated stalagmites. Spatial analysis suggests that the reconstruction can be also representative for the whole LP region. The precipitation variations show a significant quasi-50 year periodicity during the last 370 years, and have an important role in determining the runoff of the middle Yellow River. The main factor controlling the decadal scale variations and long-term trend in precipitation over this region is southerly water vapour transport associated with the Asian summer monsoon. The Pacific Decadal Oscillation is also an important influence on precipitation variation in this region, as it can affect the East Asian summer monsoon and the West Pacific Subtropical High.</p

Acceleration of modern acidification in the South China Sea driven by anthropogenic CO2

Modern acidification by the uptake of anthropogenic CO2 can profoundly affect the physiology of marine organisms and the structure of ocean ecosystems. Centennial-scale global and regional influences of anthropogenic CO2 remain largely unknown due to limited instrumental pH records. Here we present coral boron isotope-inferred pH records for two periods from the South China Sea: AD 1048-1079 and AD 1838-2001. There are no significant pH differences between the first period at the Medieval Warm Period and AD 1830-1870. However, we find anomalous and unprecedented acidification during the 20th century, pacing the observed increase in atmospheric CO2. Moreover, pH value also varies in phase with inter-decadal changes in Asian Winter Monsoon intensity. As the level of atmospheric CO2 keeps rising, the coupling global warming via weakening the winter monsoon intensity could exacerbate acidification of the South China Sea and threaten this expansive shallow water marine ecosystem.</p

Reconstructing surface ocean circulation with 129I time series recordsfrom corals

The long-lived radionuclide 129I (half-life: 15.7&nbsp;&times;&nbsp;106&nbsp;yr) is well-known as a useful environmental tracer. At present, the global 129I in surface water is about 1&ndash;2 orders of magnitude higher than pre-1960 levels. Since the 1990s, anthropogenic 129I produced from industrial nuclear fuels reprocessing plants has been the primary source of 129I in marine surface waters of the Atlantic and around the globe. Here we present four coral 129I time series records from: 1) Con Dao and 2) Xisha Islands, the South China Sea, 3) Rabaul, Papua New Guinea and 4) Guam. The Con Dao coral 129I record features a sudden increase in 129I in 1959. The Xisha coral shows similar peak values for 129I as the Con Dao coral, punctuated by distinct low values, likely due to the upwelling in the central South China Sea. The Rabaul coral features much more gradual 129I increases in the 1970s, similar to a published record from the Solomon Islands. The Guam coral 129I record contains the largest measured values for any site, with two large peaks, in 1955 and 1959. Nuclear weapons testing was the primary 129I source in the Western Pacific in the latter part of the 20th Century, notably from testing in the Marshall Islands. The Guam 1955 peak and Con Dao 1959 increases are likely from the 1954 Castle Bravo test, and the Operation Hardtack I test is the most likely source of the 1959 peak observed at Guam. Radiogenic iodine found in coral was carried primarily through surface ocean currents. The coral 129I time series data provide a broad picture of the surface distribution and depth penetration of 129I in the Pacific Ocean over the past 60 years.</p