9 research outputs found
Correction: New ferrocene-based 2-thio-imidazol-4-ones and their copper complexes. Synthesis and cytotoxicity
No full textDimension estimates for arbitrary subsets of limit sets of a Markov construction and related multifractal analysis
No full textExperimental and Kinetic Modeling Study of Cyclohexane Oxidation in a JSR at High Pressure
No full textSynthesis of 5-Phenyl-2,2'-bipyridines 6-Substituted with Donor Groups by aza-Diels–Alder Reactions of 5-R-1,2,4-Triazines under High Pressure Conditions
No full textAtomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics
Full text linkThe weakly coordinating cluster [CB11H12]− is used as a versatile building block for the preparation of luminescent copper(I) complexes. Treatment of [CB11H11‐12‐C≡CH]− with CuI and ammonia affords {(CB11H11‐12‐C≡C)2Cu4(NH3)3}n (2). Addition of selected phosphine and pyridine ligands transforms 2 to a range of homometallic products 3–13. All compounds have been characterized by X‐ray crystallography, which reveals a surprising variety of structural complexity featuring cores with two to ten Cu+ centers. In the solid state, products 3–13 exhibit room‐temperature phosphorescence across the visible spectrum in colors from blue to deep red. Lifetimes at room temperature are in the microsecond regime, and quantum yields of up to Φ=0.99 are observed
New ferrocene-based 2-thio-imidazol-4-ones and their copper complexes. Synthesis and cytotoxicity
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