1,042 research outputs found
Core-shell nanoparticle arrays double the strength of steel
Manipulating structure, defects and composition of a material at the atomic scale for enhancing its physical or mechanical properties is referred to as nanostructuring. Here, by combining advanced microscopy techniques, we unveil how formation of highly regular nano-arrays of nanoparticles doubles the strength of an Fe-based alloy, doped with Ti, Mo, and V, from 500 MPa to 1 GPa, upon prolonged heat treatment. The nanoparticles form at moving heterophase interfaces during cooling from the high-temperature face-centered cubic austenite to the body-centered cubic ferrite phase. We observe MoC and TiC nanoparticles at early precipitation stages as well as core-shell nanoparticles with a Ti-C rich core and a Mo-V rich shell at later precipitation stages. The core-shell structure hampers particle coarsening, enhancing the material's strength. Designing such highly organized metallic core-shell nanoparticle arrays provides a new pathway for developing a wide range of stable nano-architectured engineering metallic alloys with drastically enhanced properties. ?The Author(s) 2017.1116Ysciescopu
Measuring Temperature Gradients over Nanometer Length Scales
When a quantum dot is subjected to a thermal gradient, the temperature of
electrons entering the dot can be determined from the dot's thermocurrent if
the conductance spectrum and background temperature are known. We demonstrate
this technique by measuring the temperature difference across a 15 nm quantum
dot embedded in a nanowire. This technique can be used when the dot's energy
states are separated by many kT and will enable future quantitative
investigations of electron-phonon interaction, nonlinear thermoelectric
effects, and the effciency of thermoelectric energy conversion in quantum dots.Comment: 6 pages, 5 figure
Theory of biopolymer stretching at high forces
We provide a unified theory for the high force elasticity of biopolymers
solely in terms of the persistence length, , and the monomer spacing,
. When the force f>\fh \sim k_BT\xi_p/a^2 the biopolymers behave as Freely
Jointed Chains (FJCs) while in the range \fl \sim k_BT/\xi_p < f < \fh the
Worm-like Chain (WLC) is a better model. We show that can be estimated
from the force extension curve (FEC) at the extension
(normalized by the contour length of the biopolymer). After validating the
theory using simulations, we provide a quantitative analysis of the FECs for a
diverse set of biopolymers (dsDNA, ssRNA, ssDNA, polysaccharides, and
unstructured PEVK domain of titin) for . The success of a specific
polymer model (FJC or WLC) to describe the FEC of a given biopolymer is
naturally explained by the theory. Only by probing the response of biopolymers
over a wide range of forces can the -dependent elasticity be fully
described.Comment: 20 pages, 4 figure
HT-FED2004-56184 CFD ANALYSIS OF GAS-INSULATED TRANSFORMERS
ABSTRACT A thermal design of transformers has been performed using an empirical formula. In order to reduce the developing cost and time, CFD analysis is used in thermal design process for gas-insulated transformers. We calculated the pressure loss of coolant and the temperature rise of winding with empirical formulas and CFD analysis. Also, we constructed some real machines and compared the analytic results with the experimental data. The comparison shows a good agreement between the CFD calculations and experimental results
Study of Thermal Properties of Graphene-Based Structures Using the Force Constant Method
The thermal properties of graphene-based materials are theoretically
investigated. The fourth-nearest neighbor force constant method for phonon
properties is used in conjunction with both the Landauer ballistic and the
non-equilibrium Green's function techniques for transport. Ballistic phonon
transport is investigated for different structures including graphene, graphene
antidot lattices, and graphene nanoribbons. We demonstrate that this particular
methodology is suitable for robust and efficient investigation of phonon
transport in graphene-based devices. This methodology is especially useful for
investigations of thermoelectric and heat transport applications.Comment: 23 pages, 9 figures, 1 tabl
Screening of suitable cationic dopants for solar absorber material CZTS/Se: A first principles study
The earth abundant and non-toxic solar absorber material kesterite Cu2ZnSn(S/Se)(4) has been studied to achieve high power conversion efficiency beyond various limitations, such as secondary phases, antisite defects, band gap adjustment and microstructure. To alleviate these hurdles, we employed screening based approach to find suitable cationic dopant that can promote the current density and the theoretical maximum upper limit of the energy conversion efficiency (P(%)) of CZTS/Se solar devices. For this task, the hybrid functional (Heyd, Scuseria and Ernzerhof, HSE06) were used to study the electronic and optical properties of cation (Al, Sb, Ga, Ba) doped CZTS/Se. Our in-depth investigation reveals that the Sb atom is suitable dopant of CZTS/CZTSe and also it has comparable bulk modulus as of pure material. The optical absorption coefficient of Sb doped CZTS/Se is considerably larger than the pure materials because of easy formation of visible range exciton due to the presence of defect state below the Fermi level, which leads to an increase in the current density and P(%). Our results demonstrate that the lower formation energy, preferable energy gap and excellent optical absorption of the Sb doped CZTS/Se make it potential component for relatively high efficient solar cells
New insights into electron spin dynamics in the presence of correlated noise
The changes of the spin depolarization length in zinc-blende semiconductors
when an external component of correlated noise is added to a static driving
electric field are analyzed for different values of field strength, noise
amplitude and correlation time. Electron dynamics is simulated by a Monte Carlo
procedure which keeps into account all the possible scattering phenomena of the
hot electrons in the medium and includes the evolution of spin polarization.
Spin depolarization is studied by examinating the decay of the initial spin
polarization of the conduction electrons through the D'yakonov-Perel process,
the only relevant relaxation mechanism in III-V crystals. Our results show
that, for electric field amplitude lower than the Gunn field, the dephasing
length shortens with the increasing of the noise intensity. Moreover, a
nonmonotonic behavior of spin depolarization length with the noise correlation
time is found, characterized by a maximum variation for values of noise
correlation time comparable with the dephasing time. Instead, in high field
conditions, we find that, critically depending on the noise correlation time,
external fluctuations can positively affect the relaxation length. The
influence of the inclusion of the electron-electron scattering mechanism is
also shown and discussed.Comment: Published on "Journal of Physics: Condensed Matter" as "Fast Track
Communications", 11 pages, 9 figure
Negative Thermal Expansion Coefficient of Graphene Measured by Raman Spectroscopy
The thermal expansion coefficient (TEC) of single-layer graphene is estimated
with temperature-dependent Raman spectroscopy in the temperature range between
200 and 400 K. It is found to be strongly dependent on temperature but remains
negative in the whole temperature range, with a room temperature value of
-8.0x10^{-6} K^{-1}. The strain caused by the TEC mismatch between graphene and
the substrate plays a crucial role in determining the physical properties of
graphene, and hence its effect must be accounted for in the interpretation of
experimental data taken at cryogenic or elevated temperatures.Comment: 17 pagese, 3 figures, and supporting information (4 pages, 3
figures); Nano Letters, 201
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