9 research outputs found
Nanoscale grains, high irreversibility field, and large critical current density as a function of high energy ball milling time in C-doped magnesium diboride
Magnesium diboride (MgB2) powder was mechanically alloyed by high energy ball
milling with C to a composition of Mg(B0.95C0.05)2 and then sintered at 1000 C
in a hot isostatic press. Milling times varied from 1 minute to 3000 minutes.
Full C incorporation required only 30-60 min of milling. Grain size of sintered
samples decreased with increased milling time to less than 30 nm for 20-50 hrs
of milling. Milling had a weak detrimental effect on connectivity. Strong
irreversibility field (H*) increase (from 13.3 T to 17.2 T at 4.2 K) due to
increased milling time was observed and correlated linearly with inverse grain
size (1/d). As a result, high field Jc benefited greatly from lengthy powder
milling. Jc(8 T, 4.2 K) peaked at > 80,000 A/cm2 with 1200 min of milling
compared with only ~ 26,000 A/cm2 for 60 min of milling. This non-compositional
performance increase is attributed to grain refinement of the unsintered powder
by milling, and to the probable suppression of grain growth by milling-induced
MgO nano-dispersions.Comment: 12 pages, 11 figure
Improved Hc2 in Bulk-Form Magnesium Diboride by Mechanical Alloying With Carbon
High energy milling of MgB2 pre-reacted powder renders the material largely
amorphous through extreme mechanical deformation and is suitable for
mechanically alloying MgB2 with dopants including carbon. Bulk samples of
milled C and MgB2 powders subjected to hot isostatic pressing and Mg vapor
annealing have achieved critical fields in excess of 32T and critical current
density approaching 10^6 A/cm^2.Comment: 13 pages, 3 figures references updated, typos corrected, numerical
error correcte
Atmospheric conditions and their effect on ball-milled magnesium diboride
Magnesium diboride bulk pellets were fabricated from pre-reacted MgB2 powder
ball milled with different amounts of exposure to air. Evidence of increased
electron scattering including increased resistivity, depressed Tc, and enhanced
Hc2 of the milled and heat treated samples were observed as a result of
increased contact with air. These and other data were consistent with alloying
with carbon as a result of exposure to air. A less clear trend of decreased
connectivity associated with air exposure was also observed. In making the case
that exposure to air should be considered a doping process, these results may
explain the wide varibability of "undoped" MgB2 properties extant in the
literature.Comment: Work presented at ASC 2006 in Seattl
Hollow carbon spheres as an efficient dopant for enhancing critical current density of MgB2 based tapes
A significant enhancement of Jc and Hirr in MgB2 tapes has been achieved by
the in situ powder-in-tube method utilizing hollow carbon spheres (HCS) as
dopants. At 4.2 K, the transport Jc for the 850C sintered samples reached
3.1x10^4, and 1.4x10^4 A/cm^2 at 10 and 12 T, respectively, and were better
than those of optimal nano-SiC doped tapes. Furthermore, the Hirr for doped
sample was raised up to 16.8 T at 10 K due to the carbon substitution effect.
The results demonstrate that HCS is one of the most promising dopants besides
nano-carbon and SiC for the enhancement of current capacity for MgB2 in high
fields.Comment: 14 pages, 5 figure
Evidence for two distinct scales of current flow in polycrystalline Sm and Nd iron oxypnictides
Early studies have found quasi-reversible magnetization curves in
polycrystalline bulk rare-earth iron oxypnictides that suggest either
wide-spread obstacles to intergranular current or very weak vortex pinning. In
the present study of polycrystalline samarium and neodymium rare-earth iron
oxypnictide samples made by high pressure synthesis, the hysteretic
magnetization is significantly enhanced. Magneto optical imaging and study of
the field dependence of the remanent magnetization as a function of particle
size both show that global currents over the whole sample do exist but that the
intergranular and intragranular current densities have distinctively different
temperature dependences and differ in magnitude by about 1000. Assuming that
the highest current density loops are restricted to circulation only within
grains leads to values of ~5 MA/cm2 at 5 K and self field, while whole-sample
current densities, though two orders of magnitude lower are 1000-10000 A/cm2,
some two orders of magnitude higher than in random polycrystalline cuprates. We
cannot yet be certain whether this large difference in global and intragrain
current density is intrinsic to the oxypnictides or due to extrinsic barriers
to current flow, because the samples contain significant second phase, some of
which wets the grain boundaries and produces evidences of SNS proximity effect
in the whole sample critical current.Comment: 28 pages, 14 figure
Evaluation of connectivity, flux pinning, and upper critical field contributions to the critical current density of bulk pure and SiC-alloyed MgB2
Measurement of critical current density Jc, normal state resistivity rho_n, and upper critical field Hc2 on pure and 10% SiC-doped MgB2 bulks show systematic enhancement of Hc2 by SiC addition and by lowering reaction temperature. Hc2 (10 K) exceeds 33 T, while the extrapolated zero temperature value exceeds 40 T. The Rowell [ Supercond. Sci. Technol. 16, R17 2003] analysis suggests that only 8%?17% of the MgB2 cross section actually carries current. Higher reaction temperature enhances the connectivity but degrades Hc2 and flux pinning, making the measured Jc a complex balance between connectivity, Hc2, and flux pinning induced by grain boundaries and precipitates