31 research outputs found

    Akten

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    [s.c.

    Der preussische Staat und die Juden

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    Selma Ster

    Darstellung

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    International Project Finance

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    Selma Stern-Taeubler Collection 1713-1991

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    This collection documents the work of historian Selma Stern-Taebler, and includes extensive research notes, articles, correspondence, a few photos, diaries, and other personal writing.The most prominent topic represented in this collection is Selma Stern-Taeubler’s published works, which is the concern of the majority of papers in the collection. Most of the collection is comprised either of background materials for professional writings, of copies of manuscripts of published works, or of correspondence or reviews focusing on the publications.Copy available in the Library. Also published in English in LBI Yearbook III, 1958.digitize

    New insights on the electronic, magnetic, electric and molecular structure of a bis-(4-cyanopyridine) iron(III) complex with the meso-tetrakis(4-methoxyphenyl)porphyrin

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    International audienceWe have successfully synthesized and characterized a new low-spin iron(III) bis(4-cyanopyridine) complex with a meso-porphyrin substituted in the para positions of the phenyls by the methoxy group, namely the bis(4-cyanopyridine)[(meso-tetrakis(4-metoxyphenylporphyrinato)]iron(III) trifluoromethanesulfonate chlorobenzene monosolvate complex with the formula [FeIII(TMPP)(4-CNpy)2]SO3CF3.C6H5Cl (I). This species was characterized through ultraviolet–visible, Fourier-transform infrared and Mössbauer spectroscopy as well as by SQUID magnetometry, cyclic voltammetry, and X-ray crystallography. These characterizations indicated that our synthetic heme model is a low-spin (S = 1/2) coordination compound and especially shows that the structural, electronic and the magnetic properties of complex (I) are closely dominated by the presence of the methoxy σ-donor group at the para positions of the meso-porphyrin
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