181 research outputs found

    Ionic liquids that form adducts with alcohols

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    Ionic liquids bearing an activated carbonyl group in the cation are shown to form adducts with alcohols without the aid of any catalysts. How these functionalised ionic liquids could be used in altering vapour phase compositions of alcohols and in alcohol separations are demonstrated.</p

    Exceptional activity of gallium(III) chloride and chlorogallate(III) ionic liquids for Baeyer–Villiger oxidation

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    The extremely high activity of chlorogallate(iii) ionic liquids and GaCl3 in promoting Baeyer–Villiger oxidation of cyclic ketones with H2O2 to lactones is reported.</p

    Separation of aromatic hydrocarbons from alkanes using the ionic liquid 1-ethyl-3-methylimidazolium bis{(trifluoromethyl) sulfonyl} amide

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    The liquid-liquid equilibrium for the ternary system formed by hexane, benzene and the ionic liquid 1-ethyl-3-methylimidazolium bis
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