Wind energy curtailment utilisation with a storage technology : applying cost-benefit base analysis in Scottish wind farms

Growing concern about global warming has been revealing its impact gradually over the last decade. Excessive use of fossil fuels has been shown as one of the most significant reason of the global warming. As a mitigation measure, deployment of renewable energy resources is appeared to be an essential energy option. In the last decade, the world witnessed the considerable deployement of the renewable energy resources to meet energy need and wind energy has a vital role within this change. However, as the use of renewable energy sources grows up, coming across some challenges having an impact on the supply and demand balance is inevitable. As the wind energy is non-dispatchable resource, minimizing wind energy curtailment is an important part to harness wind energy efficiently. Deployment of storage technologies for wind energy with supporting policies could help to use wind energy wisely

Techno-economic analysis of on-site energy storage units to mitigate wind energy curtailment : a case study in Scotland

Wind energy plays a major role in decarbonisation of the electricity sector and supports achieving net-zero greenhouse gas emissions. Over the last decade, the wind energy deployments have grown steadily, accounting for more than one fourth of the annual electricity generation in countries like the United Kingdom, Denmark, and Germany. However, as the share of wind energy increases, system operators face challenges in managing excessive wind generation due to its nondispatchable nature. Currently, the most common practice is wind energy curtailment in which wind farm operators receive constraint payments to reduce their renewable energy production. This practice not only leads to wastage of large volumes of renewable energy, but also the associated financial cost is reflected to rate payers in the form of increased electricity bills. On-site energy storage technologies come to the forefront as a technology option to minimise wind energy curtailment and to harness wind energy in a more efficient way. To that end, this paper, first, systematically evaluates different energy storage options for wind energy farms. Second, a depth analysis of curtailment and constraint payments of major wind energy farms in Scotland are presented. Third, using actual wind and market datasets, a techno-economic analysis is conducted to examine the relationship between on-site energy storage size and the amount of curtailment. The results show that, similar to recent deployments, lithium-ion technology is best suited for on-site storage. As case studies, Whitelee and Gordon bush wind farms in Scotland are chosen. The most suitable storage capacities for 20 years payback period is calculated as follows: (i) the storage size for the Gordonbush wind farm is 100 MWh and almost 19% of total curtailment can be avoided and (ii) the storage size for the Whitlee farm is 125 MWh which can reduce the curtailment by 20.2%. The outcomes of this study will shed light into analysing curtailment reduction potential of future wind farms including floating islands, seaports, and other floating systems

Plasma total anti-oxidant capacity correlates inversely with the extent of acute appendicitis: a case control study

BACKGROUND: The role of free oxygen radicals in inflammatory conditions is well known. Free radicals cause lipid peroxidation of cellular membranes resulting in cell death. The purpose of this study was to investigate the levels of total anti-oxidant status (TAS), as a marker of anti-oxidant defense system and malondialdehyde (MDA), as a marker of oxidative stress, in the plasma of patients with acute appendicitis. METHODS: Fifty-one adult patients with a median age of 31 years who underwent operations with a preoperative diagnosis of acute appendicitis were included in this prospective study. Blood samples for C-reactive protein (CRP), MDA and TAS were collected preoperatively. Groups were compared by using the Mann-Whitney U test. RESULTS: There were 27 patients with acute phlagmenous appendicitis and 19 patients with advanced appendicitis (10 gangrenous and 9 perforated appendicitis), while 5 negative explorations were documented. No significant differences in WBC counts and MDA levels between groups were encountered. Plasma CRP was significantly higher in patients with perforated appendicitis, but not in the other groups. In advanced appendicitis group, TAS level was significantly lower than the other groups. On the other hand, plasma TAS level in acute phlagmenous appendicitis group was significantly higher. CONCLUSION: A decrease in plasma total anti-oxidant capacity might be a predictor of the progression of inflammation to the perforation in acute appendicitis

Delipidation Of Plasma Has Minimal Effects On Human Butyrylcholinesterase

Human butyrylcholinesterase (BChE) is purified in large quantities from Cohn fraction IV-4 to use for protection against the toxicity of chemical warfare agents. Small scale preliminary experiments use outdated plasma from the American Red Cross as the starting material for purifying BChE (P06276). Many of the volunteer donor plasma samples are turbid with fat, the donor having eaten fatty food before the blood draw. The turbid fat interferes with enzyme assays performed in the spectrophotometer and with column chromatography. Our goal was to find a method to remove fat from plasma without loss of BChE activity. Satisfactory delipidation was achieved by adding a solution of 10% dextran sulfate and calcium chloride to fatty plasma, followed by centrifugation, and filtration through a 0.8 μm filter. Treatment with Aerosil also delipidated fatty plasma, but was accompanied by loss of 50% of the plasma volume. BChE activity and the BChE isozyme pattern on nondenaturing gel electrophoresis were unaffected by delipidation. BChE in delipidated plasma was efficiently captured by immobilized monoclonal antibodies B2 18-5 and mAb2. The immunopurified BChE was released from antibody binding with acid and visualized as a highly enriched, denatured BChE preparation by SDS gel electrophoresis. In conclusion, delipidation with dextran sulfate/CaCl2 preserves BChE activity and the tetramer structure of BChE.PubMedWoSScopu

Hupresin Retains Binding Capacity for Butyrylcholinesterase and Acetylcholinesterase after Sanitation with Sodium Hydroxide

Hupresin is a new affinity resin that binds butyrylcholinesterase (BChE) in human plasma and acetylcholinesterase (AChE) solubilized from red blood cells (RBC). Hupresin is available from the CHEMFORASE company. BChE in human plasma binds to Hupresin and is released with 0.1 M trimethylammonium bromide (TMA) with full activity and 10–15% purity. BChE immunopurified from plasma by binding to immobilized monoclonal beads has fewer contaminating proteins than the one-step Hupresin-purified BChE. However, when affinity chromatography on Hupresin follows ion exchange chromatography at pH 4.5, BChE is 99% pure. The membrane bound AChE, solubilized from human RBC with 0.6% Triton X-100, binds to Hupresin and remains bound during washing with sodium chloride. Human AChE is not released in significant quantities with non-denaturing solvents, but is recovered in 1% trifluoroacetic acid. The denatured, partially purified AChE is useful for detecting exposure to nerve agents by mass spectrometry. Our goal was to determine whether Hupresin retains binding capacity for BChE and AChE after Hupresin is washed with 0.1 M NaOH. A 2 mL column of Hupresin equilibrated in 20 mM TrisCl pH 7.5 was used in seven consecutive trials to measure binding and recovery of BChE from 100 mL human plasma. Between each trial the Hupresin was washed with 10 column volumes of 0.1 M sodium hydroxide. A similar trial was conducted with red blood cell AChE in 0.6% Triton X-100. It was found that the binding capacity for BChE and AChE was unaffected by washing Hupresin with 0.1 M sodium hydroxide. Hupresin could be washed with sodium hydroxide at least seven times without losing binding capacity

The Relations Among General Intelligence, Metacognition and Text Learning Performance

The main aim of this study was to investigate the relations among text learning performance, general intelligence and the three components of metacognition; namely metacognitive knowledge, metacognitive monitoring and metacognitive control. The participants were 91 fifth graders. The results of the study indicated no significant correlations among metacognitive knowledge, metacognitive control and general intelligence. On the other hand, metacognitive monitoring and general intelligence correlated significantly. The results of the regression analysis showed that metacognitive knowledge did not contribute to students' text-learning performance whereas metacognitive monitoring and metacognitive control, together with general intelligence, were found to be significant predictors in explaining students' text-learning performance

Silica embedded cobalt(0) nanoclusters: Efficient, stable and cost effective catalyst for hydrogen generation from the hydrolysis of ammonia borane

Cobalt(0) nanoclusters embedded in silica (Co@SiO2) were prepared by a facile two-step procedure. In the first step, the hydrogenphosphate anion (HPO42-) stabilized cobalt(0) nanoclusters were in situ generated from the reduction of cobalt(II) chloride during the hydrolysis of sodium borohydride (NaBH4) in the presence of stabilizer. Next, HPO42- anion-stabilized cobalt(0) nanoclusters were embedded in silica formed by in situ hydrolysis and condensation of tetraethylorthosilicate added as ethanol solution. Co@SiO2 can be separated from the solution by vacuum filtration and characterized by UV-Vis electronic absorption spectroscopy, TEM, SEM-EDX, ATR-IR and ICP-OES techniques. Co@SiO2 are found to be highly active and stable catalysts in the hydrolysis of ammonia borane (AB) even at low cobalt concentration and room temperature. They provide an initial turnover frequency of 13.3 min(-1) and 24,400 total turnovers over 52 h in the hydrolysis of AB at 25.0 +/- 0.5 degrees C. Moreover, Co@SiO2 retain 72% and 74% of the initial activity after ten runs recyclability and five cycles reusability test in the hydrolysis of AB, respectively. The kinetics of hydrogen generation from the hydrolysis of AB catalyzed by Co@SiO2 was studied depending on the catalyst concentration, substrate concentration, and temperature. The activation parameters of this catalytic reaction were also determined from the evaluation of the kinetic data. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved