A search for interstellar and circumstellar C60

It has recently been suggested that the diffuse interstellar bands may be formed by ionized polyhedral carbon molecules such as C60(+). While specific laboratory measurements of absorption bands of this molecular ion have not been made, a feature due to the neutral molecule C60 has been discovered at 3860A. Examination of spectra of several reddened stars, as well as one star known to have circumstellar carbonaceous dust, shows no sign of the feature, leading to upper limits of the order of 10 to the 14th/sq cm for the column density of C60. These limits are not yet sensitive enough to violate the expectations of crude predictions

Diffuse band profiles in the spectrum of HD 29647: Evidence for a molecular origin?

High signal-to-noise ratio spectra have been obtained of the diffuse interstellar bands at 5780 and 5797 Å in the spectrum of HD 29647, a heavily reddened star within or behind a portion of the Taurus dark cloud complex. The observations were made using the coudé spectrograph on the Canada-France-Hawaii Telescope. The Reticon detector combined with the coudé spectrograph and excellent observing conditions allowed S/N ratios as high as 200 for this star, which was V=8.37 and E(B–V)=1.03. In two separate exposures both bands were found to be narrower and weaker than normal values for stars of similar reddening, and the profiles appear to deviate from those normally seen as well. Theories of band formation due to absorption centers in solid grains require bandwidths much greater than observed in HD 29647 and predict profile variations with grain size that are quite different from what is seen. Therefore we suggest that these observations argue for a molecular origin for the diffuse bands. The observed profiles may be explained as due to unusual rotational excitation in molecules

The physics of grain-grain collisions and gas-grain sputtering in interstellar shocks

Grain-grain collisions and ion sputtering destroy dust grains in interstellar shocks. An analytical theory is developed for the propagation of shock waves in solids driven by grain-grain collisions, which compares very favorably with detailed numerical calculations. This theory is used to determine the fraction of a grain vaporized by a grain-grain collision. Our results predict much less vaporization of colliding grains in interstellar shocks than previous estimates. This theory can also be used to determine the fraction of a colliding grain that melts, shatters, or undergoes a phase transformation to a higher density phase. In particular, the latter two processes can be much more important in interstellar shocks than vaporization. The sputtering of grains by impacting gas ions is reanalyzed based upon extensive laboratory studies and a theoretically derived ``universal\u27\u27 sputtering relation. The analytical results are compared to available experimental studies of sputtering of graphite/amorphous carbon, SiO2, SiC, Fe, and H2O. Sputtering yields for astrophysically relevant materials as a function of impact energy and ion mass are derived. These yields are also averaged over thermal impact spectrum and simple polynomial fits to the resulting yields as a function of temperature are presented. The derived sputtering yields are similar to those adopted in previous studies, except for graphite near threshold where the new yields are much larger due to a lower adopted binding energy. The ion bombardment will amorphitize the surface layers of interstellar grains. It will also convert graphite into hydrogenated amorphous carbon (HAC) to a depth of 10–20 Å. It is suggested that these HAC surfaces are the carriers of the 3.4 µm absorption feature in the interstellar mediu

The physics of grain-grain collisions and gas-grain sputtering in interstellar shocks

Grain-grain collisions and ion sputtering destroy dust grains in interstellar shocks. An analytical theory is developed for the propagation of shock waves in solids driven by grain-grain collisions, which compares very favorably with detailed numerical calculations. This theory is used to determine the fraction of a grain vaporized by a grain-grain collision. Our results predict much less vaporization of colliding grains in interstellar shocks than previous estimates. This theory can also be used to determine the fraction of a colliding grain that melts, shatters, or undergoes a phase transformation to a higher density phase. In particular, the latter two processes can be much more important in interstellar shocks than vaporization. The sputtering of grains by impacting gas ions is reanalyzed based upon extensive laboratory studies and a theoretically derived ``universal\u27\u27 sputtering relation. The analytical results are compared to available experimental studies of sputtering of graphite/amorphous carbon, SiO2, SiC, Fe, and H2O. Sputtering yields for astrophysically relevant materials as a function of impact energy and ion mass are derived. These yields are also averaged over thermal impact spectrum and simple polynomial fits to the resulting yields as a function of temperature are presented. The derived sputtering yields are similar to those adopted in previous studies, except for graphite near threshold where the new yields are much larger due to a lower adopted binding energy. The ion bombardment will amorphitize the surface layers of interstellar grains. It will also convert graphite into hydrogenated amorphous carbon (HAC) to a depth of 10–20 Å. It is suggested that these HAC surfaces are the carriers of the 3.4 µm absorption feature in the interstellar mediu

Spatial correlation between CH, CN and the diffuse interstellar band carriers

Observations are presented of the diffuse interstellar bands at 5780 and 5797 A and of the ultraviolet lines of CH and CN in the light of six bright stars which lie behind isolated interstellar clouds. It is found that CN and CH are only present when the 5797 band is deeper than the 5780 one. Comparisons with satellite measurements of the UV extinction show that the shape of the extinction curve is linked to the same band ratio in these stars. The results support a previous suggestion that the various components of the absorption spectrum of an isolated cloud (the extinction law, atomic and molecular features and the diffuse interstellar bands) all vary together

Spatial correlation between CH, CN and the diffuse interstellar band carriers

Observations are presented of the diffuse interstellar bands at 5780 and 5797 A and of the ultraviolet lines of CH and CN in the light of six bright stars which lie behind isolated interstellar clouds. It is found that CN and CH are only present when the 5797 band is deeper than the 5780 one. Comparisons with satellite measurements of the UV extinction show that the shape of the extinction curve is linked to the same band ratio in these stars. The results support a previous suggestion that the various components of the absorption spectrum of an isolated cloud (the extinction law, atomic and molecular features and the diffuse interstellar bands) all vary together

The weakness of diffuse bands in nebular environments. Possible impact on thePAH+ hypothesis

It has been widely suggested that PAH cations (PAH+) may be the carriers of the diffuse interstellar bands, so it is of interest to probe diffuse behavior in regions suspected of having high abundances of PAHs. Here we examine the strengths of several of the visible-wavelength diffuse interstellar bands in two nebular environments where infrared emission and ultraviolet indicators show that PAHs are abundant. One might expect the PAHs to be predominantly positively ionized in these regions, yet the diffuse bands are systematically weak. This led us to examine the ionization balance for see whether the weakness of the diffuse bands might rule out PAH cations as the carriers. We find that this conclusion is ambiguous, however, due to the very rapid rates for recombination of PAHs: under conditions that may reasonably represent our observed nebulae, the PAHs might be in predominantly neutral form. If so, this would explain the weakness of the diffuse bands, but leaves open some very perplexing questions about where the PAHs might be dominantly in cation form, hence where the diffuse bands do arise if they are due to PAH+

The weakness of diffuse bands in nebular environments. Possible impact on thePAH+ hypothesis

It has been widely suggested that PAH cations (PAH+) may be the carriers of the diffuse interstellar bands, so it is of interest to probe diffuse behavior in regions suspected of having high abundances of PAHs. Here we examine the strengths of several of the visible-wavelength diffuse interstellar bands in two nebular environments where infrared emission and ultraviolet indicators show that PAHs are abundant. One might expect the PAHs to be predominantly positively ionized in these regions, yet the diffuse bands are systematically weak. This led us to examine the ionization balance for see whether the weakness of the diffuse bands might rule out PAH cations as the carriers. We find that this conclusion is ambiguous, however, due to the very rapid rates for recombination of PAHs: under conditions that may reasonably represent our observed nebulae, the PAHs might be in predominantly neutral form. If so, this would explain the weakness of the diffuse bands, but leaves open some very perplexing questions about where the PAHs might be dominantly in cation form, hence where the diffuse bands do arise if they are due to PAH+

SiO emission from the Galactic Center Molecular Clouds

We have mapped the J=1-0 line of SiO in a 1 degree x 12 arcmin. (lxb) region around the Galactic center (GC) with an angular resolution of 2 arcmin. (approx. 4 pc). In contrast to the spatial distribution of other high dipole moment molecules like CS, whose emission is nearly uniform, the SiO emission is very fragmented and it is only associated with some molecular clouds. In particular, it is remarkable that the SiO emission closely follows the non-thermal radio arc in the GC. The SiO clouds are more extended than the beam with typical sizes between 4 and 20 pc. High angular resolution (26 arcsec.) mapping in the J=1-0 line of SiO toward the molecular clouds in Sgr B2 and Sgr A shows that the SiO emission is relatively smooth with structures of typically 2 pc. From the line intensities of the J=1-0, J=3-2 and J=5-4 transitions of SiO we derive H2 densities for these clouds of a few 1e4 cm-3. The SiO fractional abundances are approx. 1e-9 for the SiO clouds and 1e-10 for the other molecular clouds in the GC. The characteristics (size and H2 densities) of the SiO emission in the GC are completely different from those observed in the Galactic disk, where the SiO emission arises from much smaller regions with larger H2 densities. We briefly discuss the implications of the SiO emission in the molecular clouds of the GC. We conclude that the particular chemistry in these clouds is probably related to large scale fast shocks occurring in the Galactic center region.Comment: 9 pages, 4 Postscript figures, To be published in ApJ letter

The Interstellar Environment of our Galaxy

We review the current knowledge and understanding of the interstellar medium of our galaxy. We first present each of the three basic constituents - ordinary matter, cosmic rays, and magnetic fields - of the interstellar medium, laying emphasis on their physical and chemical properties inferred from a broad range of observations. We then position the different interstellar constituents, both with respect to each other and with respect to stars, within the general galactic ecosystem.Comment: 39 pages, 12 figures (including 3 figures in 2 parts